A reactor suitable for a reaction containing an exothermic reaction is provided. The reactor includes the following components. A reaction channel has an inlet and an outlet, and has a front-end reaction zone, middle-end reaction zones, and a back-end reaction zone from the inlet to the outlet. A front-end catalyst support and a front-end catalyst are located in the front-end reaction zone, a middle-end catalyst support and a middle-end catalyst are respectively located in the middle-end reaction zones, and a back-end catalyst support and a back-end catalyst are located in the back-end reaction zone. The concentration of the front-end catalyst is less than the concentration of the back-end catalyst, and the concentration of the middle-end catalyst is decided via a computer simulation of reaction parameters. The reaction parameters include size and geometric shape of the reaction channel.

The present invention provides a semiconductor crystal comprising a semiconductor material having a tuned band gap energy, and methods for preparation thereof. More particularly, the invention provides a semiconductor crystal comprising a semiconductor material and amino acid molecules, peptides, or a combination thereof, incorporated within the crystal lattice, wherein the amino acid molecules, peptides, or combination thereof tune the band gap energy of the semiconductor material.

A composition of matter having the following chemical structure:

[00001]$\left[\frac{H_x{O}_{\left(x-1\right)}}{2}\right]Z_y$ wherein x is and odd integer ≥3; y is an integer between 1 and 20; and Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or a polyatomic ion having a charge between −1 and −3.

A composition of matter having the following chemical structure:

[00001]$\left[\frac{H_x{O}_{\left(x-1\right)}}{2}\right]Z_y$ wherein x is and odd integer ≥3; y is an integer between 1 and 20; and Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or a polyatomic ion having a charge between −1 and −3.

A method of making an alkaline hydronium composition and composition of matter having the following chemical structure:

[H.sub.xO.sub.x-y].sub.mZ.sub.n where x is an integer greater than 3; y is and integer less than x; and wherein the charge value associated with the molecular component is at least −1

A method of making an alkaline hydronium composition and composition of matter having the following chemical structure:

[H.sub.xO.sub.x-y].sub.mZ.sub.n where x is an integer greater than 3; y is and integer less than x; and wherein the charge value associated with the molecular component is at least −1

Improved methods of synthesizing ammonia from hydrogen sulfide and lithium nitrate are disclosed. Specifically, in a continuous cycle, hydrogen sulfide reactant is regenerated from the elemental sulfur that is extracted from a product of the ammonia synthesis, and the regenerated hydrogen sulfide is fed back into the ammonia synthesis reaction. The cycle that regenerates the hydrogen sulfide uses either a water-containing or a water and carbon-containing feedstock to facilitate the regeneration of the hydrogen sulfide from the elemental sulfur.

Diffusion and infusion resistant implantable devices and methods for reducing pulsatile pressure are provided. The implantable device includes a balloon implantable within a blood vessel of a patient, e.g., the pulmonary artery. The balloon is injected with a fluid mixture comprising a constituent fluid(s) and a diffusion-resistant gas to provide optimal balloon volume and limit fluid diffusion throughout multiple cardiac cycles. The fluid mixture may be pressurized such that the balloon is transitionable between an expanded state and a collapsed state responsive to pressure fluctuations in the blood vessel.

Diffusion and infusion resistant implantable devices and methods for reducing pulsatile pressure are provided. The implantable device includes a balloon implantable within a blood vessel of a patient, e.g., the pulmonary artery. The balloon is injected with a fluid mixture comprising a constituent fluid(s) and a diffusion-resistant gas to provide optimal balloon volume and limit fluid diffusion throughout multiple cardiac cycles. The fluid mixture may be pressurized such that the balloon is transitionable between an expanded state and a collapsed state responsive to pressure fluctuations in the blood vessel.

Provided are porous Fe.sub.3O.sub.4/sulfur composites. The composites are composed of porous Fe.sub.3O.sub.4 nanoparticles and sulfur, where the sulfur loading is 70-85% by weight based on the total weight of the composite. Also provided are batteries having cathodes containing porous FE.sub.3O.sub.4 composites of the present disclosure.