Kerosene boiling range or jet fuel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. The resulting kerosene boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight ratio, a low but substantial aromatics content, and a low sulfur content. Such fractions can potentially be used as fuel after a reduced or minimized amount of additional refinery processing. By reducing, minimizing, or avoiding the amount of refinery processing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

A method of desulfurizing a liquid hydrocarbon having the steps of: adding a liquid hydrocarbon to a vessel, the hydrocarbon having a sulfur content; adding a catalyst and an oxidizer to create a mixture; oxidizing at least some of the sulfur content of the liquid hydrocarbon to form oxidized sulfur in the liquid hydrocarbon; separating the liquid hydrocarbon from the mixture; and removing at least some of the oxidized sulfur from the liquid hydrocarbon. Such methods can be carried out by batch or continuously. Systems for undertaking such methods are likewise disclosed.

The removal of poisonous metalloids from crude oil is a method of removing naturally occurring arsenic (As), antimony (Sb), and bismuth (Bi) from crude oil before the crude oil is processed through a refinery. The removal of poisonous metalloids from crude oil entails forming an emulsion comprising the crude oil and an inorganic salt or mineral acid solution prepared by recirculation and agitation. The agitation of the emulsion causes arsenic (As), antimony (Sb), and bismuth (Bi) containing compounds to dissolve in the inorganic salt or mineral acid solution. The crude oil is separated from the inorganic salt or mineral acid solution by settling. The treated crude oil has a poisonous metalloid concentration of less than 1 ppm making it acceptable for oil refining operations. Optionally, any inorganic salt or mineral acid solution remaining in the crude oil after separation can be removed using a silica gel dryer.

Kerosene boiling range or jet fuel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. The resulting kerosene boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight ratio, a low but substantial aromatics content, and a low sulfur content. Such fractions can potentially be used as fuel after a reduced or minimized amount of additional refinery processing. By reducing, minimizing, or avoiding the amount of refinery processing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

A method of desulfurizing a liquid hydrocarbon having the steps of: adding a liquid hydrocarbon to a vessel, the hydrocarbon having a sulfur content; adding a catalyst and an oxidizer to create a mixture; oxidizing at least some of the sulfur content of the liquid hydrocarbon to form oxidized sulfur in the liquid hydrocarbon; separating the liquid hydrocarbon from the mixture; and removing at least some of the oxidized sulfur from the liquid hydrocarbon. Such methods can be carried out by batch or continuously. Systems for undertaking such methods are likewise disclosed.

Methods are provided for treatment of kerosene/jet fuel boiling range fractions, such as previously qualified jet fuel fractions, to allow blending of the kerosene/jet fuel boiling range fractions to produce a jet fuel boiling range blend having a breakpoint that is equal to or greater than the breakpoint of at least one of the kerosene jet fuel boiling range fractions used to form the blend. The breakpoint of the jet fuel boiling range blend can be maintained by treating at least one of the component fractions of the blend and/or by treating the blend to reduce a nitrogen content. The reduced nitrogen content can correspond to a reduced content of total nitrogen and/or a reduced content of unexpected nitrogen compounds.

Methods are provided for treatment of kerosene/jet fuel boiling range fractions, such as previously qualified jet fuel fractions, to allow blending of the kerosene/jet fuel boiling range fractions to produce a jet fuel boiling range blend having a breakpoint that is equal to or greater than the breakpoint of at least one of the kerosene jet fuel boiling range fractions used to form the blend. The breakpoint of the jet fuel boiling range blend can be maintained by treating at least one of the component fractions of the blend and/or by treating the blend to reduce a nitrogen content. The reduced nitrogen content can correspond to a reduced content of total nitrogen and/or a reduced content of unexpected nitrogen compounds.

A method of desulfurizing a liquid hydrocarbon having the steps of: adding a liquid hydrocarbon to a vessel, the hydrocarbon having a sulfur content; adding a catalyst and an oxidizer to create a mixture; oxidizing at least some of the sulfur content of the liquid hydrocarbon to form oxidized sulfur in the liquid hydrocarbon; separating the liquid hydrocarbon from the mixture; and removing at least some of the oxidized sulfur from the liquid hydrocarbon. Such methods can be carried out by batch or continuously. Systems for undertaking such methods are likewise disclosed.

A light naphtha feedstock containing olefins is introduced with hydrogen sulfide into a mercaptanization zone for conversion of the olefins into a mercaptan stream that is substantially free of olefins, after which the mercaptans are sent with an alkali caustic solution into a mercaptan oxidation treatment unit (MEROX) to produce a spent caustic stream and sweet light naphtha product stream that is substantially free of olefins and of mercaptans. Disulfide oils are produced from the wet air oxidation of the spent caustic, and the disulfide oils can be further processed to provide high purity olefin building blocks.

The present application provides a one-step refining process of a hydrocarbon feedstock, said process comprising heating said hydrocarbon feedstock with one or more fatty acids or mixtures thereof, at a temperature below 350 C., to obtain a light hydrocarbon product, wherein said light hydrocarbon product obtained in said process contains no heavy hydrocarbons products.