The present invention is directed at intercalative metal oxide/conductive polymer composites suitable for use as electrode materials for rechargeable batteries. The composites can be prepared by agitation of the metal oxide and the conductive polymer in aqueous media. The present invention is also directed at a sodium rich layered manganese oxide hydrate prepared by annealing manganese (II, III) oxide and sodium hydroxide. The sodium rich manganese (III, IV) oxide so formed indicates an enhanced capacity for Na-ion storage suitable for the use of electrode materials for aqueous energy storage.

A lattice energy converter (LEC) is disclosed that produces ionizing radiation and/or electricity based on the thermal energy in the lattice of a specially prepared working electrode comprised in whole or in part of hydrogen host materials that are occluded with hydrogen or the isotopes of hydrogen and wherein the hydrogen host materials may include vacancies, superabundant vacancies, and other lattice defects. When the hydrogen host material is occluded with hydrogen, the LEC was found to self-initiate the production of ionizing radiation and, when the hydrogen host materials are in fluidic contact with a gas or vapor containing hydrogen or isotopes of hydrogen, the LEC was found to self-sustain the production of ionizing radiation. When the LEC includes one or more additional electrodes or electrode structures, the ionizing radiation was found to be converted to electrical energy. Materials that are normally considered to be radioactive are not required.

A lattice energy converter (LEC) is disclosed that produces ionizing radiation and/or electricity based on the thermal energy in the lattice of a specially prepared working electrode comprised in whole or in part of hydrogen host materials that are occluded with hydrogen or the isotopes of hydrogen and wherein the hydrogen host materials may include vacancies, superabundant vacancies, and other lattice defects. When the hydrogen host material is occluded with hydrogen, the LEC was found to self-initiate the production of ionizing radiation and, when the hydrogen host materials are in fluidic contact with a gas or vapor containing hydrogen or isotopes of hydrogen, the LEC was found to self-sustain the production of ionizing radiation. When the LEC includes one or more additional electrodes or electrode structures, the ionizing radiation was found to be converted to electrical energy. Materials that are normally considered to be radioactive are not required.

A method of pre-lithiating an electrode for a secondary battery, the method including: a first step of bringing a lithium metal into direct contact with an electrode in an electrolyte and applying pressure to the electrode to prepare a pre-lithiated electrode; and a second step of removing the lithium metal and then applying pressure to the pre-lithiated electrode to perform a stabilization process. The electrode for the secondary battery after going through the pre-lithiation can relieve volume change of the electrode and reduce contact loss of the electrode.

This application describes an electrode material comprising particles of an electrochemically active material dispersed in a polymer binder, where the polymer binder is an acidic polymer or a mixture comprising a binder soluble in an aqueous solvent or a non-aqueous solvent (e.g. NMP) and an acidic polymer. The application also further relates to processes for the preparation of the electrode material and electrodes containing the material, as well as to the electrochemical cells and their use.

The present disclosure relates to a method of making core-shell and yolk-shell nanoparticles, and to electrodes comprising the same. The core-shell and yolk-shell nanoparticles and electrodes comprising them are suitable for use in electrochemical cells, such as fluoride shuttle batteries. The shell may protect the metal core from oxidation, including in an electrochemical cell. In some embodiments, an electrochemically active structure includes a dimensionally changeable active material forming a particle that expands or contracts upon reaction with or release of fluoride ions. One or more particles are at least partially surrounded with a fluoride-conducting encapsulant and optionally one or more voids are formed between the active material and the encapsulant using sacrificial layers or selective etching. The fluoride-conducting encapsulant may comprise one or more metals. When the electrochemically active structures are used in secondary batteries, the presence of voids can accommodate dimensional changes of the active material.

The disclosure relates to a complexed iodine-based electrolyte, a redox flow battery comprising the complexed iodine-based electrolyte, and a method for producing the redox flow battery.

High-performance flexible batteries are promising energy storage devices for portable and wearable electronics. The major obstacle to develop flexible batteries is the shortage of flexible electrodes with excellent electrochemical performance. Another challenge is the limited progress in the flexible batteries beyond Li-ion because of safety concerns for the Li-based electrochemical system. Accordingly, a self-supported tin sulfide (SnS) porous film (PF) was fabricated as a flexible cathode material in Al-ion battery, which delivers a high specific capacity of 406 mAh/g. A capacity decay rate of 0.03% per cycle was achieved, indicating a good stability. The self-supported and flexible SnS film also shows an outstanding electrochemical performance and stability during dynamic and static bending tests. Microscopic images demonstrated that the porous structure of SnS is beneficial for minimizing the volume expansion during charge/discharge. This leads to an improved structural stability and superior long-term cyclability.

A method for forming an anode of a sodium ion battery includes a step of heat treating the red phosphorus precursor and reduced graphene oxide powder at a first temperature that vaporizes the red phosphorus precursor such that red phosphorus structures grow on the reduced graphene oxide powder. Another method for forming an anode of a sodium ion battery includes steps of placing a red phosphorus precursor and a graphene oxide precursor in a reaction chamber; establishing a reducing environment in the reaction chamber; and heating the red phosphorus precursor and a graphene oxide precursor to a first temperature that is sufficient temperature to form a composite of red phosphorus and reduced graphene oxide. Characteristically, red phosphorus deposition and graphene oxide reduction are completed simultaneously in a single-step heat treatment. A method for making a black phosphorus-composite for sodium-ion batter anodes is also provided.

A method of producing a powder mass for a lithium battery, the method comprising: (a) providing a solution containing a sulfonated elastomer dissolved in a solvent or a precursor in a liquid form or dissolved in a solvent; (b) dispersing a plurality of particles of a cathode active material in the solution to form a slurry; and (c) dispensing the slurry and removing the solvent and/or polymerizing/curing the precursor to form the powder mass, wherein the powder mass comprises multiple particulates and at least a particulate comprises one or a plurality of particles of a cathode active material being encapsulated by a thin layer of sulfonated elastomer having a thickness from 1 nm to 10 μm, a fully recoverable tensile strain from 2% to 800%, and a lithium ion conductivity from 10.sup.−7 S/cm to 5×10.sup.−2 S/cm at room temperature.