A flexible, asymmetric electrochemical cell comprising: (A) A sheet of graphene paper as first electrode comprising nano graphene platelets having a platelet thickness less than 1 nm, wherein the first electrode has electrolyte-accessible pores; (B) A thin-film or paper-like first separator and electrolyte; and (C) A thin-film or paper-like second electrode which is different in composition than the first electrode; wherein the separator is sandwiched between the first and second electrode to form a flexible laminate configuration. The asymmetric supercapacitor cells with different NGP-based electrodes exhibit an exceptionally high capacitance, specific energy, and stable and long cycle life.

Provided is a metal-air battery including a cathode having a space which may be filled with a metal oxide formed during a discharge of the metal-air battery and thus having improved energy density and lifespan. The cathode for the metal-air battery includes a plurality of cathode materials, a plurality of electrolyte films disposed on surfaces of the plurality of cathode materials, and a plurality of spaces which are not occupied by the plurality of cathode materials and the plurality of electrolyte films. A volume of the plurality of spaces may be greater than or equal to a maximum space of a metal oxide formed during a discharge of the metal-air battery.

An electrochemical device including a housing and a stack of electrochemical cells in the housing. Each electrochemical cell includes an anode electrode, a cathode electrode, a separator located between the anode electrode and the cathode electrode and an electrolyte. The electrochemical device also includes a current collector located between adjacent electrochemical cells, an anode bus operatively connected to the anodes of the electrochemical cells in the stack and a cathode bus operatively connected to the cathodes of the electrochemical cells in the stack. The housing, the anode electrode, the cathode electrode, the separator, the anode bus and the cathode bus are non-metallic.

The invention relates to a rechargeable battery includes a first electrode, a second electrode, a separator, and electrolyte. The first electrode includes a first supercapacitor electrode, a first battery electrode, a first current collector, and a first connector. The first battery electrode is sandwiched between the first supercapacitor electrode and the first current collector. The first supercapacitor electrode and the first current collector are electrically connected via the first connector.

A supercapacitor to be submerged in a medium containing a biological material and an oxidant, wherein the anode comprises a first enzyme that can catalyse the oxidation of the biological material and the cathode comprises a second enzyme that can catalyse the reduction of the oxidant, and wherein each of the anode and cathode electrodes consists of a solid agglomerate of a conductive material mixed with the first or the second enzyme, said agglomerate having a specific surface that is larger than or equal to 20 m.sup.2/g and an average pore size varying between 0.7 nm and 10 pm.

Carbon nanosheets fabricated by carbonization and activation or by carbonization alone. The nanosheets possess a disordered structure for copious reversible binding of ions at the carbon defects. They are also hierarchically micro-meso-macro porous, allowing facile ion transport at high rates both through the pore-filling electrolyte and in the solid-state. Also, a combined batterysupercapacitor energy storage device using the carbon nanosheets as one or both of the electrodes therein. Tuning the mass-loading ratio of the carbon nanosheets in the two electrodes configures the carbon nanosheets to operate either as a bulk insertion electrode (anode) or a surface adsorption electrode (cathode). The energy storage device may further include a housing with a form factor of a commercial battery.

A charge storage device and system comprises an anode assembly and a cathode assembly, each of the assemblies comprising a charge storage layer of a conjugated polymer material, wherein the conjugated polymer material of the charge storage layer of the cathode assembly is air stable and non-ionic in its discharged state, and wherein the conjugated polymer material of the charge storage layer of the anode assembly includes is air stable and non-ionic in its discharged state. The polymer materials are fully conjugated along the main chain, and are made by processes that do not involve oxidative or electrochemical polymerisation. The charge storage layers are formed from solutions of these polymers, and are amorphous and continuous.

A composite membrane including ion conductive inorganic particles; and a polymer layer, wherein the ion conductive inorganic particles penetrate the polymer layer. Also, a preparation method thereof, and a lithium-air battery including the composite membrane.

Embodiments provide a hybrid supercapacitor exhibiting high energy and power densities enabled by a high-performance lithium-alloy anode coupled with a porous carbon cathode in an electrolyte containing lithium salt. Embodiments include a size reduced silicon oxide anode, a boron-doped silicon oxide anode, and/or a carbon coated silicon oxide anode, which may improve cycling stability and rate performance. Further embodiments include a hybrid supercapacitor system using a Li-active anode in an electrolyte including LiPF6 in a mixture of ethylene carbonate, diethyl carbonate, and dimethyl carbonate (EC:DEC:DMC, 2:1:2 by vol.) and 10 wt % fluoroethylene carbonate (FEC), which may reduce the self-discharge rate.

An air-cathode battery includes a porous cathode current collector with an air interface, an ionic liquid electrolyte disposed in pores of the porous cathode current collector; a metal anode, and a separator in contact with the ionic liquid electrolyte and coupled between the porous cathode current collector and the metal anode. The porous cathode current collector is an ionogel formed from a silica sol-gel or a carbonized resorcinol-formaldehyde aerogel and the pores are functionalized with a thiol group-containing species that is functionalized with one or more catalytic nanoparticles or the pores are electroplated with catalytic metal.