The present invention describes a processes, systems, and catalysts for the conversion of carbon dioxide and water and electricity into low carbon or zero carbon high quality fuels and chemicals. In one aspect, the present invention provides an integrated process for the conversion of a feed stream comprising carbon dioxide to a product stream comprising hydrocarbons between 5 and 24 carbon atoms in length.

A reverse water-gas shift catalyst that can be used at a high temperature is obtained, and a production method thereof is obtained. The reverse water-gas shift catalyst is obtained by at least supporting one or both of nickel and iron as a catalytically active component on a carrier containing a ceria-based metal oxide or a zirconia-based metal oxide as a main component, and a ratio of the carrier to the entire catalyst is 55% by weight or more.

As a hydrocarbon production system that synthesizes hydrocarbons using water and carbon dioxide as raw materials, a hydrocarbon production system capable of producing hydrocarbons by securing hydrogen and carbon monoxide required for hydrocarbon synthesis is provided. In a hydrocarbon production system that produces hydrocarbons from at least water and carbon dioxide, the hydrocarbon production system includes at least an electrolytic reaction unit, a reverse water-gas shift reaction unit, and a hydrocarbon synthesis reaction unit.

The present invention relates to a novel heterogeneous catalyst for selective carbon dioxide methanation reaction having high activity and long-term stability, wherein the catalyst comprising of at least one alkali promoter metal, active metals selected from Nickel and Iron and a stable support for active metals having combination of CeO.sub.2 \-γAl.sub.2O.sub.3.Further, the present invention provides a process for synthesis of said catalyst. Secondly, the present invention also provides a sustainable process for synthesis of methane using said novel heterogenous catalyst. The benefits of present invention are that it provides a sustainable CO.sub.2 methanation process as the novel outstanding catalyst having high performance and long-term stability and totally eliminates catalyst regeneration or reloading step due to its very long-term stability for > 1000 h.

A plant, such as a hydrocarbon plant, is provided, which consists of a syngas stage for syngas generation and a synthesis stage where said syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular CO.sub.2 and H.sub.2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.

A process of catalytically dehydrogenating an alkane to an alkene, using Cr.sub.2O.sub.3 as a catalyst, where the catalyst is oxidized to CrO.sub.3 during the dehydrogenation, and is regenerated by using CO as a reducing gas. In regenerating the catalyst with CO, CO.sub.2 is produced, which may be fed to a dehydrogenation reactor with the alkane and reacted with H.sub.2 produced by the dehydrogenation, to form CO and H.sub.2O by the reverse water-gas shift reaction.

Traditional residential and industrial furnace systems convert the chemical energy of liquid and gas fuels into thermal energy and, in some earlier applications, also into electric energy. This process is driven by a burner specifically designed and built. Often these systems operate at high temperatures, high pressures and relatively lower efficiency levels. The field of present invention generally relates to furnaces that combine the fuel production to the both thermal either electrical energy production. More particularly, the present invention produces a combustible gas that, within the internal workings of the present invention, and can efficiently be burned without the production of high levels of pollutants, at relatively lower temperatures and pressures. The foregoing characteristics, along with the limited size of the elements needed to practice the present invention, make it conducive for use as and in connection with, among other things, residential furnaces and other heating systems, including, for example, heat exchangers and residential hot water tanks. In short, the present invention involves the production of a combustible fuel gas, thermal and electric energy. This production is accomplished through the interconnected use of water electrolysis, catalysts, storage means, regulation, and mean of reusing materials to increase production efficiencies.

The invention relates to a process for the parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product, wherein one or more hydrocarbons are thermally decomposed and at least part of the pyrolysis gas formed is taken off from the reaction zone of the decomposition reactor at a temperature of from 800 to 1400° C. and reacted with carbon dioxide to form a gas mixture comprising carbon monoxide and hydrogen (synthesis gas).

A process for converting carbon dioxide and hydrogen into a product stream comprising carbon monoxide, water and hydrogen by introducing carbon dioxide, hydrogen and oxygen into a reaction vessel, and performing a reverse water gas shift reaction at elevated temperature, wherein (a) no catalyst is present in vessel (b) gas stream comprising carbon dioxide, a hydrogen and an oxygen rich gas stream are introduced into the vessel in separate feed streams, (c) the hydrogen and oxygen rich gas stream being introduced in close vicinity of each other, via burner comprising coaxial channels wherein gases gas undergo a combustion reaction, providing the heating energy required for the reverse water-gas shift reaction; and (d) the temperature in vessel is in the range of 1000 to 1500° C. by varying the molar ratio of hydrogen to oxygen.

It is useful in reducing the carbon footprint of certain industrial technologies, and in production of synthesis gas.

A method and catalyst for forming higher carbon number products from carbon dioxide is provided. An exemplary catalyst includes red mud including iron and aluminum, and impregnated potassium.