Provided herein are new aluminum alloys comprising Ca, Mg and/or Zn and new coated aluminum alloys comprising surface layers (e.g., coatings) comprising Ca, Mn, Zn, and/or Ni that can be used in aluminum alloy products, such as clad layers. Also provided are methods of making these aluminum alloys, coated aluminum alloys, and clad layers, as well as clad products. These alloys, coated alloys, clad layers, and products possess a combination of strength and other key attributes, such as corrosion resistance, formability, and applicability of paint line pretreatments. The materials can be used in a variety of applications, including automotive, transportation, and electronics applications.

Provided is a surface hardening method for surface hardening a sulfuric acid-anodized aluminum alloy oxide layer, which includes: pre-treatment in which various foreign substances, including an oxide film, attached to a surface of an aluminum alloy are removed; sealing treatment in which the aluminum alloy having been subjected to the pre-treatment is immersed in a sealing solution, whereby fine pores formed in a film are sealed; and heat treatment in which the aluminum alloy having been subjected to the sealing treatment is charged to, and thermally treated in, a heat treatment furnace and then naturally cooled. By lowering the withstand voltage of an aluminum alloy oxide layer and increasing the hardness by subjecting the same to sealing treatment and subsequent post-heat treatment, the present invention has the effect of providing an environmentally-friendly and crack-free lightweight material that can replace steel products.

Provided is a surface hardening method for surface hardening a sulfuric acid-anodized aluminum alloy oxide layer, which includes: pre-treatment in which various foreign substances, including an oxide film, attached to a surface of an aluminum alloy are removed; sealing treatment in which the aluminum alloy having been subjected to the pre-treatment is immersed in a sealing solution, whereby fine pores formed in a film are sealed; and heat treatment in which the aluminum alloy having been subjected to the sealing treatment is charged to, and thermally treated in, a heat treatment furnace and then naturally cooled. By lowering the withstand voltage of an aluminum alloy oxide layer and increasing the hardness by subjecting the same to sealing treatment and subsequent post-heat treatment, the present invention has the effect of providing an environmentally-friendly and crack-free lightweight material that can replace steel products.

This application discloses aluminum alloy products, such as can body stock and can end stock, that have improved processing qualities in high-speed production equipment due to engineered surfaces. For can body stock, processing is improved by providing at least two different surface roughnesses. For can end stock, processing is improved by reducing anisotropy at least at the top and bottom surfaces of the can end stock.

This application discloses aluminum alloy products, such as can body stock and can end stock, that have improved processing qualities in high-speed production equipment due to engineered surfaces. For can body stock, processing is improved by providing at least two different surface roughnesses. For can end stock, processing is improved by reducing anisotropy at least at the top and bottom surfaces of the can end stock.

The casting alloy according to the invention is based on aluminum-iron-nickel and includes the following elements:

TABLE-US-00001 iron 0.8 to 3.0% by weight nickel 0.1 to 3.5% by weight boron 40 to 300 ppm zinc 0-5% by weight tin 0-5% by weight copper 0-3% by weight manganese 0-1% by weight magnesium 0-0.6% by weight phosphorus 0-500 ppm Silicon 0-0.4%.

The casting alloy according to the invention is based on aluminum-iron-nickel and includes the following elements:

TABLE-US-00001 iron 0.8 to 3.0% by weight nickel 0.1 to 3.5% by weight boron 40 to 300 ppm zinc 0-5% by weight tin 0-5% by weight copper 0-3% by weight manganese 0-1% by weight magnesium 0-0.6% by weight phosphorus 0-500 ppm Silicon 0-0.4%.

An aluminum alloy additive manufacturing product and a method manufactures the same. The aluminum alloy additive manufacturing product is formed by molding a raw metal by an additive manufacturing method. The raw metal is made of an aluminum alloy. The aluminum alloy contains Fe and one or more of Mn and Cr. The Fe is an inevitable impurity of 0.3 weight % or less. The one or more of Mn and Cr have a total weight of 0.3 to 10 weight %. The aluminum alloy additive manufacturing product contains any one or more of an intermetallic compound and an aluminum alloy solid solution. The intermetallic compound contains two or more of Al, Mn, Fe, and Cr. One or more elements of Mn, Fe, and Cr are dissolved in the aluminum alloy solid solution.

A method for combined rolling and extruding of cast billet is proposed. When implementing the method for combined rolling and extruding of metals or alloys, a cast billet with a predetermined temperature is fed to the working gauge, in which it is rolled and then to the die, through which the cast billet is extruded. When the cast billet is fed into the working gauge, a cladding layer of metal or alloy is created on the surfaces of the rolls by extruding the cast billet through the gaps formed between the surfaces of the rolls and the die. This invention makes it possible to improve the quality of the resulting products, as well as to increase the efficiency of the process as a whole.

A method for combined rolling and extruding of cast billet is proposed. When implementing the method for combined rolling and extruding of metals or alloys, a cast billet with a predetermined temperature is fed to the working gauge, in which it is rolled and then to the die, through which the cast billet is extruded. When the cast billet is fed into the working gauge, a cladding layer of metal or alloy is created on the surfaces of the rolls by extruding the cast billet through the gaps formed between the surfaces of the rolls and the die. This invention makes it possible to improve the quality of the resulting products, as well as to increase the efficiency of the process as a whole.