Patent classifications
C08F110/00
METALLOCENE COMPOUND, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
A metallocene compound having a structure shown by formula (I). A functional group connected to a bridging atom of the metallocene compound is an amine-substituted group and/or a metallocene-substituted group and/or a substituted metallocene group. A metallocene catalyst containing the metallocene compound has high catalytic activity, and can synthesize metallocene polypropylene having high isotacticity.
R.sup.IR.sup.IIZ(Cp.sup.III).sub.n(E).sub.2-nML.sup.IVL.sup.V (I)
METALLOCENE COMPOUND, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
A metallocene compound having a structure shown by formula (I). A functional group connected to a bridging atom of the metallocene compound is an amine-substituted group and/or a metallocene-substituted group and/or a substituted metallocene group. A metallocene catalyst containing the metallocene compound has high catalytic activity, and can synthesize metallocene polypropylene having high isotacticity.
R.sup.IR.sup.IIZ(Cp.sup.III).sub.n(E).sub.2-nML.sup.IVL.sup.V (I)
Method of preparing ethylene polymers by controlled high pressure polymerization
The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Poyldispersity Index PD=1, 2-4.5).
Apparatus and method for removing halogens generated during preparation of polybutene
Disclosed are an apparatus and a method for removing halogens generated during the preparation of polybutene, which are capable of improving the utilization of polybutene and light polymers by removing halogen components contained in the polybutene and the light polymers. The method for removing halogens generated during the preparation of polybutene comprises the steps of: preparing a reaction product by supplying a catalyst and a reaction raw material to a reactor and polymerizing; removing a catalyst component from the reaction product and neutralizing; separating the reaction product into an organic compound and impurities comprising the catalyst component; heating the organic compound to distill an unreacted material; and removing a halogen component in a remaining polymerization mixture after the distillation using a halogen removing catalyst, or removing a halogen component in polybutene and light polymers obtained from the polymerization mixture using the halogen removing catalyst.
Polyolefin composition with improved balance of properties
The present invention is directed to a polyolefin composition comprising a blend of a heterophasic polypropylene composition and 5.0 to 30.0 wt % of an ethylene homo- or copolymer, the ethylene homo- or copolymer having a density of at least 941 kg/m.sup.3 and a melt flow rate MFR.sub.21 of 1 to 10 g/10 min. The heterophasic polypropylene composition comprises a propylene homopolymer or a propylene ethylene random copolymer and an elastomeric ethylene propylene rubber, and is characterized by 75.0 to 95.0 wt % of a crystalline fraction having an ethylene content of up to 4.0 wt % and an MFR.sub.2 of 0.1 to 100 g/10 min, and 5.0 to 25.0 wt % of a soluble fraction having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/kg, wherein the crystalline fraction and the soluble fraction are determined in 1,2,4-trichlorobenzene at 40° C.
Polyolefin composition with improved balance of properties
The present invention is directed to a polyolefin composition comprising a blend of a heterophasic polypropylene composition and 5.0 to 30.0 wt % of an ethylene homo- or copolymer, the ethylene homo- or copolymer having a density of at least 941 kg/m.sup.3 and a melt flow rate MFR.sub.21 of 1 to 10 g/10 min. The heterophasic polypropylene composition comprises a propylene homopolymer or a propylene ethylene random copolymer and an elastomeric ethylene propylene rubber, and is characterized by 75.0 to 95.0 wt % of a crystalline fraction having an ethylene content of up to 4.0 wt % and an MFR.sub.2 of 0.1 to 100 g/10 min, and 5.0 to 25.0 wt % of a soluble fraction having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/kg, wherein the crystalline fraction and the soluble fraction are determined in 1,2,4-trichlorobenzene at 40° C.
LAMINATE AND PRODUCT
A laminated body 10 includes: a layer (C) 12 consisting of a composition (c) containing a copolymer that contains a conjugated diene unit and a non-conjugated olefin unit and contains 0 mol % of a butylene unit; and a layer (R) 14 consisting of a composition (r) containing an olefin-based resin, in which the layer (C) 12 is adjacent to the layer (R) 14. The laminated body 10 is excellent in a mechanical strength and impact resistance, and is easy to repair.
Polymerization of propylene
Disclosed are a method and system for propylene polymerization utilizing a loop slurry reactor. The method can include polymerizing propylene in a loop slurry reactor under bulk polymerization conditions to produce polypropylene. The propylene polymerization system can include i) a loop slurry reactor and a heat exchange system that is configured to cool the legs of the loop slurry reactor and/or ii) an inlet manifold that is configured to connect flashline heaters to a separator.
POLYOLEFIN COMPOSITION WITH IMPROVED BALANCE OF PROPERTIES
The present invention is directed to a polyolefin composition comprising a blend of a heterophasic polypropylene composition and 5.0 to 30.0 wt % of an ethylene homo- or copolymer, the ethylene homo- or copolymer having a density of at least 941 kg/m.sup.3 and a melt flow rate MFR.sub.21 of 1 to 10 g/10 min. The heterophasic polypropylene composition comprises a propylene homopolymer or a propylene ethylene random copolymer and an elastomeric ethylene propylene rubber, and is characterized by 75.0 to 95.0 wt % of a crystalline fraction having an ethylene content of up to 4.0 wt % and an MFR.sub.2 of 0.1 to 100 g/10 min, and 5.0 to 25.0 wt % of a soluble fraction having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/kg, wherein the crystalline fraction and the soluble fraction are determined in 1,2,4-trichlorobenzene at 40° C.
POLYOLEFIN COMPOSITION WITH IMPROVED BALANCE OF PROPERTIES
The present invention is directed to a polyolefin composition comprising a blend of a heterophasic polypropylene composition and 5.0 to 30.0 wt % of an ethylene homo- or copolymer, the ethylene homo- or copolymer having a density of at least 941 kg/m.sup.3 and a melt flow rate MFR.sub.21 of 1 to 10 g/10 min. The heterophasic polypropylene composition comprises a propylene homopolymer or a propylene ethylene random copolymer and an elastomeric ethylene propylene rubber, and is characterized by 75.0 to 95.0 wt % of a crystalline fraction having an ethylene content of up to 4.0 wt % and an MFR.sub.2 of 0.1 to 100 g/10 min, and 5.0 to 25.0 wt % of a soluble fraction having an ethylene content of 10.0 to 70.0 wt % and an intrinsic viscosity of 1.0 to 4.0 dl/kg, wherein the crystalline fraction and the soluble fraction are determined in 1,2,4-trichlorobenzene at 40° C.