The present invention relates to an electrode for a lithium secondary battery, a method for preparing the same, an electrode assembly for a lithium secondary battery comprising the same, and a lithium secondary battery comprising the same, wherein the electrode comprises an electrode active material, an aqueous binder, a compound represented by Formula 1, and a compound represented by Formula 2. Formula 1 and Formula 2 are the same as set forth in the specification. The electrode for a lithium secondary battery improves the physical properties of the aqueous binder in a manner whereby a cross-linking reaction material is combined with the aqueous binder, so that the electrode can improve initial charge/discharge efficiency and the life span of a lithium secondary battery, preferably a lithium sulfur battery, and improve the area capacity of the electrode.

A positive electrode active material having a core/shell structure, which includes a sulfur-carbon composite containing thermally expanded-reduced graphene oxide, a carbon material as a core, and carbon nanotubes as a shell. A method for preparing a positive electrode active material having a core/shell structure for a lithium secondary battery, including the steps of thermally expanding graphene oxide by heat treatment at a temperature in a range of 300° C. to 500° C. to prepare a thermally-expanded graphene oxide. Then, reducing the thermally-expanded graphene oxide by heat treatment at a temperature in a range of 700° C. to 1200° C. to prepare a thermally expanded-reduced graphene oxide. Next, mixing the thermally expanded-reduced graphene oxide and sulfur to prepare a sulfur-carbon composite. Last, mixing the sulfur-carbon composite and carbon nanotubes to form carbon nanotubes on a surface of the sulfur-carbon composite.

A positive electrode material for a free-standing film-type lithium secondary battery, a preparation method thereof, and a lithium secondary battery including the same. More specifically, the positive electrode material is manufactured in the form of a free-standing film. The positive electrode material contains carbon-containing sulfur melt, which is obtained through a dry process using the properties of pressurization, and sulfur exhibits strong self-cohesion and the porous carbon material exhibits flexibility. The positive electrode material may be applied with a high loading amount as a positive electrode, and since it is prepared by a simplified process, process efficiency may be improved in terms of cost and time.

A method for preparing a sulfur-carbon composite including: (a) stirring a porous carbon material in a solvent mixture including a carbonate-based compound and a volatile solvent and then drying; and (b) mixing the dried porous carbon material with sulfur and then depositing the sulfur in and on the porous carbon material by a heat melting method. A method for preparing a sulfur-carbon composite including: (a) mixing and stirring a porous carbon material and sulfur in a solvent mixture including a carbonate-based compound and a volatile solvent and then drying; and (b) depositing the sulfur in and on the porous carbon material by a heat melting method. In the sulfur-carbon composite, sulfur present in and on the porous carbon material, a proportion of β-monoclinic sulfur phase to sulfur contained in the sulfur-carbon composite is 90% or more based on a total molar ratio of sulfur.

A composition of matter having the following chemical structure: $.Math.H_x{O}_{\frac{\left(x-1\right)}{2}}.Math.Z_y$
wherein x is
and odd integer ≥3;
y is an integer between 1 and 20; and
Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or a polyatomic ion having a charge between −1 and −3.

A composition of matter having the following chemical structure: $.Math.H_x{O}_{\frac{\left(x-1\right)}{2}}.Math.Z_y$
wherein x is
and odd integer ≥3;
y is an integer between 1 and 20; and
Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between −1 and −3 or a polyatomic ion having a charge between −1 and −3.

A method of making an alkaline hydronium composition and composition of matter having the following chemical structure:
[H.sub.xO.sub.x-y].sub.mZ.sub.n where x is an integer greater than 3; y is and integer less than x; and wherein the charge value associated with the molecular component is at least −1.

A method of making an alkaline hydronium composition and composition of matter having the following chemical structure:
[H.sub.xO.sub.x-y].sub.mZ.sub.n where x is an integer greater than 3; y is and integer less than x; and wherein the charge value associated with the molecular component is at least −1.

The invention relates to a method for producing a master batch comprising between 0.01 and 50 wt. % of carbonaceous nanofillers and at least one sulphurated material such as elemental sulphur by melt compounding, and to the master batch thus produced and the different uses thereof. The invention also relates to a solid composition comprising carbonaceous nanofillers dispersed in a sulphurated material.

A reactor suitable for a reaction containing an exothermic reaction is provided. The reactor includes the following components. A reaction channel has an inlet and an outlet, and has a front-end reaction zone, middle-end reaction zones, and a back-end reaction zone from the inlet to the outlet. A front-end catalyst support and a front-end catalyst are located in the front-end reaction zone, a middle-end catalyst support and a middle-end catalyst are respectively located in the middle-end reaction zones, and a back-end catalyst support and a back-end catalyst are located in the back-end reaction zone. The concentration of the front-end catalyst is less than the concentration of the back-end catalyst, and the concentration of the middle-end catalyst is decided via a computer simulation of reaction parameters. The reaction parameters include size and geometric shape of the reaction channel.