Patent classifications
B01J27/00
Phosphorus-doped tubular carbon nitride micro-nano material and application thereof in catalytic treatment of exhaust gas
The invention discloses a phosphorus-doped tubular carbon nitride micro-nano material and application thereof in waste gas treatment. Melamine is partially hydrolyzed into cyanuric acid through a phosphorous acid-assisted hydrothermal method to form a melamine-cyanuric acid super molecular precursor; the center of the precursor starts to be pyrolyzed under heating calcination, and thus phosphorus-doped tubular carbon nitride is obtained; the phosphorus-doped tubular carbon nitride and sodium borohydride are mixed and subjected to low-temperature calcination in an inert gas atmosphere, and defect-modified phosphorus-doped tubular carbon nitride is obtained. The defect-modified phosphorus-doped tubular carbon nitride micro-nano material has a good photocatalytic effect on catalytic degradation of waste gas; besides, the production raw materials are abundant and easy to obtain, and the phosphorus-doped tubular carbon nitride micro-nano material is good in stability and recyclable and has application prospects in waste gas treatment.
Molybdenum sulfide, method for producing same, and hydrogen generation catalyst
Provided is a molybdenum sulfide that is ribbon-shaped and particularly suitable for a hydrogen generation catalyst. Disclosed are a ribbon-shaped molybdenum sulfide, in which 50 particles as measured by observation with a scanning electron microscope (SEM) have a shape of, on average, 500 to 10000 nm in length, 10 to 1000 nm in width, and 3 to 200 nm in thickness; a method for producing the ribbon-shaped molybdenum sulfide, including: (1) heating a molybdenum oxide at a temperature of 200 to 1000° C. in the presence of a sulfur source; or (2) heating a molybdenum oxide at a temperature of 100 to 800° C. in the absence of a sulfur source, and then heating the molybdenum oxide at a temperature of 200 to 1000° C. in the presence of a sulfur source; and a hydrogen generation catalyst including the ribbon-shaped molybdenum sulfide.
Preparation of mesoporous silica supported NiMoS catalysts for hydrodesulfurization application
A method of making a hydrodesulfurization catalyst having nickel and molybdenum sulfides deposited on a support material containing mesoporous silica that is optionally modified with zirconium. The method of making the hydrodesulfurization catalyst involves a single-step calcination and reduction procedure. The utilization of the hydrodesulfurization catalyst in treating a hydrocarbon feedstock containing sulfur compounds (e.g. dibenzothiophene, 4,6-dimethyldibenzothiophene) to produce a desulfurized hydrocarbon stream is also provided.
Silica-coated alumina activator-supports for metallocene catalyst compositions
Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.
Silica-coated alumina activator-supports for metallocene catalyst compositions
Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.
Composite photocatalyst structure, and photocatalytic filter and air purification device including the same
A composite photocatalyst, a photocatalytic filter for air purification, and an air purification device that includes the photocatalytic filter. The composite photocatalyst includes: a first metal oxide particle; and second metal oxide particles arranged on a surface of the first metal oxide particle, wherein specific surface area of the second metal oxide particles is greater than specific surface area of the first metal oxide particle, and bandgap energy of the second metal oxide particles is greater than bandgap energy of the first metal oxide particle. The composite photocatalyst structure may degrade and remove gaseous pollutants under room temperature and atmospheric pressure conditions. The composite photocatalyst may be applied to various indoor and outdoor air purification systems in the form of a photocatalytic filter.
Silica-Coated Alumina Activator-Supports For Metallocene Catalyst Compositions
Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.
Method and catalyst for producing methylbenzyl alcohol from ethanol by catalytic conversion
Method and catalyst for producing methylbenzyl alcohol from ethanol by catalytic conversion. A route and corresponding catalysts for directly producing methylbenzyl alcohols through catalytic conversion starting from ethanol, providing an important alternative route for increasing the production of aromatic oxygenates. The selectivity of the methylbenzyl alcohols is up to 60%. At the same time, the prepared catalysts have excellent stability. Moreover, this innovative reaction route produces hydrogen as co-product without CO, thus can be directly used in chemical reactions and fuel cells. In addition, the route also produces high carbon number alcohols which can be used as fuels or oil additives to partially replace petroleum-based products, thus partly reducing the dependence on petroleum.
Silica-coated alumina activator-supports for metallocene catalyst compositions
Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.
Silica-coated alumina activator-supports for metallocene catalyst compositions
Silica-coated alumina activator-supports, and catalyst compositions containing these activator-supports, are disclosed. Methods also are provided for preparing silica-coated alumina activator-supports, for preparing catalyst compositions, and for using the catalyst compositions to polymerize olefins.