The invention relates to a method including a system of additives which increase fluidity and/or flow capacity and minimize pressure drops from the steps of lifting in production wells, collection lines, dehydration systems and ducts for transporting heavy and extra-heavy hydrocarbons. In addition, the injected system of chemical additives increases the dilution capacity of the solvents that need to be applied to improve the quality of the crude oil (reduce viscosity and density, and increase API gravity), thereby facilitating the dehydration and transport.

The invention relates to a method including a system of additives which increase fluidity and/or flow capacity and minimize pressure drops from the steps of lifting in production wells, collection lines, dehydration systems and ducts for transporting heavy and extra-heavy hydrocarbons. In addition, the injected system of chemical additives increases the dilution capacity of the solvents that need to be applied to improve the quality of the crude oil (reduce viscosity and density, and increase API gravity), thereby facilitating the dehydration and transport.

This invention relates to drag reducing agents used in case of transportation of crude oil products, in particular, to solid dry poly(meth)acrylate with dry poly alpha-olefins powders based agents. The technical result of the solution involves the preparation of an effective, fast-dissolving, stable solid dry drag reducing agent suitable for use in heavy crude oil. The drag reducing agents compositions have better drag reducing performance in heavy crude applications as compared with traditional drag reducing slurries is also disclosed, which consists of the following components, wt%: a mixture of at least two drag reducing polymers, from 65 to 90 a separating agent from 3 to 25 anti-agglomerating agent from 3 to 25 a surfactant from 3 to 25,where the first polymer is poly(meth)acrylate, the second polymer is poly alpha-olefin, the ratio of the polyacrylate weight and polyalphaolefin weight varies in the range from 2:1 to 5:1.

This invention relates to drag reducing agents used in case of transportation of crude oil products, in particular, to solid dry poly(meth)acrylate with dry poly alpha-olefins powders based agents. The technical result of the solution involves the preparation of an effective, fast-dissolving, stable solid dry drag reducing agent suitable for use in heavy crude oil. The drag reducing agents compositions have better drag reducing performance in heavy crude applications as compared with traditional drag reducing slurries is also disclosed, which consists of the following components, wt%: a mixture of at least two drag reducing polymers, from 65 to 90 a separating agent from 3 to 25 anti-agglomerating agent from 3 to 25 a surfactant from 3 to 25,where the first polymer is poly(meth)acrylate, the second polymer is poly alpha-olefin, the ratio of the polyacrylate weight and polyalphaolefin weight varies in the range from 2:1 to 5:1.

In one embodiment, an alkylphenol copolymer is disclosed wherein the copolymer comprises at least one alkylphenol monomer and the alkylphenol copolymer exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −5° C. in a first oscillation temperature sweep and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C. In a further embodiment, a petroleum composition is disclosed wherein the composition comprises a petroleum source and a macromolecular compound wherein the macromolecular compound exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −10° C. in a first oscillation temperature sweep, and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C.

In one embodiment, an alkylphenol copolymer is disclosed wherein the copolymer comprises at least one alkylphenol monomer and the alkylphenol copolymer exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −5° C. in a first oscillation temperature sweep and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −5° C. In a further embodiment, a petroleum composition is disclosed wherein the composition comprises a petroleum source and a macromolecular compound wherein the macromolecular compound exhibits the following: an oscillation displacement Θ of greater than 0 at a temperature of −10° C. in a first oscillation temperature sweep, and an oscillation displacement Θ in a second oscillation temperature sweep within 25% of the oscillation displacement Θ in the first oscillation temperature sweep at a temperature of −10° C.

Methods of reducing drag in a flowing hydrocarbon include introducing to the flowing hydrocarbon an amount of a solid drag reducing additive effective to improve the flow, the solid drag reducing additive including a polymer particle prepared from at least one polar monomer and a percent by weight (wt%) of liquid of 50 wt% or less. Methods also include producing a solid drag reducing additive that includes forming a polymer from at least one polar monomer by emulsion polymerization; and disrupting the emulsion by adding at least one demulsifier and at least one anti-blocking agent to form the solid drag reducing additive. Compositions include a solid drag reducing additive comprising a polymer prepared from at least one polar monomer and having an average particle size in a range of about 100 .Math.m to about 500 .Math.m, wherein the solid drag reducing additive comprises less than 50 wt% of liquid.

Methods of reducing drag in a flowing hydrocarbon include introducing to the flowing hydrocarbon an amount of a solid drag reducing additive effective to improve the flow, the solid drag reducing additive including a polymer particle prepared from at least one polar monomer and a percent by weight (wt%) of liquid of 50 wt% or less. Methods also include producing a solid drag reducing additive that includes forming a polymer from at least one polar monomer by emulsion polymerization; and disrupting the emulsion by adding at least one demulsifier and at least one anti-blocking agent to form the solid drag reducing additive. Compositions include a solid drag reducing additive comprising a polymer prepared from at least one polar monomer and having an average particle size in a range of about 100 .Math.m to about 500 .Math.m, wherein the solid drag reducing additive comprises less than 50 wt% of liquid.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.