Systems, methods, and apparatus for a three-dimensional (3D)-printed vessel for wettability assessment of fracturing proppants are disclosed. The vessel includes a base component including a threaded cylindrical portion extending outward from a first side of the base component. The cylindrical portion has a particular thread profile. The base component defines a cavity sized to contain a proppant sample. A cap is configured to be screwed onto the threaded cylindrical portion after the proppant sample is injected into the cavity. A surface of the cap is shaped to flatten a proppant surface of the proppant sample. The cap is threaded with the particular thread profile. A pin is configured to be partially screwed onto a second side of the base component before the proppant sample is injected into the cavity. The second side is opposite to the first side. Other embodiments may be described or claimed.

Systems, methods, and apparatus for a three-dimensional (3D)-printed vessel for wettability assessment of fracturing proppants are disclosed. The vessel includes a base component including a threaded cylindrical portion extending outward from a first side of the base component. The cylindrical portion has a particular thread profile. The base component defines a cavity sized to contain a proppant sample. A cap is configured to be screwed onto the threaded cylindrical portion after the proppant sample is injected into the cavity. A surface of the cap is shaped to flatten a proppant surface of the proppant sample. The cap is threaded with the particular thread profile. A pin is configured to be partially screwed onto a second side of the base component before the proppant sample is injected into the cavity. The second side is opposite to the first side. Other embodiments may be described or claimed.

A force sensing probe (100) for sensing snap-in and/or pull-off force of a liquid droplet (111) brought into and/or separated from contact with a hydrophobic sample surface (151), respectively, comprises: a sensing tip (101); a sensor element (102) connected to the sensing tip, capable of sensing sub-micronewton forces acting on the sensing tip in a measurement direction; and a droplet holding plate (104) having a first main surface (105) and a hydrophilic second main surface (106) connected via a peripheral edge surface (107), and being attached via the first main surface to the sensing tip (101) perpendicularly relative to the measurement direction for receiving and holding a liquid droplet (111) as attached to the second main surface; the droplet holding plate comprising an electrically conductive surface layer (115), the first and the second main surfaces and the peripheral edge surface being defined by the surface layer.

A method for determining properties of different cation exchange sites in a rock core sample, at a preserved state of the rock core sample may include providing a rock core sample that includes a plurality of indigenous exchangeable cations adsorbed onto the cation exchange sites, a plurality of cation exchange sites occupied by a crude oil, and one or more fluids occupying pore spaces in the rock core sample; subjecting the rock core sample to a plurality of coreflooding steps, the plurality of coreflooding step displacing the plurality of indigenous exchangeable cations, the crude oil, and the one or more fluids in at least three separate coreflooding steps to render the rock core sample clean of native components; determining an amount of indigenous exchangeable cations adsorbed onto the cation exchange sites; subjecting the rock core sample clean of native components to a plurality of coreflooding steps to determine a total amount of exchangeable cations adsorbed onto the cation exchange sites when the rock core sample is clean of native components; and determining at least one property of different cation exchange sites in the rock core sample at the preserved state based on the amount of indigenous exchangeable cations and the total amount of exchangeable cations.

A method for determining properties of different cation exchange sites in a rock core sample, at a preserved state of the rock core sample may include providing a rock core sample that includes a plurality of indigenous exchangeable cations adsorbed onto the cation exchange sites, a plurality of cation exchange sites occupied by a crude oil, and one or more fluids occupying pore spaces in the rock core sample; subjecting the rock core sample to a plurality of coreflooding steps, the plurality of coreflooding step displacing the plurality of indigenous exchangeable cations, the crude oil, and the one or more fluids in at least three separate coreflooding steps to render the rock core sample clean of native components; determining an amount of indigenous exchangeable cations adsorbed onto the cation exchange sites; subjecting the rock core sample clean of native components to a plurality of coreflooding steps to determine a total amount of exchangeable cations adsorbed onto the cation exchange sites when the rock core sample is clean of native components; and determining at least one property of different cation exchange sites in the rock core sample at the preserved state based on the amount of indigenous exchangeable cations and the total amount of exchangeable cations.

Systems, methods, and apparatus for a three-dimensional (3D)-printed vessel for wettability assessment of fracturing proppants are disclosed. The vessel includes a base component including a threaded cylindrical portion extending outward from a first side of the base component. The cylindrical portion has a particular thread profile. The base component defines a cavity sized to contain a proppant sample. A cap is configured to be screwed onto the threaded cylindrical portion after the proppant sample is injected into the cavity. A surface of the cap is shaped to flatten a proppant surface of the proppant sample. The cap is threaded with the particular thread profile. A pin is configured to be partially screwed onto a second side of the base component before the proppant sample is injected into the cavity. The second side is opposite to the first side. Other embodiments may be described or claimed.

Systems, methods, and apparatus for a three-dimensional (3D)-printed vessel for wettability assessment of fracturing proppants are disclosed. The vessel includes a base component including a threaded cylindrical portion extending outward from a first side of the base component. The cylindrical portion has a particular thread profile. The base component defines a cavity sized to contain a proppant sample. A cap is configured to be screwed onto the threaded cylindrical portion after the proppant sample is injected into the cavity. A surface of the cap is shaped to flatten a proppant surface of the proppant sample. The cap is threaded with the particular thread profile. A pin is configured to be partially screwed onto a second side of the base component before the proppant sample is injected into the cavity. The second side is opposite to the first side. Other embodiments may be described or claimed.

A method of estimating a wettability characteristic of a rock material includes acquiring a plurality of T2 distributions based on nuclear magnetic resonance (NMR) measurements of a rock material under a plurality of fluid saturated rock conditions, constructing a measurement matrix based on the plurality of T2 distributions, and performing non-negative factorization of the measurement matrix to determine feature components. The method also includes reconstructing the plurality of T2 distributions based on the feature components, and extracting a first set of T2 distributions associated with mobile water under a wetting condition and a second set of T2 distributions associated with mobile water under a non-wetting condition based on the feature components, and calculating a wettability index (WI) based on the first extracted set of T2 distributions and the second extracted set of T2 distributions.

A method of estimating a wettability characteristic of a rock material includes acquiring a plurality of T2 distributions based on nuclear magnetic resonance (NMR) measurements of a rock material under a plurality of fluid saturated rock conditions, constructing a measurement matrix based on the plurality of T2 distributions, and performing non-negative factorization of the measurement matrix to determine feature components. The method also includes reconstructing the plurality of T2 distributions based on the feature components, and extracting a first set of T2 distributions associated with mobile water under a wetting condition and a second set of T2 distributions associated with mobile water under a non-wetting condition based on the feature components, and calculating a wettability index (WI) based on the first extracted set of T2 distributions and the second extracted set of T2 distributions.

A method of assessing the effect of a production chemical on the stability of a water and oil emulsion, the emulsion comprising the production chemical, is provided. The method comprises: applying a potential difference across the emulsion at a detection site; measuring a current flowing through the emulsion due to the applied potential difference; and using this measured current to assess the effect of the production chemical. The step of using the measured current to assess the effect of the production chemical may comprise determining, based on the measured current, whether a critical potential of the emulsion has been reached or exceeded. The emulsion may be a crude oil emulsion. It may be a water-in-oil emulsion. The production chemical may be an emulsion breaker. Also provided is an apparatus for assessing the effect of a production chemical on a water and oil emulsion.