Improvements to the gasifier furnace design and process method to facilitate continuous production of mainly H.sub.2, CO and granulated solid from molten liquid or the liquid slag in the presence of carbonaceous material. It is a method of quenching molten liquid and cooling post quenched hot granulated solid which is done within a long horizontal reaction chamber space of the furnace in the presence of C and H.sub.2O. A moving layer of continuously gas cooled granulated solid protects the moving floor underneath by substantially reducing the possibility of heat transfer from the horizontal reaction chamber to such moving floor and its parts and preventing direct contact between the post quenched hot solid granulates and such moving floor. Such moving floor having plurality of gas passages and is disposed above a plenum that receives gas from outside source and uniformly distributes the gas to pass through all the gas passages.

The present invention discloses a device and method for generating high-purity hydrogen by biomass pyrolysis-chemical looping combustion. The device comprises a biomass pyrolysis unit, a chemical looping hydrogen generation unit and a waste heat recovery unit; the biomass pyrolysis unit comprises a vertical bin, a screw feeder, a rotary kiln pyrolysis reactor and a high temperature filter; the chemical looping hydrogen generation unit comprises a path switching system of intake gas end, at least one packed bed reactor and a path switching system of tail gas end, wherein the packed bed reactor is composed of three parallel packed bed reactors I, II and III, which are continuously subjected to fuel reduction-steam oxidation-air combustion stages (steam purging stage) successively; the waste heat recovery unit comprises a waste heat boiler, a cooler and a gas-liquid separator. According to the present invention, a process flow of generating hydrogen from biomass is short, high-purity hydrogen can be obtained by simple condensation and water removal of a hydrogen-containing product that is generated after entrance of a pyrolysis gas into the chemical looping hydrogen generation unit, no complex gas purification device is employed, and the costs for hydrogen generation are low.

Disclosed are a pulverized coal preprocessing method and a pulverized coal gasifying method. The pulverized coal preprocessing method comprises the following steps: (1) performing pore broadening on pulverized coal to obtain preprocessed pulverized coal; (2) loading alkali metal ions into the preprocessed pulverized coal under an ion exchange condition to obtain alkali metal loaded pulverized coal. The method further comprises loading a chrome complex into the alkali metal loaded pulverized coal obtained in described step (2). In gasification, the pulverized coal loaded with alkali metal potassium and chrome catalysts obtained by the method has the advantages of high sulphur removal rate, high carbon conversion rate, short gasifying reaction time and high methane production.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.

A plant and a method for the production of hydrogen and bicarbonate. The plant includes a gasifier, a reformer, a direct contact exchanger and an apparatus for the production of bicarbonate. The plant is suitable for receiving fuel, oxygen, water, carbonate, brine at the inlet and for producing hydrogen, bicarbonate and calcium chloride at the outlet. The plant uses a self-cleaning direct contact heat exchanger to cool the syngas downstream of the reformer and to produce the superheated steam that feeds the gasifier: this heat exchanger allows the production of hydrogen at low costs and in modular plants.

The present invention describes a mixture comprising carbonaceous raw material of low value as a fuel and a nanocatalyst. The catalytic mixture comprises from 1% to 50% by weight of a nanocatalyst; and from 99% to 50% by weight of carbonaceous raw material selected from petroleum coke, coal, heavy residual fraction of oil, or a mixture thereof. The nanocatalyst comprises a carbon nanomaterial of between 99.99% and 80% by weight in contents and at least one alkali metal of between 0.01% and 20% by weight in contents, based on the total weight of the nanocatalyst, and the specific surface area of the nanocatalyst ranges between 400 and 1300 m2/g. Furthermore, the present invention also describes a process for gasifying the catalytic mixture which comprises the steps of placing the mixture in a gasifier; heating the mixture in the presence of an oxidizing agent selected from air, pure oxygen, carbon dioxide, water vapor, or a mixture thereof at a temperature ranging between 200 and 1,300° C.; and obtaining a gaseous product comprising H2, CO, CO2, CH4.

A waste treatment, pyrolysis and gasification and concerns an apparatus for syngas bio-methanation include a unit for pyrolysis/gasification receiving organic material, the unit for pyrolysis/gasification generating syngas, comprising at least one membrane reactor inside a liquid bath comprising at least one bacteria population, the membrane reactor comprising at least one hollow fiber in contact with the liquid bath, around which a biofilm is formed and into which the syngas from the unit for pyrolysis/gasification flows, so as to convert the syngas into methane. A method for bio-methanation of syngas comprising a step of providing syngas from a unit for pyrolysis/gasification to a membrane reactor inside a liquid bath comprising at least one suitable bacteria population, the membrane reactor comprising at least one hollow fiber in contact with the liquid bath, around which a biofilm is formed and into which the output syngas of the unit for pyrolysis flows, so as to convert the syngas into methane.

Chemical recycling facilities for processing mixed waste plastic are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy recovery facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

A chemical recycling process and facility for turning one or more waste plastics into syngas are provided. Generally, the chemical recycling process involves: (a) liquefying at least one solid waste plastic to form a liquefied waste plastic; (b) introducing at least a portion of the liquefied waste plastic into a partial oxidation (POX) gasifier; and (c) converting at least a portion of the liquefied waste plastic in the POX gasifier into a syngas composition.

An integrated biomass conversion system and a method of starting and shutting down the system are disclosed. The integrated biomass conversion system comprises a syngas generator, such as a gasifier, a cleanup engine and a syngas utilization system, which could be a power producing engine or a chemical reactor for chemical or fuel synthesis. The cleanup engine operates rich and at high temperatures so that the tars exhausted by the syngas generators are destroyed and not allowed to foul other components. An orderly sequence to start and shut down the integrated biomass conversion system is disclosed.