Disclosed is an organometallic compound represented by a following Chemical Formula 1. When the organometallic compound is used as dopant of a light-emitting layer of an organic electroluminescent device, rigidity is imparted to the organometallic compound molecule such that a full width at half maximum (FWHM) is narrow and thus color purity is improved. Further, a non-luminescent recombination process is reduced such that luminous efficiency and lifespan of the organic electroluminescent device are improved. Chemical Formula 1 is shown below:

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A composition including a first compound represented by Formula 1 and a second compound represented by Formula 2:

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wherein in Formula 1, M.sub.1 is Pt, Pd, or Au, in Formula 2, M.sub.2 is Ir, L.sub.11 is a ligand represented by Formula 2-1, L.sub.12 is a ligand represented by Formula 2-2, L.sub.13 is a ligand represented by Formula 2-1 or 2-2, L.sub.11 and L.sub.12 are different from each other, n11, n12, and n13 are each independently 0, 1, 2, or 3, and a sum of n11+n12+n13 is equal to 3, and wherein the remaining substituent groups are each understood by referring to the detailed description provided herein.

An organometallic compound represented by Formula 1 emits deep blue light. A light-emitting device including the organometallic compound, and an electronic apparatus including the light-emitting device may have excellent or suitable driving voltage, luminescence efficiency, color conversion efficiency, and/or lifespan characteristics:

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In Formula 1, X.sub.1 to X.sub.4 are each independently C or N, Y.sub.11 is C(Z.sub.11) or N, and Y.sub.12 is C(Z.sub.12) or N.

Porphyrin photosensitizers including 5,15-di(naphthalimide) moieties useful for photocatalytic hydrogen evolution, compositions including the same, and methods of use thereof.

The invention is directed to ruthenium-based metathesis catalysts of the Grubbs-Hoveyda type. The new 2-aryloxy-substituted ruthenium catalysts described herein reveal rapid initiation behavior. Further, the corresponding styrene-based precursor compounds are disclosed. The catalysts are prepared in a cross-metathesis reaction starting from styrene-based precursors which can be prepared in a cost-effective manner. The new Grubbs-Hoveyda type catalysts are suitable to catalyze ring-closing metathesis (RCM), cross metathesis (CM) and ring-opening metathesis polymerization (ROMP). Low catalyst loadings are necessary to convert a wide range of substrates including more complex and critical substrates via metathesis reactions at low to moderate temperatures in high yields within short reaction times.

The invention relates to monocarbonyl complexes of ruthenium and osmium with bi- and tridentate nitrogen and phosphine ligands. The invention relates to methods for preparing these complexes and the use of these complexes, isolated or prepared in situ, as catalysts for reduction reactions of ketones and aldehydes both via transfer hydrogenation or hydrogenation with hydrogen.

An organic light-emitting material contains a 6-silyl-substituted isoquinoline ligand. The organic light-emitting material is a metal complex containing a 6-silyl-substituted isoquinoline ligand and may be used as a light-emitting material in a light-emitting layer of an organic electroluminescent device. These new complexes can provide redder and saturated emission and meanwhile demonstrate a significantly improved lifetime and efficient and excellent device performance. Further disclosed are an electroluminescent device and a compound formulation including the metal complex.

The present invention relates to a ruthenium precursor compound, and more particularly, to a ruthenium precursor compound which is for providing ruthenium to an ammonia decomposition reaction catalyst and is represented by Formula C.sub.xH.sub.yO.sub.zN.sub.mRu.sub.n, wherein x is an integer of 3 to 20, y is an integer of 0 to 32, z is an integer of 0 to 20, m is an integer of 0 to 10, and n is an integer of 1 to 3. In addition, the present invention relates to an ammonia reaction catalyst using the ruthenium precursor, and to a method for preparing the ammonia reaction catalyst, and provides an ammonia reaction catalyst having an excellent ammonia conversion rate at low temperatures, thereby being capable of efficient hydrogen production.

A process for the manufacture of a complex of the formula [MHal(R.sup.1R.sup.2C═CR.sup.3R.sup.4).sub.2].sub.2 with M = Rh or Ir; Hal = Cl, Br or l; and R.sup.1R.sup.2C═CR.sup.3R.sup.4 = a gaseous mono olefin with 2 to 4 carbon atoms, the process comprising the steps: (1) preparing an aqueous alcoholic solution of a MHal.sub.3 hydrate salt, (2) reacting the dissolved MHal.sub.3 hydrate salt with the gaseous mono olefin R.sup.1R.sup.2C═CR.sup.3R.sup.4 under formation of precipitated [MHal(R.sup.1R.sup.2C═CR.sup.3R.sup.4).sub.2].sub.2, (3) optionally, cooling the reaction mixture obtained after conclusion of step (2) down to a temperature in the range of > 0 to 10° C. and keeping it there, and (4) collecting and drying the precipitated [MHal(R.sup.1R.sup.2C═CR.sup.3R.sup.4).sub.2].sub.2, wherein the temperature of the reaction mixture during step (2) is kept in a range of 15 to 30° C.

A compound of Formula I,

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is disclosed. In Formula I, M is Pd or Pt; each of X.sup.1 to X.sup.12 is C or N; each of X.sup.13 and X.sup.14 is CH, CD or N; each of Z.sup.1, Z.sup.2, and Z.sup.3 is C or N; L.sup.1 is selected from a variety of bivalent linkers; X is selected from O, S, Se, NR′, and CR″R′″; each R, R′, R.sup.1, R.sup.2, R.sup.3, R.sup.A, R.sup.B, R.sup.C, R.sup.D, and R.sup.E is hydrogen or a General Substituent; at least one of Z.sup.1, Z.sup.2, and Z.sup.3 is a carbon atom substituted with a substituent with a molecular weight of at least 16. Formulations, OLEDs, and consumer products that include Formula I are also disclosed.