C01F11/00

Facile, low-energy routes for the production of hydrated calcium and magnesium salts from alkaline industrial wastes

Divalent ions are extracted from solids by leaching to form a divalent ion-containing solution. The divalent ion-containing solution is subjected to concentration to form a concentrated divalent ion-containing solution. Precipitation of a divalent ion hydroxide salt is induced from the concentrated divalent ion-containing solution. In other cases, the concentrated divalent ion-containing solution is exposed to carbon dioxide to induce precipitation of a divalent ion carbonate salt.

Membrane electrode assembly of electrochemical device, membrane electrode assembly of fuel cell, fuel cell, membrane electrode assembly of electrochemical hydrogen pump, electrochemical hydrogen pump, membrane electrode assembly of hydrogen sensor, and hydrogen sensor

A membrane electrode assembly of an electrochemical device includes a proton conductive solid electrolyte membrane and an electrode including Ni and an electrolyte material which contains as a primary component, at least one of a first compound having a composition represented by BaZr.sub.1-x1M.sup.1.sub.x1O.sub.3 (M.sup.1 represents at least one element selected from trivalent elements each having an ion radius of more than 0.720 A° to less than 0.880 A°, and 0<x.sub.1<1 holds) and a second compound having a composition represented by BaZr.sub.1-x2Tm.sub.x2O.sub.3 (0<x.sub.2<0.3 holds).

Membrane electrode assembly of electrochemical device, membrane electrode assembly of fuel cell, fuel cell, membrane electrode assembly of electrochemical hydrogen pump, electrochemical hydrogen pump, membrane electrode assembly of hydrogen sensor, and hydrogen sensor

A membrane electrode assembly of an electrochemical device includes a proton conductive solid electrolyte membrane and an electrode including Ni and an electrolyte material which contains as a primary component, at least one of a first compound having a composition represented by BaZr.sub.1-x1M.sup.1.sub.x1O.sub.3 (M.sup.1 represents at least one element selected from trivalent elements each having an ion radius of more than 0.720 A° to less than 0.880 A°, and 0<x.sub.1<1 holds) and a second compound having a composition represented by BaZr.sub.1-x2Tm.sub.x2O.sub.3 (0<x.sub.2<0.3 holds).

Method of treating wastewater

A method of treating a waste liquid includes: an aluminum dissolution step of dissolving aluminum in an acidic waste liquid and performing separation into a first treated water and a reduced heavy metal precipitate; a gypsum recovery step of adding a calcium compound to the first treated water at a liquid property of a pH of 4 or less, and performing separation into a second treated water and gypsum; an aluminum and fluorine removal step of adding an alkali to the second treated water and performing separation into a third treated water and a precipitate containing aluminum and fluorine; and a neutralization step of adding an alkali to the third treated water and performing separation into an alkali neutralization treated water and a neutralized precipitate of a heavy metal hydroxide.

BUFFER-FREE PROCESS CYCLE FOR CO2 SEQUESTRATION AND CARBONATE PRODUCTION FROM BRINE WASTE STREAMS WITH HIGH SALINITY

A method includes: (1) using a chelating agent, extracting divalent ions from a brine solution as complexes of the chelating agent and the divalent ions; (2) using a weak acid, regenerating the chelating agent and producing a divalent ion salt solution; and (3) introducing carbon dioxide to the divalent ion salt solution to induce precipitation of the divalent ions as a carbonate salt. Another method includes: (1) combining water with carbon dioxide to produce a carbon dioxide solution; (2) introducing an ion exchanger to the carbon dioxide solution to induce exchange of alkali metal cations included in the ion exchanger with protons included in the carbon dioxide solution and to produce a bicarbonate salt solution of the alkali metal cations; and (3) introducing a brine solution to the bicarbonate salt solution to induce precipitation of divalent ions from the brine solution as a carbonate salt.

Composite hexagonal ferrite materials

Disclosed herein are embodiments of composite hexagonal ferrite materials formed from a combination of Y phase and Z phase hexagonal ferrite materials. Advantageously, embodiments of the material can have a high resonant frequency as well as a high permeability. In some embodiments, the materials can be useful for magnetodielectric antennas.

Composite hexagonal ferrite materials

Disclosed herein are embodiments of composite hexagonal ferrite materials formed from a combination of Y phase and Z phase hexagonal ferrite materials. Advantageously, embodiments of the material can have a high resonant frequency as well as a high permeability. In some embodiments, the materials can be useful for magnetodielectric antennas.

Methods for Forming Silicates of Calcium
20230076896 · 2023-03-09 ·

A method includes forming a reaction bed containing feed agglomerates in a reaction chamber by heating the feed agglomerates. Individual feed agglomerates initially contain particles of a gypsum source and of a silicon source approximately homogeneously distributed throughout the individual agglomerates. The gypsum and silicon in the feed agglomerates react during the heating in the reaction chamber and, thereby, form processed agglomerates that contain silicates of calcium and an increased amount of amorphous silicon compared to the feed agglomerates before the heating. The method includes generating off gas from the reaction bed, the off gas containing oxides of sulfur, and removing the processed agglomerates from the reaction chamber.

Oxide ion conductor and electrochemical device

An oxide ion conductor has a X.sub.3Z.sub.2(TO.sub.4).sub.3 structure, where X is a divalent metal element, Z is a trivalent metal element, and T is a tetravalent metal element, and has a composition expressed by (X.sub.1-xA.sub.x).sub.3(Z.sub.1-yB.sub.y).sub.2(T.sub.1-zC.sub.z).sub.3O.sub.12+δ where the element X is Ca, Fe, Gd, Ba, Sr, Mn, and/or Mg, the element Z is Al, Cr, Fe, Mn, V, Ga, Co, Ni, Ru, Rh, and/or Ir, the element T is Si and/or Ge, an element A is La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and/or Sr, an element B is Zn, Mn, Co, Ru, and/or Rh, and an element C is Si, Al, Ga, and/or Sn, 0≤x≤0.2, 0≤y≤0.2, and 0≤z≤0.2 are satisfied, and δ is a value securing electrical neutrality.

FACILE, LOW-ENERGY ROUTES FOR THE PRODUCTION OF HYDRATED CALCIUM AND MAGNESIUM SALTS FROM ALKALINE INDUSTRIAL WASTES

Divalent ions are extracted from solids by leaching to form a divalent ion-containing solution. The divalent ion-containing solution is subjected to concentration to form a concentrated divalent ion-containing solution. Precipitation of a divalent ion hydroxide salt is induced from the concentrated divalent ion-containing solution. In other cases, the concentrated divalent ion-containing solution is exposed to carbon dioxide to induce precipitation of a divalent ion carbonate salt.