The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li.sub.7La.sub.3Zr.sub.2O.sub.12.

The present invention relates to a positive electrode active material and a lithium secondary battery comprising the same.

Coated zirconia fine particle containing a zirconia fine particle and a coating layer coating the surface of the fine particle. The coating layer includes one or more metal elements selected from Mg, Ca, Al and rare-earth elements, and the coated zirconia fine particle has an average particle size of 3 to 100 nm and a specific surface area of 20 to 500 m.sup.2/g.

The present disclosure relates to a method for preparing a ceria-zirconia composite oxide, a ceria-zirconia composite oxide, and a catalyst including the same.

There is provided a secondary battery including a cathode, an anode including an anode active material layer and a coating film, and an electrolytic solution. The anode active material layer includes a titanium-containing compound, and a surface of the anode active material layer is coated with the coating film. The electrolytic solution includes one or more of unsaturated cyclic carbonate esters. Porosity of a portion of the anode active material layer measured with use of a mercury intrusion technique is within a range from 30% to 50% both inclusive. The portion of the anode active material layer is cut together with a portion of the coating film from a surface of the coating film to a depth of 10 μm.

The present invention relates to a mixed oxide of aluminium, of zirconium, of cerium, of lanthanum and optionally of at least one rare-earth metal other than cerium and lanthanum that makes it possible to repair a catalyst that retains, after severe ageing, a good thermal stability and a good catalytic activity. The invention also relates to the process for preparing this mixed oxide and also to a process for treating exhaust gases from internal combustion engines using a catalyst prepared from this mixed oxide.

A proton conductor of the present disclosure includes a compound represented by the chemical formula BaZr.sub.(1-x-y)Yb.sub.xSc.sub.yO.sub.3-δ. The chemical formula satisfies 0<x<0.5, 0 <y<0.5, (x+y)<0.5, and 0<δ<0.5.

An electrode material of the present disclosure is an electrode material that includes a compound represented by the chemical formula BaZr.sub.1-x-yM.sub.xCo.sub.yO.sub.3-δ. M is In or Yb, and the chemical formula satisfies 0<x<1, 0<y<1, 0<(x+y)<1, and 0<δ<1. A membrane electrode assembly of the present disclosure includes a first electrode including the electrode material, and an electrolyte membrane provided on a first main surface of the first electrode.

An object of the present invention is to provide a hydrogen permeable material having excellent hydrogen permeability. Another object of the present invention is to provide a composite member and a fuel cell including the hydrogen permeable material. The hydrogen permeable material comprises a perovskite type compound represented by the following general formula (1a). In another embodiment, the hydrogen permeable material comprises a hydrogen-containing perovskite type compound, which is the perovskite type compound represented by the general formula (1a) with introduced hydride ion (H.sup.−). Wherein M is at least one alkaline earth metal selected from the group consisting of Ba, Sr and Ca, x is a numerical value of 0 or more and 0.3 or less, y is a numerical value of more than 0 and 0.75 or less, w is a value at which an average valence of In is +1.0 or more and +2.5 or less, and y≥w.

M.sub.1-xZr.sub.1-yIn.sub.yO.sub.3-x-0.5y-2  (1a)

The problem to be solved by the present invention is to provide an oxygen storage and release material comprising a ceria-zirconia-based complex oxide improved in ability to remove HC and NOx and a three-way catalyst able to reduce an amount of NOx emission. Further, to solve this problem, an oxygen storage and release material comprising a ceria-zirconia-based complex oxide containing Gd.sub.2O.sub.3 in 0.1 mol % or more and less than 20 mol % and having an ion conductivity of 2×10.sup.−5 S/cm or more at 400° C. is provided. Further, in addition to the above, an oxygen storage and release material having a molar ratio of cerium and zirconium of 0.2 or more and 0.6 or less by cerium/(cerium+zirconium) and an speed of oxygen storage and release “Δt.sub.50” of 20.0 seconds or more or amount of oxygen storage and release of 300 μmol-O.sub.2/g or more etc. was obtained. Further, by applying the oxygen storage and release material to the catalyst, it is possible to assist the purification of exhaust gas as it changes every instant in accordance with the driving conditions and possible to obtain a catalyst with a higher ability to remove harmful components of catalytic precious metals than before. In particular, it is possible to obtain an automotive exhaust gas purification system excellent in ability to remove CO, NOx, and HC.