Provided is a dip-molded article, and more particularly, provided are a dip-molded article including: a layer derived from a latex composition for dip-molding; and a layer derived from a polymer including a repeating unit derived from a diacetylene-based compound, a latex composition for dip-molding, and a preparation method thereof.

A process for improving sensitivity of a film base, coated with a dispersion of a normally crystalline polyacetylenic compound in a non-solvating liquid which is dried on the film surface, to particular photon energy band, specifically, long wavelength UV; the polyacetylenic compound preferably having at least two conjugated acetylenic linkages and containing from 12 to 60 carbon atoms. The sensitization of the film to long wavelength UV is achieved via the addition of photoinitiator(s) capable of absorbing UV energy and converting it to free radicals.

Provided is a dip-molded article, and more particularly, provided are a dip-molded article including: a layer derived from a latex composition for dip-molding; and a layer derived from a polymer including a repeating unit derived from a diacetylene-based compound, a latex composition for dip-molding, and a preparation method thereof.

A process for improving sensitivity of a film base, coated with a dispersion of a normally crystalline polyacetylenic compound in a non-solvating liquid which is dried on the film surface, to particular photon energy band, specifically, long wavelength UV; the polyacetylenic compound preferably having at least two conjugated acetylenic linkages and containing from 12 to 60 carbon atoms. The sensitization of the film to long wavelength UV is achieved via the addition of photoinitiator(s) capable of absorbing UV energy and converting it to free radicals. The process comprises dispersing the normally crystalline polyacetylenic compound in the non-solvating liquid to a concentration of from about 2 to about 50% polyacetylene crystalline solids and a photoinitiator or combination of photoinitiators to a concentration of from 0.01 to 10%. The resultant dispersion is then coated and dried on a substrate. Additionally, applications using this film as a UVA illumination indicator and dosimeter are disclosed as well.

A hydrochromic polydiacetylene polymer patch and a method of manufacturing the same are provided. The hydrochromic polymer patch comprises a polymer matrix; and polydiacetylene present in the polymer matrix. The polydiacetylene has an ionic functional group in the repeating unit thereof. The ionic functional group is R.sup.M.sup.+ or R.sup.+X.sup.. R.sup. is a carboxylate anion, M.sup.+ is an alkali metal cation, and R.sup.+ is a quaternary ammonium group, and X.sup. is F.sup., Cl.sup., Br.sup., I.sup., PF.sub.6.sup., BF.sub.4.sup., bis(trifluoromethane)sulfonimide (Tf.sub.2N.sup.), trifluoromethanesulfonate (TfO.sup.), SCN.sup., or CH.sub.3COO.sup..

A process for improving sensitivity of a film base, coated with a dispersion of a normally crystalline polyacetylenic compound in a non-solvating liquid which is dried on the film surface, to particular photon energy band, specifically, long wavelength UV; the polyacetylenic compound preferably having at least two conjugated acetylenic linkages and containing from 12 to 60 carbon atoms. The sensitization of the film to long wavelength UV is achieved via the addition of photoinitiator(s) capable of absorbing UV energy and converting it to free radicals. The process comprises dispersing the normally crystalline polyacetylenic compound in the non-solvating liquid to a concentration of from about 2 to about 50% polyacetylene crystalline solids and a photoinitiator or combination of photoinitiators to a concentration of from 0.01 to 10%. The resultant dispersion is then coated and dried on a substrate. Additionally, applications using this film as a UVA illumination indicator and dosimeter are disclosed as well.