C08G2310/00

Sprayable polyurethane/urea elastomer for agriculture

A process for preparing a polymeric membrane for materials used in crop production comprising: a) providing an aqueous dispersion of a polyurethane or polyurethane-urea elastomer comprising segments formed from the copolymer segment of Formula I
A.sup.1-[Y.sup.1].sub.n-L-[Y.sup.2].sub.q-A.sup.2  Formula I
wherein A.sup.1 is an end capping group; A.sup.2 is hydrogen or an end capping group; each [Y.sup.1].sub.n and [Y.sup.2].sub.q is independently selected from a polyether macrodiol, polycarbonate macrodiol, polyester macrodiol, and wherein at least one of [Y.sup.1].sub.n and [Y.sup.2].sub.q is a polyester macrodiol; L is a divalent linking compound independently selected from urethane, urea, carbonate, ester, and phosphonate; n is an integer of 2 to 50; q is an integer of 2 to 50; and b) spraying the aqueous dispersion onto materials to be used in crop production to form a polymeric membrane on the materials.

CATALYST FOR COPOLYMERIZATION OF CARBON DIOXIDE AND EPOXY AND METHOD OF MANUFACTURING THE SAME

A ternary composite catalyst of diethylzinc and yttrium trifluoroacetate loaded on chitin for copolymerization of carbon dioxide, epoxy cyclohexane and ethylene oxide is provided. The ternary composite catalyst exhibits strong catalytic activity for the ternary copolymerization of carbon dioxide, cyclohexane oxide and ethylene oxide. A high molecular weight and content of ester chain is maintained. Conventional rare earth ternary catalysts leave residues in the polymer, and the polymer requires rinsing with hydrochloric acid. The ternary composite catalyst can be removed through filtration. The average molecular weight of the resulting polycarbonate is more than 100,000, and the ester chain content is more than 90%. The resulting polymer has a lower metal content. The ternary composite catalyst can be used in agricultural film, disposable packaging and other polymer materials.

POLYCARBONATE RESIN

The present invention relates to a polycarbonate resin containing, in the molecule, a structure represented by the following formula (1):

##STR00001##

wherein X has a structure represented by any one of the following formulae (2) to (4):

##STR00002##

wherein each of R.sup.1 to R.sup.4 independently represents a hydrogen atom or an organic group having a carbon number of 1 to 30; the organic group may have an arbitrary substituent, and any two or more members of R.sup.1 to R.sup.4 may combine with each other to form a ring, which is excellent in heat resistance, transparency, light resistance, weather resistance and mechanical strength.

Electronic device, method and apparatus for producing an electronic device, and composition therefor
11240916 · 2022-02-01 · ·

An electronic device, a method and apparatus for producing an electronic device, and a composition therefor are disclosed. An adhesive material is applied in a first pattern on a surface of a receiver substrate. A carrier having a metal foil disposed thereon is brought into contact with the first substrate such that a portion of the metal foil contacts the adhesive material. The adhesive material includes a first polymer, a second polymer, and a conductive carbon black dispersion, and is activated using at least one of mechanical pressure and heat while the portion of the metal foil is in contact with the adhesive material. The first substrate and the second substrate are separated, whereby the portion of the metal foil is transferred to the first substrate. The adhesive is electrically conductive to maximize the possibility of maintaining electrical connectivity even when there is a break in the metal foil.

TIRE
20210395518 · 2021-12-23 · ·

Provided is a tire that prevents a polyurethane foam layer from discoloring to brown. A tire comprises: a polyurethane foam layer laminated on an outer layer of the tire with a barrier layer therebetween, wherein the polyurethane foam layer contains a polyurethane foam, and the barrier layer is formed from a rubber composition containing butyl rubber as a rubber component.

