A smoke producing method and device of the present disclosure produces a non-incendiary, organic-polymerization based, smoke-producing reaction. Some versions of the smoke are effective carriers for capsaicinoid compounds. The method of generating smoke comprises initiating a frontal polymerization reaction by heating a composition comprising a monomer compound that exothermically polymerizes upon initiation with an initiator compound and an initiator compound that initiates polymerization of the monomer compound present at a mass concentration that is at least five percent of the mass concentration of the monomer compound. The polymerization of the monomer compound is exothermic, and in one embodiment the concentration of initiator compound is at least five percent of the concentration of monomer compound. The smoke mainly comprises thermal decomposition products of the initiator compound.

There is provided an energy management method, comprising steps of conducting (304) electric energy from an energy production plant (110, 112, 114, 140) to an energy storage facility (120, 220), applying, in the energy storage facility (120, 220), the received electric energy on a chemical compound (222) to separate the chemical compound to a first component (224) and a second component (226), and storing (306), in the energy storage facility (120, 220), the first component and the second component separately.

There is provided an energy management method, comprising steps of conducting (304) electric energy from an energy production plant (110, 112, 114, 140) to an energy storage facility (120, 220), applying, in the energy storage facility (120, 220), the received electric energy on a chemical compound (222) to separate the chemical compound to a first component (224) and a second component (226), and storing (306), in the energy storage facility (120, 220), the first component and the second component separately.

An apparatus for heating a product includes a storage compartment for a product to be heated and a heater module physically and thermally coupled to the storage compartment. The heater module has a housing that defines a reaction chamber. A rigid barrier is inside the reaction chamber and defines first and second portions thereof. A first reactant is inside the reaction chamber, and a flexible bag (with a second reactant) is in the first portion of the first chemical reactant. The first and second reactants react exothermically upon contact. A piercing element can pierce the flexible bag. After piercing, the a fluid path and one or more fluid channels carry the second reactant to a section of the first portion of the reaction chamber away from where the flexible bag is located.

An apparatus for heating a product includes a storage compartment for a product to be heated and a heater module physically and thermally coupled to the storage compartment. The heater module has a housing that defines a reaction chamber. A rigid barrier is inside the reaction chamber and defines first and second portions thereof. A first reactant is inside the reaction chamber, and a flexible bag (with a second reactant) is in the first portion of the first chemical reactant. The first and second reactants react exothermically upon contact. A piercing element can pierce the flexible bag. After piercing, the a fluid path and one or more fluid channels carry the second reactant to a section of the first portion of the reaction chamber away from where the flexible bag is located.

A heating device having at least one package surrounding a hygroscopic salt and a heater mix having at least a metal reactant. The heating device may include a source of moisture positioned in the package, the source of moisture initially generating an atmosphere having nearly 100% relative humidity inside the package. The hygroscopic salt is spatially separated from the source of moisture within the at least one package and positioned so as to absorb moisture out of the atmosphere to form an electrolyte, and the hygroscopic salt is further positioned so that the electrolyte generated by the hygroscopic salt is in contact with the heater mix. Rather than have an internal source of moisture, the at least one package may be water vapor permeable to allow ambient moisture from the atmosphere to enter the interior of the package to combine with the hygroscopic salt to generate an electrolyte.

A heating device having at least one package surrounding a hygroscopic salt and a heater mix having at least a metal reactant. The heating device may include a source of moisture positioned in the package, the source of moisture initially generating an atmosphere having nearly 100% relative humidity inside the package. The hygroscopic salt is spatially separated from the source of moisture within the at least one package and positioned so as to absorb moisture out of the atmosphere to form an electrolyte, and the hygroscopic salt is further positioned so that the electrolyte generated by the hygroscopic salt is in contact with the heater mix. Rather than have an internal source of moisture, the at least one package may be water vapor permeable to allow ambient moisture from the atmosphere to enter the interior of the package to combine with the hygroscopic salt to generate an electrolyte.

A nested temperature regulation device includes a watertight pouch having a gas valve, a first plurality of reactive spheres and a rupturable fluid bag. The first reactive spheres are configured to create an endothermic reaction or an exothermic reaction for a set period of time when engaged by the fluid. At least one soluble barrier is positioned within the pouch and includes a hollow interior space that contains another plurality of reactive spheres. Each soluble barrier is constructed to dissolve and to permit the fluid from the bag to engage a subsequent plurality of reactive spheres after a predetermined period of time that is equal to the effective reaction time of the plurality of reactive spheres immediately previously engaged by the fluid. One or more of the plurality of reactive spheres includes a coating that delays the fluid from accessing the reactive material of the sphere having the coating.

A container may include a storage volume configured to store a payload. A thermal insulation layer may surround the storage volume. A thermoregulation layer may surround the thermal insulation layer. There may be activation of a chemical reaction in the thermoregulation layer. The thermal insulation layer may have R-value per inch configured to expose the payload to a desired temperature to ensure viability of the payload and dampen a temperature spike of the chemical reaction. A system of containers may include a system storage volume with N containers in the system storage volume, wherein N is a whole number of 2 or more. A method of making an insulated container may include preparing an outer skin barrier layer, stacking a thermoregulation layer on the outer skin barrier layer, stacking a thermal insulation layer on the thermoregulation layer, and stacking an inner skin barrier layer on the thermal insulation layer.

A container may include a storage volume configured to store a payload. A thermal insulation layer may surround the storage volume. A thermoregulation layer may surround the thermal insulation layer. There may be activation of a chemical reaction in the thermoregulation layer. The thermal insulation layer may have R-value per inch configured to expose the payload to a desired temperature to ensure viability of the payload and dampen a temperature spike of the chemical reaction. A system of containers may include a system storage volume with N containers in the system storage volume, wherein N is a whole number of 2 or more. A method of making an insulated container may include preparing an outer skin barrier layer, stacking a thermoregulation layer on the outer skin barrier layer, stacking a thermal insulation layer on the thermoregulation layer, and stacking an inner skin barrier layer on the thermal insulation layer.