Provided is, a glove production method including: (1) the step of immersing a glove forming mold in a liquid coagulant containing calcium ions so as to allow the coagulant to adhere to the glove forming mold; (2) the dispersion step of leaving a dip molding composition to stand with stirring; (3) the dipping step; (4) the gelling step; (5) the leaching step; (6) the beading step; (7) the precuring step; and (8) the curing step, in which method the steps (3) to (8) are performed in the order mentioned, and the dip molding composition has a specific formulation.

An organic microgel system as support material for 3D printing of soft materials such as silicone and methods for manufacturing and using the organic microgel system are disclosed. In some embodiments, the organic microgel system comprises a plurality of microgel particles formed by blending a di-block copolymer and a tri-block copolymer in an organic solvent. The organic microgel system may allow high precision 3D printing of silicone objects with complex shapes.

The invention provides a composite structure containing a foam layer, an inner layer and an outer layer of a thermoplastic compact cover layer, and a lacquer layer in this order, and having a tensile strength according to DIN EN ISO 527-3 at 2000 mm/min and 23° C. of less than 5 MPa in both a first direction and a second direction perpendicular to the first direction, wherein the density of the foam layer is 40 to 150 kg/m3, the inner layer contains particles of an elastomer (polymer (F)) and at least 50 wt % of a thermoplastic polyolefin (polymer (E)) and is directly bonded to the outer layer, the outer layer differs from the inner layer in its composition and contains the following polymers (A) to (C) in a total amount of 100 parts by weight: 25 to 70 parts by weight of particles of an elastomer (polymer (A)), 0 to 40 parts by weight of a low-density polyethylene (polymer (B)), and 20 to 70 parts by weight of a thermoplastic polyolefin (polymer (C)) other than polymer (B). The invention provides the use of the composite structure in car interiors, in particular as airbag cover, a method for the production of the composite structure.

A thin organic solvent resistant glove (100) is disclosed including: a first polymeric layer (202) in a shape of a glove including at least one of a blend of a polyisobutylene material and a nitrile-butadiene material, or a nitrile-butadiene material; a second polymeric layer (206) in a shape of a glove including at least one of a polyisobutylene material or a blend of a polyisobutylene material and a nitrile-butadiene material, disposed on the first polymeric layer, and a third polymeric layer (212) in a shape of a glove including a nitrile-butadiene material or an acrylic polymer material disposed on the second polymeric layer.

A latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex and a cholate-based emulsifier, wherein the cholate-based emulsifier is included in an amount of 0.02 to 3 parts by weight based on a solid content with respect to a solid content of 100 parts by weight of the carboxylic acid-modified nitrile-based copolymer latex. A method of preparing the latex composition for dip molding and a molded article produced using the same are also provided.

The present disclosure is directed to additive manufacturing cartridges having an oxygen impermeable layer and to processes for producing cured polymeric products by additive manufacturing wherein the oxygen content during additive manufacturing is limited such as by use of the cartridge and/or by use of an inert gas.

The present technology relates to a latex composition for dip molding comprising a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formulas 1 and 2, wherein the carboxylic acid-modified nitrile-based copolymer includes a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, and a molded article.

A thin organic solvent resistant glove is disclosed including: a first polymeric layer in a shape of a glove including at least one of a blend of a polyisobutylene material and a nitrile-butadiene material, or a nitrile-butadiene material; a second polymeric layer in a shape of a glove including at least one of a polyisobutylene material or a blend of a polyisobutylene material and a nitrile-butadiene material, disposed on the first polymeric layer, and a third polymeric layer in a shape of a glove including a nitrile-butadiene material or an acrylic polymer material disposed on the second polymeric layer.

The present invention relates to methods for reprocessing elastomeric films or articles comprising an elastomer film wherein the elastomeric film is made from a polymer latex comprising: (a) particles of a carboxylated conjugated diene nitrile latex polymer (a) obtainable by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers comprising conjugated dienes; monomers selected from ethylenically unsaturated nitrile compounds; ethylenically unsaturated carboxylic acids and/or salts thereof; optionally vinyl aromatic monomers; and optionally alkyl esters of ethylenically unsaturated acids, in combination or association with (b) particles of a latex polymer (b) comprising at least one oxirane-functional group; wherein the monomer composition of the latex polymer (a) is different from the monomer composition of the latex polymer (b) and to the use of the polymer latex to make an elastomeric film obtained from the polymer latex self-healing, repairable and/or recyclable.

Provided herein are curable compositions useful for, among other things, making three-dimensional parts by additive manufacturing. The compositions when cured exhibit a surprising balance of improved tensile strength and percent elongation.