The invention relates to nitrogen-generating compositions for saturation fire-extinguishing and to methods for producing same. The composition comprises: 25.0-45.0% by mass of a heavy metal oxide, 12.0-18.0% by mass of a combustion modifier in the form of aluminium oxide modified with cobalt (II) nitrate (Co(NO3)2), with accelerating additives of nickel oxide and copper oxide, with an alkali metal azide making up the remainder to 100% and 0.07-2.0% by mass of a carboxylic acid ester as moistener (residue after drying) above 100%. The composition is produced by mixing aluminium oxide with cobalt nitrate and with the moistener, allowing the mixture to stand and dry out so as to produce a first mixture, separately mixing the first mixture with the heavy metal oxide and the moistener until a second mixture is produced, separately preparing a mixture of alkali metal azide powder with the moistener until a third mixture is produced and then mixing the second mixture and the third mixture simultaneously with copper oxide and nickel oxide, drying out the produced mass and forming granules.

The invention relates to nitrogen-generating compositions for saturation fire-extinguishing and to methods for producing same. The composition comprises: 25.0-45.0% by mass of a heavy metal oxide, 12.0-18.0% by mass of a combustion modifier in the form of aluminium oxide modified with cobalt (II) nitrate (Co(NO3)2), with accelerating additives of nickel oxide and copper oxide, with an alkali metal azide making up the remainder to 100% and 0.07-2.0% by mass of a carboxylic acid ester as moistener (residue after drying) above 100%. The composition is produced by mixing aluminium oxide with cobalt nitrate and with the moistener, allowing the mixture to stand and dry out so as to produce a first mixture, separately mixing the first mixture with the heavy metal oxide and the moistener until a second mixture is produced, separately preparing a mixture of alkali metal azide powder with the moistener until a third mixture is produced and then mixing the second mixture and the third mixture simultaneously with copper oxide and nickel oxide, drying out the produced mass and forming granules.

Provided is a method for preparing copper azide and cuprous azide encapsulated by conductive metal-organic framework. The method uses a conductive copper-containing metal-organic framework material as a precursor, and completes the azidation of the precursor by means of a liquid-solid electrochemical azidation reaction. Copper azide and cuprous azide nanocrystals are highly uniformly embedded within a conductive framework, which may effectively avoid the agglomeration of copper azide and cuprous azide, and reduce static charge generated by friction, displacement, and the like. Meanwhile, the conductive framework may promote the effective transfer of charge, avoid the accumulation of static charge, and improve the electrostatic safety. In addition, the liquid-solid electrochemical azidation reaction has advantages such as being safe and efficient, having a short reaction time and having strong operability, and the preparation process is compatible with a MEMS process, which is beneficial for the application of copper azide and cuprous azide materials in micro devices.

Provided is a method for preparing copper azide and cuprous azide encapsulated by conductive metal-organic framework. The method uses a conductive copper-containing metal-organic framework material as a precursor, and completes the azidation of the precursor by means of a liquid-solid electrochemical azidation reaction. Copper azide and cuprous azide nanocrystals are highly uniformly embedded within a conductive framework, which may effectively avoid the agglomeration of copper azide and cuprous azide, and reduce static charge generated by friction, displacement, and the like. Meanwhile, the conductive framework may promote the effective transfer of charge, avoid the accumulation of static charge, and improve the electrostatic safety. In addition, the liquid-solid electrochemical azidation reaction has advantages such as being safe and efficient, having a short reaction time and having strong operability, and the preparation process is compatible with a MEMS process, which is beneficial for the application of copper azide and cuprous azide materials in micro devices.

A detonation transfer assembly is disclosed. A detonation transfer assembly may comprise an external casing comprising an input end and an output end axially opposite the input end, an explosive column spanning axially inside the external casing, a primary explosive disposed within the explosive column, and a secondary explosive disposed within the explosive column axially between the primary explosive and the output end. The primary explosive and/or the secondary explosive may comprise a thermally insensitive initiation material that resists at least one of detonation or thermal degradation in response to temperature increase rate of 3.3° C. per hour over at least twenty hours.

A detonation transfer assembly is disclosed. A detonation transfer assembly may comprise an external casing comprising an input end and an output end axially opposite the input end, an explosive column spanning axially inside the external casing, a primary explosive disposed within the explosive column, and a secondary explosive disposed within the explosive column axially between the primary explosive and the output end. The primary explosive and/or the secondary explosive may comprise a thermally insensitive initiation material that resists at least one of detonation or thermal degradation in response to temperature increase rate of 3.3° C. per hour over at least twenty hours.

Provided is a bullet hit squib including: an electrical connection line; a glow wire connected to the electrical connection line; and a primary explosive charge by which an active substance is formed which can be ignited by the glow wire. The primary explosive charge is formed by a primary explosive which is free of heavy metals and contains silver azide. A method for producing a bullet hit squib is also provided.

The invention relates to nitrogen-generating compositions for saturation fire-extinguishing and to methods for producing same. The composition comprises: 25.0-45.0% by mass of a heavy metal oxide, 12.0-18.0% by mass of a combustion modifier in the form of aluminium oxide modified with cobalt (II) nitrate (Co(NO3)2), with accelerating additives of nickel oxide and copper oxide, with an alkali metal azide making up the remainder to 100% and 0.07-2.0% by mass of a carboxylic acid ester as moistener (residue after drying) above 100%. The composition is produced by mixing aluminium oxide with cobalt nitrate and with the moistener, allowing the mixture to stand and dry out so as to produce a first mixture, separately mixing the first mixture with the heavy metal oxide and the moistener until a second mixture is produced, separately preparing a mixture of alkali metal azide powder with the moistener until a third mixture is produced and then mixing the second mixture and the third mixture simultaneously with copper oxide and nickel oxide, drying out the produced mass and forming granules.

Energetic compounds based on bismuth salts with reduced toxicity that are obtained through the reaction of soluble bismuth salts with soluble salts of organic or inorganic energetic compounds based on azides, derivatives aromatic nitro compounds or nitrogenous heterocyclic compounds, together with the methods for their preparation and application.

Energetic compounds based on bismuth salts with reduced toxicity that are obtained through the reaction of soluble bismuth salts with soluble salts of organic or inorganic energetic compounds based on azides, derivatives aromatic nitro compounds or nitrogenous heterocyclic compounds, together with the methods for their preparation and application.