A process for manufacturing a masterbatch comprises the following steps: (a) bringing at least one initial polymer comprising at least one carbon-carbon unsaturation into contact with at least one 1,3-dipolar grafting agent bearing at least one nitrile oxide dipole in the presence of at least one organophosphorus additive selected from the group consisting of phosphoric acid triesters, phosphonates, phosphinates, phosphine oxides and the mixtures of these compounds, and (b) recovering the masterbatch obtained in the preceding step. The masterbatch and compositions containing it and also tires comprising such compositions are also disclosed.

The present disclosure relates to thermoplastic collagen elastomer compositions comprising collagen, at least one reactive thermoplastic elastomer, and at least one softener, as well as composite materials made from these compositions. Methods of making and using the thermoplastic collagen elastomer composite materials to produce engineered leather are also disclosed.

The present invention relates to a resin composition comprising: a base resin comprising a petroleum resin of which at least a part is hydrogenated or non-hydrogenated; and an additive comprising a modified C.sub.9 polymer having a structure in which a molecular weight modifier binds to at least one terminal of the two terminals of the petroleum resin of which at least a part is hydrogenated or non-hydrogenated. The present invention also relates to a gas barrier film comprising the resin composition, and a tire.

Methods for treating a cured inner liner as well as treated, cured inner liners resulting from such methods are disclosed. Also disclosed are tires containing the treated inner liners. The methods include treatment of the lower surface of inner liner surface with a rubber-containing liquid to produce a rubber-containing film thereupon.

The present invention discloses a multilayer composite rubber-plastic foam insulation material and a preparation method thereof. The composite rubber-plastic foam insulation material includes a two-layer structure; the two-layer structure includes an insulation layer and a first functional layer; the insulation layer and the first functional layer are both made of a rubber-plastic foam material; the first functional layer and the insulation layer are integrally molded by blending extrusion and vulcanization foaming, and the first functional layer and the insulation layer form an integral structure. The multilayer composite rubber-plastic foam insulation material provided by the present invention adopts a vulcanization foaming integral molding process, and not only ensures the thermal insulation property of the insulation layer, but also gives the functional layer corresponding functions by selecting different functional polymers, thereby satisfying a variety of personalized needs in engineering applications.

A rubber composition manufacturing method comprises an operation in which at least rubber, silica, and silane coupling agent are kneaded in an internal kneader at not less than a temperature lower limit for a coupling reaction between the silica and the silane coupling agent to proceed. For at least a portion of time during which that operation is being carried out, a compressed gas is delivered to the kneading chamber while the ram is in a nonpressing state.

A rubber composition manufacturing method comprises: an operation in which at least amine antioxidant, zinc oxide, silane coupling agent, silica, and rubber comprising modified polymer are fed into an internal kneader; and an operation in which kneading is carried out at the internal kneader while kneading temperature is controlled so as to suppress occurrence of a coupling reaction between the silica and the silane coupling agent, and so as to suppress occurrence of a bonding reaction between the silica and the modified polymer.

A pneumatic tire having a fiber-reinforced rubber layer can help prevent foreign objects from penetrating/extending beyond the tread and into its underlying layer(s), thereby desirably increasing the overall lifespan of the tire. In one embodiment, the tire includes at least one fiber-reinforced rubber layer, which can be generally supported by a tire carcass and interposed directly between a tread portion and belt ply. The fiber-reinforced rubber layer can define a barrier/barrier layer between the tread portion and belt ply and includes a rubber compound that is reinforced with one or more types of fiber (e.g., chopped nylon fiber) and has one or more specific chemical compounds that can provide desirable barrier properties (e.g., abrasion resistance, penetration energy, and DIN properties), thereby helping to prevent foreign objects from penetrating/extending beyond the tire tread and into its underlying layer(s), such as the belt ply and carcass.

A tire is provided with an external sidewall, said external sidewall comprising at least one elastomeric composition based on: (a) an elastomeric matrix comprising at least one diene elastomer, (b) a crosslinking system, and (c) at least one polymer incompatible with the elastomeric matrix. A process for the preparation of an elastomeric composition for an external sidewall is also disclosed.

According to the process for preparing a vulcanized rubber composition of the invention comprising (a) a step of preparing a master batch comprising a butadiene rubber and silica, (b) a step of preparing a master batch comprising an isoprene rubber and silica, (c) a step of kneading the master batch obtained in (a) and the master batch obtained in (b), and (d) a step of vulcanizing a kneaded product obtained in (c), wherein the obtained vulcanized rubber composition comprises a BR phase and a IR phase, which are incompatible with each other, a predetermined abundance ratio α of silica in the BR phase satisfies 0.3≦α≦0.7 (Relation 1), and a proportion β of the butadiene rubber satisfies 0.4≦β≦0.8 (Relation 2) it is possible to improve performance on ice and abrasion resistance and to provide a vulcanized rubber composition having excellent performance on ice and abrasion resistance, and a studless tire with a tread made using the same.