A distillation apparatus for use in microwave-assisted pyrolysis includes a microwave, a pyrolysis reactor, a microwave-absorbent bed, and a condenser. The pyrolysis reactor is located within the microwave and configured to receive a liquid input stream and to output a vapor. The microwave-absorbent bed is located within the pyrolysis reactor that converts microwave energy provided by the microwave to thermal energy to initiate pyrolysis within the pyrolysis reactor, wherein the pyrolysis reactor provides a vapor output. The condenser is configured to receive the vapor output of the pyrolysis reactor and to cool and condense the vapor into a recoverable product.

A method of producing a hydrocarbon fuel from a soapstock includes supplying a pyrolysis reactor that includes a microwave absorbent bed susceptible to microwave irradiation, applying microwave energy to the pyrolysis reactor, wherein the microwave absorbent bed converts the microwave energy to thermal energy, supplying the soapstock to the microwave absorbent bed, and condensing a vapor generated by pyrolysis of the soapstock sufficient to collect the hydrocarbon fuel.

Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction including naphtha and diesel and a vacuum gas oil fraction; and feeding the distillate fraction to a three step hydrotreating operation. The three step hydrotreating operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream, feeding the first product stream to a second hydrotreating unit to remove mono-olefins to produce a second product stream; and feeding the second product stream to a third hydrotreating unit to remove sulfur and nitrogen by hydrodesulfurization and hydrodenitrogenation to produce a third product stream. Such system may be integrated with a conventional refinery.

Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction including naphtha and diesel and a vacuum gas oil fraction; and feeding the distillate fraction to a three step hydrotreating operation. The three step hydrotreating operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream, feeding the first product stream to a second hydrotreating unit to remove mono-olefins to produce a second product stream; and feeding the second product stream to a third hydrotreating unit to remove sulfur and nitrogen by hydrodesulfurization and hydrodenitrogenation to produce a third product stream. Such system may be integrated with a conventional refinery.

A method for reducing or preventing corrosion or fouling in an apparatus for carrying out a chemical process, where corrosion or fouling is caused by acidic compounds present in the chemical process, which comprises the addition of at least one quaternary ammonium hydroxide of the formula (I) to the apparatus, wherein the chemical process is carried out: [Chem. 1] where R.sup.1, R.sup.2, R.sup.3 are each independently C.sub.1-C.sub.10 alkyl; R.sup.4 is inter alia C.sub.1-C.sub.18 alkyl, benzyl, monocycloalkyl having 5, 6, 7 or 8 carbon atoms, bicycloalkyl having 6 to 8 carbon atoms, tricycloalkyl having 7 to 10 carbon atoms, where monocycloalkyl, bicycloalkyl and tricycloalkyl are unsubstituted or substituted by 1 or 2 methyl groups, or tri-C.sub.1-C.sub.4 alkyl ammonium groups. R.sup.1 and R.sup.2 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups; and/or R.sup.3 and R.sup.4 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups.

A processing facility is provided that includes a feedstock separation system configured to separate a feed stream into a lights stream and a heavies stream, a hydrogen production system configured to produce hydrogen and carbon dioxide from the lights stream, and a carbon dioxide conversion system configured to produce synthetic hydrocarbons or the carbon dioxide. The processing facility also includes a hydroprocessing system configured to process the heavies stream, and a hydroprocessor separation system configured to separate a hydroprocessing system effluent into a separator tops stream and a separator bottoms stream, wherein the separator bottoms stream is fed to the hydrogen production system.

Systems and methods for crude oil separation and upgrading, which include the ability to reduce aromatic complex bottoms content in gasoline and higher-quality aromatic compounds. In some embodiments, aromatic complex bottoms are recycled for further processing. In some embodiments, aromatic complex bottoms are separated for further processing.

Systems and integrated methods are disclosed for processing aromatic complex bottoms into high value products. The system includes an adsorption column, the adsorption column in fluid communication with an aromatics complex and operable to receive and remove polyaromatics from an aromatic bottoms stream. The adsorption column producing a cleaned aromatic bottoms stream with reduced polyaromatic content and a reject stream including the removed polyaromatics. In some embodiments, the reject stream is recycled for further processing, passed to a coke production unit to produce high quality coke, or both.

A bifunctional catalyst for example for conversion of oxygenates, the bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl.sub.2O.sub.4.

A bifunctional catalyst for example for conversion of oxygenates, the bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl.sub.2O.sub.4.