Polyurethane moisture barrier coatings containing thermoplastic resins

A moisture barrier coating includes the reaction product of (A) at least one polyol and (B) at least one polyisocyanate. The moisture barrier coating further includes at least one amorphous thermoplastic material that forms a homogeneous mixture with the polyol, and is nonreactive with the polyol and with the polyisocyanate. A controlled release fertilizer, a method for the production of a controlled release fertilizer, and a moisture barrier coating composition are also disclosed.

SPRAYABLE POLYMER MEMBRANE FOR AGRICULTURE

A process for preparing a polymeric membrane for soil materials used in crop production comprising providing an aqueous dispersion of polyurethane and spraying the aqueous dispersion onto soil materials to be used in crop production to form a polymeric membrane.

Sebacic acid by-product fatty acid polyester polyol for polyurethane controlled-release fertilizer envelope, preparation method thereof and envelope
20220153678 · 2022-05-19 ·

A polyester polyol is synthesized through an esterification reaction with a sebacic acid by-product fatty acid as a raw material; wherein the sebacic acid by-product fatty acid is refined from a by-product produced during preparing a sebacic acid from a castor oil; the sebacic acid by-product fatty acid includes, in weight percentage: a palmitic acid 15-25%, a stearic acid 10-16%, an oleic acid 45-57%, and a linoleic acid 12-28%. A method for preparing the polyester polyol is provided, as well as a polyurethane controlled-release fertilizer envelope and a polyurethane controlled-release fertilizer. The sebacic acid by-product fatty acid is used as a raw material to synthesize the polyester polyol because of a low price. The prepared fertilizer has excellent envelope and controlled-release performance, product structure performance is stable, cost performance is high, and degradation performance is sufficient after being applied to soil.

Polyester polyol with high biomass ratio for polyurethane controlled-release fertilizer envelope, preparation method thereof and envelope
20220153654 · 2022-05-19 ·

Epoxy soybean oil polyol is firstly prepared by open-ring etherification of an epoxy soybean oil and a small molecular alcohol with an organic acid catalyst, and then the epoxy soybean oil polyol is further esterified with an organic acid under an esterification catalyst to prepare a polyester polyol with a high biomass ratio. The polyester polyol includes a compound having an Ñ-type structure and a compound having an Ò-type structure. A method for preparing the polyester polyol is provided, as well as a polyurethane controlled-release fertilizer envelope and a polyurethane controlled-release fertilizer prepared by cross-linking the polyester polyol and MDI on surfaces of the fertilizer. The epoxy soybean oil and the small molecular alcohol can be derived from biomass, so a biomass content is high, the synthesized product is environmentally safe, and product performance is excellent.

POLYOL COMPOSITIONS

Disclosed is a polyol composition comprising: (a) at least one monomeric polyol comprising three or more hydroxyl groups; (b) at least one higher polyol comprising three or more hydroxyl groups; and (c) at least one polyhydroxylated aromatic compound; wherein the at least one higher polyol comprises residues of either or both of the at least one monomeric polyol and the polyhydroxylated aromatic compound linked by one or more carbonate groups, oxygen ether groups, or a combination thereof, and wherein the polyol composition has a viscosity of less than 5000 cps at 150 degrees Fahrenheit. The at least one monomeric polyol and at least one higher polyol may have any structures affording polyol compositions and polyurethane compositions having the requisite physical characteristics in terms of polyol composition viscosity and polyurethane heat resistance, strength and flexural modulus. The polyol compositions are adapted to provide structurally robust, temperature resistant polyurethanes, but are of sufficiently low viscosity to permit the use of currently available pumping and mixing equipment. The resultant polyurethane compositions may exhibit heat distortion temperatures in excess of 110 degrees centigrade, high strength and essentially no loss of material properties in prolonged humidity tests at 70 degrees centigrade, lower peak exotherms, typically less than 250 degrees Fahrenheit during in-mold curing/polymerization. Articles prepared from polyurethanes incorporating such polyol compositions as reactants exhibit flexural strengths in excess of 10,000 psi and flexural moduli in excess of 400,000 psi, and exhibit outstanding green strength.