C08B11/00

Method for producing cellulose ether

A method for producing a cellulose ether having a high viscosity while keeping the same degree of polymerization as that in the production of a shaped pulp without changing a raw material or production facility. More specifically, provided is a method for producing a cellulose ether including steps of: cutting or pulverizing pulp to obtain sheet-like, chip-like, or powdery cellulose pulp, wherein the pulp is formed in a form of roll whose surface layer on at least one of the circumferential side and the ends is removed, or in a form of bale whose surface layer on at least one side is removed; bringing the obtained cellulose pulp into contact with an alkali metal hydroxide solution to obtain alkali cellulose; reacting the alkali cellulose with an alkylating agent to obtain a reaction product mixture; and subjecting the reaction product mixture to purification to obtain the cellulose ether.

Method for producing cellulose ether

A method for producing a cellulose ether having a high viscosity while keeping the same degree of polymerization as that in the production of a shaped pulp without changing a raw material or production facility. More specifically, provided is a method for producing a cellulose ether including steps of: cutting or pulverizing pulp to obtain sheet-like, chip-like, or powdery cellulose pulp, wherein the pulp is formed in a form of roll whose surface layer on at least one of the circumferential side and the ends is removed, or in a form of bale whose surface layer on at least one side is removed; bringing the obtained cellulose pulp into contact with an alkali metal hydroxide solution to obtain alkali cellulose; reacting the alkali cellulose with an alkylating agent to obtain a reaction product mixture; and subjecting the reaction product mixture to purification to obtain the cellulose ether.

Cellulosic polymer nanoparticles and methods of forming them

Nanoparticles including a cellulosic polymer and a hydrophobic material and methods for forming them.

Cellulose ether-lactam hybrid polymers, compositions, and methods for preparing and using the hybrid polymers
11753484 · 2023-09-12 · ·

The present invention provides novel hybrid polymers having unique physical properties. The hybrid polymers comprise a cellulose ether moiety, a linking group moiety, a spacer group moiety, and a lactam moiety. The present invention also provides compositions comprising the hybrid polymers and methods for preparing and using the hybrid polymers. In a first embodiment, the hybrid polymers have the structure:
A-(L.sub.1-S—(B).sub.k).sub.q
wherein A is derived from a cellulose ether moiety comprising a —OH group; L.sub.1 is a linking group moiety selected from the group consisting of urethanes, amides, esters, carbonates, and phosphate esters, or is derived from a moiety selected from the group consisting of anhydrides, cyclic ethers, and aziridines; S is a spacer group moiety, selected from the group consisting of straight- or branched-chain functionalized and unfunctionalized alkyl, cycloalkyl, alkenyl, and aryl groups, wherein any of the above groups may be with or without heteroatoms, or is a direct bond; and B is a lactam moiety; wherein k≥1 and q≥1. In a second embodiment, the hybrid polymers have the structure:
A-(L.sub.2-S—B).sub.y
wherein A is derived from a cellulose ether moiety comprising a —OH group; L.sub.2 is an ether linking group moiety; S is a spacer group moiety, selected from the group consisting of straight- or branched-chain functionalized and unfunctionalized alkyl, cycloalkyl, alkenyl, and aryl groups, wherein any of the above groups may be with or without heteroatoms, or is a direct bond; and B is a lactam moiety; wherein y≥1; with the proviso that when the cellulose ether moiety is hydroxyethyl cellulose, -(L.sub.2-S—B).sub.y is not derived from 1-(hydroxymethyl)-2-pyrrolidinone.

Cellulose ether-lactam hybrid polymers, compositions, and methods for preparing and using the hybrid polymers
11753484 · 2023-09-12 · ·

The present invention provides novel hybrid polymers having unique physical properties. The hybrid polymers comprise a cellulose ether moiety, a linking group moiety, a spacer group moiety, and a lactam moiety. The present invention also provides compositions comprising the hybrid polymers and methods for preparing and using the hybrid polymers. In a first embodiment, the hybrid polymers have the structure:
A-(L.sub.1-S—(B).sub.k).sub.q
wherein A is derived from a cellulose ether moiety comprising a —OH group; L.sub.1 is a linking group moiety selected from the group consisting of urethanes, amides, esters, carbonates, and phosphate esters, or is derived from a moiety selected from the group consisting of anhydrides, cyclic ethers, and aziridines; S is a spacer group moiety, selected from the group consisting of straight- or branched-chain functionalized and unfunctionalized alkyl, cycloalkyl, alkenyl, and aryl groups, wherein any of the above groups may be with or without heteroatoms, or is a direct bond; and B is a lactam moiety; wherein k≥1 and q≥1. In a second embodiment, the hybrid polymers have the structure:
A-(L.sub.2-S—B).sub.y
wherein A is derived from a cellulose ether moiety comprising a —OH group; L.sub.2 is an ether linking group moiety; S is a spacer group moiety, selected from the group consisting of straight- or branched-chain functionalized and unfunctionalized alkyl, cycloalkyl, alkenyl, and aryl groups, wherein any of the above groups may be with or without heteroatoms, or is a direct bond; and B is a lactam moiety; wherein y≥1; with the proviso that when the cellulose ether moiety is hydroxyethyl cellulose, -(L.sub.2-S—B).sub.y is not derived from 1-(hydroxymethyl)-2-pyrrolidinone.

METHOD FOR PRODUCING MODIFIED CELLULOSE

The present invention is a method for producing a modified cellulose including the following step A: step A: introducing a cellulose raw material with a substituent having 6 or more carbon atoms to a group in which a hydrogen atom is removed from a hydroxyl group of a cellulose backbone, in the presence of water and a surfactant. The present invention relates to a method for producing a modified cellulose having a high affinity of an organic solvent, a resin or the like, and a hydrophobic medium, using a reaction system with low environmental loads and with prospects of reduction in production costs.