This invention relates to polymer-based partially-open, hollow reservoirs in the nano-size to micro-size range that encapsulate an additive, which can be released from the reservoirs using specific event stimuli such as reduction-oxidation and voltage change, or at will, using the same stimuli. This invention also relates to method preparing such reservoirs, and for releasing the additive. This invention further relates to matrix that comprises such reservoirs and the method of preparing such matrix. This invention also relates to applications, for example in corrosion inhibition, lubrication, and adhesion, that benefit from using such a controlled release of an additive.

Lubricating oil has a kinematic viscosity in a range of 1 mm.sup.2/S to 7 mm.sup.2/S at 40° C., has a mass average molecular weight in a range of 150 to 400, and contains 0.5% by mass or more of a high molecular weight component. The high molecular weight component has a mass molecular weight of greater than or equal to 500. A crankshaft serving as a shaft part of a compression element includes a main shaft that includes a sliding surface. In a case where the sliding surface is a single sliding surface, a length of the single sliding surface in an axial direction is a single sliding length L, whereas in a case where the sliding surface is divided into a plurality of sliding surfaces, a length of one of the sliding surfaces in the axial direction, the one sliding surface having a least length in the axial direction among the plurality of sliding surfaces, is the single sliding length L, and a ratio L/D of the single sliding length L to an external diameter D of the main shaft is less than or equal to 2.0.

A magnetorheological fluid is provided having a reduced coefficient of friction and favorable settling characteristics. The fluid contains magnetically responsive particles, a carrier fluid, and an amine oleate salt.

With the present invention, sustainable systems for corrosion, inhibition in the processing of metals (in particular iron, aluminum and magnesium) are made available. These systems being in full accordance with the principles of green chemistry comprise an amino acid as neutralizing component for an acidic corrosion inhibitor, whereby the amino acid is used in deprotonated form. The resulting metalworking fluids may be water- or oil-based or semi synthetic formulations. The neutralization of acidic corrosion inhibitors with the claimed system comprising an amino acid consistently achieves convincing results and, together with acidic corrosion inhibitors from corresponding sources, completely renewable systems for corrosion inhibition are provided.

The present disclosure describes lubricant compositions effective to minimize average engine sludge through selection of lubricant additives that control the total nitrogen as well as the origin of the nitrogen in the lubricant composition. In aspects, the lubricant compositions herein include at least a base oil of lubricating viscosity, a dispersant system, and at least one antioxidant.

Lubricating compositions comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The lubricating composition also comprises an antiwear agent. Methods of lubricating an internal combustion engine comprise contacting the internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. Methods of reducing lubricant oxidation and/or corrosion in an internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The use of a comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative to reduce lubricant oxidation and/or corrosion in an internal combustion engine.

A lubricant composition of an oil of lubricating viscosity, a grafted copolymer viscosity modifier that is an ashless condensation reaction product of an olefin polymer, having a number average molecular weight of about 1000 to about 10,000, comprising carboxylic acid or equivalent functionality grafted onto the polymer backbone, with a monoamine or a polyamine often having a single primary amino group, which exhibits good dispersancy and viscometric performance in a driveline device.

Lubricating compositions comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, or compounds having at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of a mercaptoazole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.

A magnetorheological fluid is provided having a reduced coefficient of friction and favorable settling characteristics. The fluid contains magnetically responsive particles, a carrier fluid, and an amine oleate salt.

Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of:

from about 38% by weight to about 48% by weight difluoromethane (HFC-32),
from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125),
from about 33% by weight to about 41% by weight trifluoroiodomethane (CF.sub.3I) and
from about 2% by weight to about 16% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)
wherein the percentages are based on the total weight of the three compounds in the blend, and methods and systems which use same.