The embodiments relate to a process for preparing a polythiol composition, which comprises reacting a halogen compound or an alcohol compound with thiourea to prepare a thiouronium salt solution; and adding a basic solution to the thiouronium salt solution to hydrolyze it. The hydrolysis reaction is terminated when the area of peak A in the graph measured by gel permeation chromatography of the reactant in the hydrolysis step under certain conditions is 0.5% to 8% based on the total peak area. A tetrafunctional polythiol composition having high purity can be obtained. Thus, an optical lens having excellent color, transparency, and refractive index can be obtained.

The embodiments relate to a process for preparing a polythiol composition, which comprises reacting a halogen compound or an alcohol compound with thiourea to prepare a thiouronium salt solution; and adding a basic solution to the thiouronium salt solution to hydrolyze it. The hydrolysis reaction is terminated when the area of peak A in the graph measured by gel permeation chromatography of the reactant in the hydrolysis step under certain conditions is 0.5% to 8% based on the total peak area. A tetrafunctional polythiol composition having high purity can be obtained. Thus, an optical lens having excellent color, transparency, and refractive index can be obtained.

A composition [composition (C)] comprising from 1 to 90% by weight (wt. %) of at least one poly(aryl ether ketone) [(PAEK) polymer], from 1 to 25 wt. % of at least one polyphenylsulfone polymer [(PPSU) polymer], from 1 to 90 wt. % of at least one polyethersulfone polymer [(PES)polymer], and from 0.1 to 50 wt. % of at least one reinforcing filler, where all wt. % are based on the total weight of the composition (C) and the (PES) polymer has as melt flow rate(MFR) at a temperature of 380° C. and under a load of 2.16 kg according to ASTM D1238 of greater than 35 g/10 min.

The present disclosure discloses a thiocarbonyl-based poly(O-thiocarbamate) compound and a preparation method and use thereof, belonging to the technical field of polymer chemistry and material science. The present disclosure provides a new thiocarbonyl-based poly(O-thiocarbamate)compound with a structure represented by Formula I, which has sulfur element introduced, and has good solubility and high molecular weight. The thiocarbonyl-based poly(O-thiocarbamate) compound provided has good thermal stability and a very high refractive index, and is expected to have desirable applications in the optical field.

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The present disclosure discloses a thiocarbonyl-based poly(O-thiocarbamate) compound and a preparation method and use thereof, belonging to the technical field of polymer chemistry and material science. The present disclosure provides a new thiocarbonyl-based poly(O-thiocarbamate)compound with a structure represented by Formula I, which has sulfur element introduced, and has good solubility and high molecular weight. The thiocarbonyl-based poly(O-thiocarbamate) compound provided has good thermal stability and a very high refractive index, and is expected to have desirable applications in the optical field.

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A polymerizable composition for an optical material according to the present invention includes a photochromic composition (A), and a polymerizable composition (B) including a bi- or higher functional iso(thio)cyanate compound and a bi- or higher functional active hydrogen compound, in which the photochromic composition (A) is a composition including at least three types of photochromic compounds (i) to (iii), the photochromic compound (i) has a structure including a chromophore a and a monovalent or a divalent organic group including one or more types of a polysiloxane chain or a polyoxyalkylene chain, the photochromic compound (ii) has the chromophore a (which is not the photochromic compound (i)), and the photochromic compound (iii) has a chromophore b different from the chromophore a.

A polymerizable composition for an optical material according to the present invention includes a photochromic composition (A), and a polymerizable composition (B) including a bi- or higher functional iso(thio)cyanate compound and a bi- or higher functional active hydrogen compound, in which the photochromic composition (A) is a composition including at least three types of photochromic compounds (i) to (iii), the photochromic compound (i) has a structure including a chromophore a and a monovalent or a divalent organic group including one or more types of a polysiloxane chain or a polyoxyalkylene chain, the photochromic compound (ii) has the chromophore a (which is not the photochromic compound (i)), and the photochromic compound (iii) has a chromophore b different from the chromophore a.

Provided are an organic magnetic material and a semiconductor device including the same. According to the inventive concept, the organic magnetic material may include a material represented by Formula 1 below.

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Provided are an organic magnetic material and a semiconductor device including the same. According to the inventive concept, the organic magnetic material may include a material represented by Formula 1 below.

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According to an embodiment, the pH of a diisocyanate composition and a diamine hydrochloride composition used in the preparation of an optical lens is adjusted to a specific range, whereby it is possible to enhance not only the yield and purity of the diisocyanate composition but also the optical characteristics of the final optical lens by suppressing the striae and cloudiness. Specifically, according to the process of the embodiment, the amount of an aqueous hydrochloric acid solution introduced to the reaction may be adjusted to control the pH of the diisocyanate composition to a desired range, thereby enhancing the yield and purity. Accordingly, the process for preparing a diisocyanate composition according to the embodiment can be applied to the preparation of a plastic optical lens of high quality.