Patent classifications
C01C3/00
METHOD FOR PRODUCING DOUBLE METAL CYANIDE CATALYSTS
The present invention relates to a method for producing a double metal cyanide (DMC) catalyst, comprising the reaction of an aqueous solution of a cyanide-free metal salt, an aqueous solution of a metal cyanide salt, an organic complex ligand, optionally a complex-forming component to form a dispersion, the dispersion being produced using a mixing nozzle and a peroxide. The invention further relates to double metal cyanide (DMC) catalysts obtainable by means of the method according to the invention and to the use of DMC catalysts to produce polyoxyalkylene polyols.
COMPOSITION INCLUDING I2SCN- IONS AND/OR I(SCN)2- IONS
A stable composition obtained by enzymatic oxidation of a halide thiocyanate mixture, including at least one ion selected from the group of the I2SCN— ions and the I(SCN).sub.2— ions, the composition being free of hypothiocyanite ions. In an embodiment, the composition further includes iodine thiocyanate ISCN. This disclosure also relates to a method for preparing the stable composition and to the uses thereof.
Process of fluorinating inorganic compounds by direct fluorination
The invention relates to a use of a fluorination gas, and the elemental fluorine (F.sub.2) is present in a high concentration, for example, in a concentration of elemental fluorine (F.sub.2), especially of equal to much higher than 15 or even 20% by volume, and to a process for the manufacture of a fluorinated compound by direct fluorination employing a fluorination gas, wherein the elemental fluorine (F.sub.2) is present in a high concentration. The process of the invention is directed to the manufacture of a fluorinated compound, for the exception of fluorinated benzene, by direct fluorination. Especially the invention is of interest in the preparation of fluorinated organic compounds, final products and as well intermediates, for usage in agro-, pharma-, electronics-, catalyst, solvent and other functional chemical applications. The fluorination process of the invention may be performed batch-wise or in a continuous manner.
COMPOSITION INCLUDING I2SCN- IONS AND/OR I(SCN)2- IONS
A stable composition obtained by enzymatic oxidation of a halide thiocyanate mixture, including at least one ion selected from the group of the I2SCN ions and the I(SCN).sub.2 ions, the composition being free of hypothiocyanite ions. In an embodiment, the composition further includes iodine thiocyanate ISCN. This disclosure also relates to a method for preparing the stable composition and to the uses thereof.
Highly active double metal cyanide compounds
The present invention is directed to supported catalyst having utility in the polymerization and co-polymerization of epoxide monomers, said supported catalyst having the general Formula (I):
[DMCC]*b Supp(I) wherein: [DMCC] denotes a double metal cyanide complex which comprises a double metal cyanide (DMC) compound, at least one organic complexing agent and a metal salt; Supp denotes a hydrophobic support material; and, b represents the average proportion by weight of said support material, based on the total weight of [DMCC] and Supp, and is preferably in the range 1 wt. %b99 wt. %.
Method for producing double metal cyanide catalysts
The present invention relates to a method for producing a double metal cyanide (DMC) catalyst, comprising the reaction of an aqueous solution of a cyanide-free metal salt, an aqueous solution of a metal cyanide salt, an organic complex ligand, optionally a complex-forming component to form a dispersion, the dispersion being produced using a mixing nozzle and a peroxide. The invention further relates to double metal cyanide (DMC) catalysts obtainable by means of the method according to the invention and to the use of DMC catalysts to produce polyoxyalkylene polyols.
THIOCYANATE SALTS FOR ANTI-INFLAMMATION
Described herein, inter alia, are thiocyanate salt compositions and methods for treating or preventing inflammation using the same.
COMPOSITION INCLUDING I2SCN-IONS AND/OR I(SCN)2-IONS
A stable composition obtained by enzymatic oxidation of a halide thiocyanate mixture, including at least one ion selected from the group of the I.sub.2SCN.sup. ions and the I(SCN).sub.2.sup. ions, the composition being free of hypothiocyanite ions. In an embodiment, the composition further includes iodine thiocyanate ISCN. Also relates to a method for preparing the stable composition and to the uses thereof.
Method for recovering cyanide from a barren solution
A process is disclosed for recovering cyanide used to leach gold or silver from ore. In the course of leaching gold or silver from ore, a barren solution is generated. A portion of the barren solution containing sodium cyanide is recycled to the cyanidation process while blowdown from the barren solution is subjected to pre-treatment, UV photodissociation and pH adjustment. Ultimately, a volatile hydrocyanic acid is formed and is absorbed into a sodium hydroxide solution through the employment of a gas-filled membrane. This forms sodium cyanide that can be recycled and used in the cyanidation process to leach gold or silver from ore.
UNCONVENTIONAL PHASE HEXAGONAL PRUSSIAN BLUE ANALOGS WITH OPEN STRUCTURES
The present invention relates to a facile synthetic method to synthesize novel hexagonal phase CuCo (HCuCo) PBAs with high crystallinity, as well as extended synthesis of doping PBAs with hexagonal phase: Fe.sub.0.1CuCo, Fe.sub.0.2CuCo, Co.sub.0.1CuCo, Ni.sub.0.1CuCo, and Zn.sub.0.1CuCo. The hexagonal phase HCuCo PBAs and the doping sequence of PBAs with hexagonal phase exhibit superior crystallinity and significantly higher intrinsic specific surface area. Meanwhile, HCuCo PBAs show great potential for gas adsorption and have a positive impact on the development of PBAs for other applications.