Patent classifications
C07C221/00
PREPREARATION AND APPLICATION OF 2,6-DIAMINOANTHRAQUINONE BIFUNCTIONAL GROUP COVALENTLY GRAFTED GRAPHENE AS NEGATIVE MATERIAL OF SUPERCAPACITOR
An electrode material of a supercapacitor includes a negative material prepared by the following steps: first dispersing graphite oxide in deionized water; after stirring and ultrasonic treatment, reducing the graphite oxide into reduced graphene oxide by using a hydrazine hydrate, and vacuum drying at 40-80° C.; dispersing the reduced graphene oxide in a DMF solution with 2,6-diaminoanthraquinone, and stirring and performing the ultrasonic treatment again; at 60-90° C., adding isoamyl nitrite, and reacting for 18-24 h; and washing reaction products with ethanol and deionized water for multiple times, and finally freeze drying to obtain a product.
PREPREARATION AND APPLICATION OF 2,6-DIAMINOANTHRAQUINONE BIFUNCTIONAL GROUP COVALENTLY GRAFTED GRAPHENE AS NEGATIVE MATERIAL OF SUPERCAPACITOR
An electrode material of a supercapacitor includes a negative material prepared by the following steps: first dispersing graphite oxide in deionized water; after stirring and ultrasonic treatment, reducing the graphite oxide into reduced graphene oxide by using a hydrazine hydrate, and vacuum drying at 40-80° C.; dispersing the reduced graphene oxide in a DMF solution with 2,6-diaminoanthraquinone, and stirring and performing the ultrasonic treatment again; at 60-90° C., adding isoamyl nitrite, and reacting for 18-24 h; and washing reaction products with ethanol and deionized water for multiple times, and finally freeze drying to obtain a product.
Mechanically shaped 2-dimensional covalent organic frameworks
Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO.sub.4 displayed room temperature conductivity up to 0.26 mS cm.sup.−1 and stability up to 10.0 V (vs. Li.sup.+/Li.sup.0). This outcome portends use of COFs as solid-state electrolytes in batteries.
Mechanically shaped 2-dimensional covalent organic frameworks
Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO.sub.4 displayed room temperature conductivity up to 0.26 mS cm.sup.−1 and stability up to 10.0 V (vs. Li.sup.+/Li.sup.0). This outcome portends use of COFs as solid-state electrolytes in batteries.
Mechanically shaped 2-dimensional covalent organic frameworks
Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO.sub.4 displayed room temperature conductivity up to 0.26 mS cm.sup.−1 and stability up to 10.0 V (vs. Li.sup.+/Li.sup.0). This outcome portends use of COFs as solid-state electrolytes in batteries.
Thermally activated delayed fluorescence material having red, green, or blue color, synthesis method thereof, and application thereof
The present disclosure relates to the field of organic light-emitting materials, and more particularly, to a thermally activated delayed fluorescence material having red, green, or blue color, a synthesis method thereof, and application thereof. The thermally activated delayed fluorescence material having red, green, or blue color has the following structural formula: ##STR00001## the present disclosure provides a novel thermally activated delayed fluorescence material having red, green, or blue color which has a lower singlet triplet energy level difference, a high RISC rate constant (kRISC), and a high photoluminescence quantum yield (PLQY). It has significant characteristics of a thermally activated delayed fluorescence material and a long service life that can be used in an electroluminescent display and a light-emitting equipment structure which are mass produced.
Thermally activated delayed fluorescence material having red, green, or blue color, synthesis method thereof, and application thereof
The present disclosure relates to the field of organic light-emitting materials, and more particularly, to a thermally activated delayed fluorescence material having red, green, or blue color, a synthesis method thereof, and application thereof. The thermally activated delayed fluorescence material having red, green, or blue color has the following structural formula: ##STR00001## the present disclosure provides a novel thermally activated delayed fluorescence material having red, green, or blue color which has a lower singlet triplet energy level difference, a high RISC rate constant (kRISC), and a high photoluminescence quantum yield (PLQY). It has significant characteristics of a thermally activated delayed fluorescence material and a long service life that can be used in an electroluminescent display and a light-emitting equipment structure which are mass produced.
Highly enantioselective access to cyclic beta-amino acids
Disclosed herein is a method of forming a compound of formula I: ##STR00001##
wherein the substituents are defined in the specification. In particular, the compounds of formula I can be converted to amino acids bearing quaternary stereocenters with exceptional optical purities.
Highly enantioselective access to cyclic beta-amino acids
Disclosed herein is a method of forming a compound of formula I: ##STR00001##
wherein the substituents are defined in the specification. In particular, the compounds of formula I can be converted to amino acids bearing quaternary stereocenters with exceptional optical purities.
Antibacterial hydrophilic compound and use thereof
The present disclosure provides an antibacterial hydrophilic compound. The antibacterial hydrophilic compound may react, induced by light through a hydrogen abstraction group in the structural formula thereof, with a C—H group and thus bind to a surface of a material having the C—H group (for example, chemical fibers such as polyester, chinlon, and the like; plastics, rubbers, and other similar materials), which can impart a durable antibacterial activity and hydrophilicity to the material. The antibacterial hydrophilic compound has a relatively strong binding force to the surface of the material without damaging the mechanical properties of the raw material. The present disclosure also provides a modified material that is modified by the antibacterial hydrophilic compound.