Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

A stabilized ammonium humate mixture including an amount of humic acid between about 7.0% to about 10% of the mixture and an amount of ammonia between about 1.0% to about 14% of the mixture, where the remainder of the mixture is water.

A stabilized ammonium humate mixture including an amount of humic acid between about 7.0% to about 10% of the mixture and an amount of ammonia between about 1.0% to about 14% of the mixture, where the remainder of the mixture is water.

A process for preparing humic-mineral agent granules is disclosed. Such a process may comprise providing a humic acid-containing material; crushing the humic acid-containing material to obtain first granules; contacting a quantity of water with the first granules, thereby forming slightly wet granules; blending the slightly wet granules for a period of time, thereby forming blended granules; contacting an amount of alkali with the blended granules, thereby forming alkali-treated granules; and mixing the alkali-treated granules at a temperature high enough to melt organic carbon substances in the alkali-treated granules. The resulting product has biologically, geologically, and chemically active properties, and may be applied to the soil alone or in combination with a commercially available fertilizer. Additionally, the resulting product may be used to detoxify solid or liquid waste products.

A process for preparing humic-mineral agent granules is disclosed. Such a process may comprise providing a humic acid-containing material; crushing the humic acid-containing material to obtain first granules; contacting a quantity of water with the first granules, thereby forming slightly wet granules; blending the slightly wet granules for a period of time, thereby forming blended granules; contacting an amount of alkali with the blended granules, thereby forming alkali-treated granules; and mixing the alkali-treated granules at a temperature high enough to melt organic carbon substances in the alkali-treated granules. The resulting product has biologically, geologically, and chemically active properties, and may be applied to the soil alone or in combination with a commercially available fertilizer. Additionally, the resulting product may be used to detoxify solid or liquid waste products.

An arrangement for production of fully soluble, pure and well-defined mono- or di-potassium phosphates, comprises an extraction section, a stripping section and end treatment arrangements. The extraction section performs a liquid-liquid extraction of phosphate between a feed liquid comprising phosphoric acid. The stripping section performs a liquid-liquid extraction of phosphate between solvent loaded with phosphate and a strip solution. The solvent depleted in phosphate is recirculated to the extraction section for further extraction of phosphate. The strip solution is an aqueous potassium phosphate solution. The end treatment arrangements comprise a source of potassium base, an adding arrangement, a cooling arrangement, a precipitate remover and a recirculation system.

The present application relates to an iron impregnated biochar and its use as a fertilizer. The iron impregnated biochar of the present application has a ratio of iron (III) to iron (II) ranging from 5:1 to 10:1. The biochar may be produced by a method including treating the biomass with an iron (II) ion solution, pyrolyzing the iron (II)-treated biomass in an oxidative environment and recovering the biochar product from the pyrolyzed iron (II)-treated biomass.

The present application relates to an iron impregnated biochar and its use as a fertilizer. The iron impregnated biochar of the present application has a ratio of iron (III) to iron (II) ranging from 5:1 to 10:1. The biochar may be produced by a method including treating the biomass with an iron (II) ion solution, pyrolyzing the iron (II)-treated biomass in an oxidative environment and recovering the biochar product from the pyrolyzed iron (II)-treated biomass.

The present invention provides for nutrient extraction and recovery devices that use the Donnan Membrane Principle (DMP) to cause spontaneous separation of dissolved ions along electrochemical potential gradients, wherein anions and cations such as H.sub.2PO.sub.4.sup.−, HPO.sub.4.sup.2−, PO.sub.4.sup.3−, Mg.sup.2+, Ca.sup.2+, NH.sub.4.sup.+, and K.sup.+ are moved from manure containing waste streams through cation and anion exchange membranes into a recovery stream thereby precipitating target compounds including but not limited to struvite, potassium struvite and hydroxyapatite.

The present invention provides for nutrient extraction and recovery devices that use the Donnan Membrane Principle (DMP) to cause spontaneous separation of dissolved ions along electrochemical potential gradients, wherein anions and cations such as H.sub.2PO.sub.4.sup.−, HPO.sub.4.sup.2−, PO.sub.4.sup.3−, Mg.sup.2+, Ca.sup.2+, NH.sub.4.sup.+, and K.sup.+ are moved from manure containing waste streams through cation and anion exchange membranes into a recovery stream thereby precipitating target compounds including but not limited to struvite, potassium struvite and hydroxyapatite.