Catalytic conversion of ketoacids is disclosed, including methods for increasing the molecular weight of ketoacids. An exemplary method includes providing in a reactor a feedstock having at least one ketoacid. The feedstock is then subjected to one or more C—C-coupling reaction(s) in the presence of a catalyst system having a first metal oxide and a second metal oxide.

Catalytic conversion of ketoacids is disclosed, including methods for increasing the molecular weight of ketoacids. An exemplary method includes providing in a reactor a feedstock having at least one ketoacid. The feedstock is then subjected to one or more C—C-coupling reaction(s) in the presence of a catalyst system having a first metal oxide and a second metal oxide.

Systems and methods are provided for integrated conversion of biomass to ultimately form naphtha and/or diesel boiling range products. The integrated conversion can include an initial conversion of biomass to alcohols, such as by fermentation, followed by conversion of alcohols to olefins and then olefins to naphtha, jet, and diesel boiling range compounds, with high selectivity for formation of diesel boiling range compounds. The integrated conversion process can be facilitated by using a common catalyst for both the conversion of alcohols to olefins and the conversion of olefins to naphtha and/or diesel boiling range compounds. For example, ZSM-48 (an MRE zeotype framework structure catalyst) can be used as the catalyst for both conversion of alcohols to olefins and for oligomerization of olefins with increased selectivity for formation of diesel boiling range products.

A process to catalytically transform natural gas liquid (NGL) into higher molecular weight hydrocarbons includes providing an NGL stream, catalytically dehydrogenating at least a portion of the NGL stream components to their corresponding alkene derivatives, catalytically oligomerizing at least a portion of the alkenes to higher molecular weight hydrocarbons and recovering the higher molecular weight hydrocarbons. The NGL stream can be extracted from a gas stream such as a gas stream coming from shale formations. The higher molecular weight hydrocarbons can be hydrocarbons that are liquid at ambient temperature and ambient pressure.

A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

A nonlimiting example method for producing a diesel boiling range composition comprises: oligomerizing an ethylene stream to a C4+ olefin stream in a first olefin oligomerization unit, wherein the C4+ olefin stream contains no greater than 10 wt% of methane, ethylene, and ethane combined in a first oligomerization; and wherein the ethylene stream contains at least 50 wt% ethylene, at least 2000 wppm ethane, no greater than 1000 wppm of methane, and no greater than 20 wppm each of carbon monoxide and hydrogen; oligomerizing the C4+ olefin stream and a propylene/C4+ olefin stream in a second oligomerization unit to produce an isoolefinic stream; wherein at least a portion of the isoolefinic stream is used to create the diesel boiling range composition.

The present disclosure is directed to microporous crystalline aluminosilicate structures with GME topologies having pores containing organic structure directing agents (OSDAs) comprising at least one piperidinium cation, the compositions useful for making these structures, and methods of using these structures. In some embodiments, the crystalline zeolite structures have a molar ratio of Si:Al that is greater than 3.5.

The present disclosure is directed to microporous crystalline aluminosilicate structures with GME topologies having pores containing organic structure directing agents (OSDAs) comprising at least one piperidinium cation, the compositions useful for making these structures, and methods of using these structures. In some embodiments, the crystalline zeolite structures have a molar ratio of Si:Al that is greater than 3.5.

Method of producing pyrolysis products from mixed plastics along with an associated system for processing mixed plastics. The method includes conducting pyrolysis of a plastic feedstock to produce plastic pyrolysis oil; feeding the plastic pyrolysis oil to a first fractionator to separate the plastic pyrolysis oil into a distillate fraction and a vacuum gas oil fraction; and feeding the distillate fraction to a two step oligomerization operation. The two step oligomerization operation includes feeding the distillate fraction to a first hydrotreating unit to remove di-olefins to produce a first product stream and feeding the first product stream to an olefin oligomerization reactor to react and combine mono-olefins into longer chain olefins. Such system may be integrated with a conventional refinery.

A method for the aromatization of hydrocarbons, comprising: introducing a feed stream to an aromatization catalyst in a fixed bed reactor wherein the feed stream comprises a hydrocarbon having 2 to 4 carbon atoms, converting the hydrocarbon having 2 to 4 carbon atoms to form an outlet stream comprising an aromatic hydrocarbon; wherein the feed stream is introduced at a GHSV of greater than or equal to 4,000 milliliters per gram of catalyst per hour(ml.Math.g.sup.−1 Cat.Math.h.sup.−1), and a pressure of greater than or equal to 0.4 MPa. The feed stream can comprise hydrogen in an amount of at least 0.1 volume percent (vol %) up to 20 vol % based upon total volume of the feed stream.