A sealer composition includes a first component and a second component. The first component includes water and a hydroxyl functionalized acrylic resin. The second component includes an epoxy silane cross-linker. Characteristically, the first component and second component are mixed at most 40 hours prior to application of the sealer composition to a substrate.

The present invention is directed to an acrylic polymer prepared from a reaction mixture comprising: (i) an ethylenically unsaturated monomer comprising hydroxyl functional groups; (ii) an ethylenically unsaturated monomer comprising polydialkylsiloxane groups; (iii) an ethylenically unsaturated monomer comprising carboxylic acid functional groups or amine functional groups; and (iv) a reactive diluent that is reactive with the ethylenically unsaturated monomer (iii). The reactive diluent (iv) is present initially in the reaction mixture as a medium in which the monomers polymerize. The present invention is further directed to aqueous polymeric dispersions prepared therefrom and aqueous, curable film-forming compositions prepared from the dispersions. The curable film-forming compositions are low VOC and are useful in methods of mitigating dirt build-up on a substrate.

A coating process is described that coats a coil-to-coil continuous substrate with a graphene-like coating. The coating process includes cleaning and activating a substrate, applying a graphene oxide dispersion to the substrate, drying the coated sub-strate, and exposing the dried coating to VUV radiation under a dry atmosphere. The atmosphere for the last step includes one or more inert gases and optionally one or more reactive gases to repair defects in the coating and/or to functionalize the coating. This coating process allows for the formation of a polygranular graphene-like coating intimately in contact with the substrate. The graphene-like coating coats the substrate with multiple monolayers of graphene in a continuous manner.

A method comprising providing a sol comprising a solvent; contacting the sol with a precipitation initiator to initiate precipitation of the sol, wherein the precipitation initiator is different to the solvent; and applying the precipitating sol to a product. The methods of the invention may be used with sols comprising a solvent, a metal alkoxide, and optionally a biopolymer and/or a catalyst, with alkoxides comprising metals, organically modified alkoxides comprising metals, alkoxides comprising metalloids, and organically modified alkoxides comprising metalloids all being encompassed by the term ‘metal alkoxide’. Also disclosed is an apparatus for use in the method comprising a first storage vessel; a second storage vessel; one or more pumps; and one or more delivery means.

A sealer composition includes a first component and a second component. The first component includes water and a hydroxyl functionalized acrylic resin. The second component includes an epoxy silane cross-linker. Characteristically, the first component and second component are mixed at most 40 hours prior to application of the sealer composition to a substrate.

A sealer composition includes a first component and a second component. The first component includes water and a hydroxyl functionalized acrylic resin. The second component includes an epoxy silane cross-linker. Characteristically, the first component and second component are mixed at most 40 hours prior to application of the sealer composition to a substrate.

The present invention is directed to an acrylic polymer prepared from a reaction mixture comprising: (i) an ethylenically unsaturated monomer comprising hydroxyl functional groups; (ii) an ethylenically unsaturated monomer comprising polydialkylsiloxane groups; (iii) an ethylenically unsaturated monomer comprising carboxylic acid functional groups or amine functional groups; and (iv) a reactive diluent that is reactive with the ethylenically unsaturated monomer (iii). The reactive diluent (iv) is present initially in the reaction mixture as a medium in which the monomers polymerize. The present invention is further directed to aqueous polymeric dispersions prepared therefrom and aqueous, curable film-forming compositions prepared from the dispersions. The curable film-forming compositions are low VOC and are useful in methods of mitigating dirt build-up on a substrate.

A coating process is described that coats a coil-to-coil continuous substrate with a graphene-like coating. The coating process includes cleaning and activating a substrate, applying a graphene oxide dispersion to the substrate, drying the coated sub-strate, and exposing the dried coating to VUV radiation under a dry atmosphere. The atmosphere for the last step includes one or more inert gases and optionally one or more reactive gases to repair defects in the coating and/or to functionalize the coating. This coating process allows for the formation of a polygranular graphene-like coating intimately in contact with the substrate. The graphene-like coating coats the substrate with multiple monolayers of graphene in a continuous manner.

The present invention provides: a surface treatment liquid which is capable of performing good hydrophilization or hydrophobization of the surface of an object to be treated even if the surface treatment liquid does not contain a coating film-forming resin; and a surface treatment method which uses this surface treatment liquid, A surface treatment liquid, comprising a resin (A) and a solvent (C), and wherein a resin having a functional group I that is a nitrogen-containing heterocyclic group and a functional group II that is a functional group other than the functional group I and having one or more groups selected from among hydrophilic groups and hydrophobic groups, and comprising a constituent unit (a1) having the functional group I, and one or more constituent units selected from the group consisting of a constituent unit (a2) having a cationic group in a side chain, and a constituent unit (a3) having an anionic group in a side chain, is used as the resin (A).

A coating process is described that coats a coil-to-coil continuous substrate with a graphene-like coating. The coating process includes cleaning and activating a substrate, applying a graphene oxide dispersion to the substrate, drying the coated substrate, and exposing the dried coating to VUV radiation under a dry atmosphere. The atmosphere for the last step includes one or more inert gases and optionally one or more reactive gases to repair defects in the coating and/or to functionalize the coating. This coating process allows for the formation of a polygranular graphene-like coating intimately in contact with the substrate. The graphene-like coating coats the substrate with multiple monolayers of graphene in a continuous manner.