Components and structures for a rechargeable electrochemical cell and an electrochemical cell having an S02 solvent based electrolyte comprising any of said components and structures are provided. The cathode (2) may comprise one or more elemental transition metals and/or one or more partially oxidized transition metals. The S02 solvent based electrolyte (3) may comprise halide-containing salt additive as an SEI-forming additive. The anode current collector (5) may comprise a carbon coated metal, an alloy of two or more metals or a carbon coated alloy of two or more metals. The electrochemical cell may comprise excess non-dissolved/solid alkali halides. The components, structures and cell may bay used in a device.

A laminate structure includes a substrate; a first layer provided on a first surface of the substrate; and a second layer provided on a second surface of the substrate. The first layer includes a first end portion and a second end portion along a width direction of the substrate, the second layer includes a third end portion and a fourth end portion along the width direction of the substrate, the first end portion is opposite to the third end portion, the second end portion is opposite to the fourth end portion. An end surface of the third end portion includes an inclined surface or a stair shape or a combined shape of the inclined surface and the stair shape.

A porous body includes a framework having a three-dimensional network structure, the framework having a body including crystal grains including nickel and cobalt as constituent elements, the cobalt having a proportion in mass of 0.2 or more and 0.8 or less with respect to a total mass of the nickel and the cobalt, the crystal grains having a shorter grain diameter of 2 μm or more, as determined in a first observed image obtained by observing the body of the framework in cross section at a magnification of 200 times.

A method of preparing a composite positive electrode active material for a lithium secondary battery includes surface-treating a nickel-based active material using carbon dioxide to form a lithium carbonate layer on the surface of the nickel-based active material, mixing the nickel-based active material having the lithium carbonate layer on the surface thereof with a metal precursor including at least one metal selected from cobalt (Co), aluminum (Al), magnesium (Mg), and gallium (Ga) to prepare a mixture, and heat-treating the mixture. A composite positive electrode active material for a lithium secondary battery may be obtained according to the method; and used in a positive electrode for a lithium secondary battery.

The present disclosure provides an electrochemical cell that cycles lithium ions. The electrochemical cell includes a positive electrode and a negative electrode. The positive electrode includes a positive electroactive material and a lithiation additive blended with the positive electroactive material. The lithiation additive includes a lithium-containing material and one or more metals. The lithium-containing material is represented by LiX, where X is hydrogen (H), oxygen (O), nitrogen (N), fluorine (F), phosphorous (P), or sulfur (S). The one or more metals are selected from the group consisting of: iron (Fe), copper (Cu), cobalt (Co), manganese (Mn), and combinations thereof. The negative electrode may include a volume-expanding negative electroactive material.

A hydrothermal synthesis for LiFePO.sub.4 is provided. First, each raw material solution is prepared using a degassed water in advance, second, those solution are mixed by dripping in a fixed order, and then those materials are reacted in a hydrothermal synthesis, so that LiFePO.sub.4 is obtained in a predesigned form.

A main object of the present disclosure is to provide an active material wherein a volume variation due to charge/discharge is small. The present disclosure achieves the object by providing an active material comprising a silicon clathrate II type crystal phase, including a void inside a primary particle, and a void amount of the void with a fine pore diameter of 100 nm or less is 0.05 cc/g or more and 0.15 cc/g or less.

In various embodiments, a solid oxide fuel cell features a functional layer for reducing interfacial resistance between the cathode and the solid electrolyte.

A metal oxide nanocomposite including metal oxide nanoparticles distributed over a carboxymethyl cellulose (CMC) shell. The metal oxide nanoparticles include at least one metal oxide nanoparticle selected from nickel oxide nanoparticles and cobalt oxide nanoparticles. A working electrode can be modified with the metal oxide nanocomposite to provide a nanohybrid electrode. The nanohybrid electrode can be effectively used in urea fuel cells (UFCs) to achieve electrochemical oxidation of urea.

The present disclosure generally relates to various electrodes suitable for electrochemical devices such as batteries, capacitors, sensors, condensers, electrochromic elements, photoelectric conversion elements, etc. Some embodiments are generally directed to electrode materials surrounded by electrolyte, e.g., filling in porous spaces within the electrode. For example, one aspect is generally directed to an electrochemical device comprising an electrode comprising particles. Some or all of the particles may be surrounded by an electrolyte, such as a solid electrolyte. Other aspects of the invention are generally directed to devices including such electrodes, methods of making or using such electrodes, kits including such electrodes, or the like.