Disclosed herein is a method for forming metal-oxides in the photoresist to improve profile control. The method includes infiltrating a metal oxide in a photoresist layer by pressurizing a methyl-containing material in a processing environment proximate a film stack. The film stack includes the photoresist layer, the photoresist layer being disposed on top of and in contact with an underlayer. The underlayer disposed on top of a substrate. The method includes etching the film stack including the photoresist layer implanted with the metal oxide.

Disclosed herein is a method for forming metal-oxides in the photoresist to improve profile control. The method includes infiltrating a metal oxide in a photoresist layer by pressurizing a methyl-containing material in a processing environment proximate a film stack. The film stack includes the photoresist layer, the photoresist layer being disposed on top of and in contact with an underlayer. The underlayer disposed on top of a substrate. The method includes etching the film stack including the photoresist layer implanted with the metal oxide.

A process for protecting a part made of a hafnium-free nickel-based single-crystal superalloy against corrosion and oxidation includes manufacturing a part made of a hafnium-free nickel-based single-crystal superalloy, depositing successively on the part, a first layer including hafnium, then a mixed layer of stacked layers of an undercoat of an alloy having 10 atomic % or more of aluminum and a second layer including hafnium or a mixed layer of an alloy of aluminum and hafnium, and then a third layer including hafnium, and diffusing and performing an oxidation treatment so as to obtain a hafnium-doped alumina layer.

A process for protecting a part made of a hafnium-free nickel-based single-crystal superalloy against corrosion and oxidation includes manufacturing a part made of a hafnium-free nickel-based single-crystal superalloy, depositing successively on the part, a first layer including hafnium, then a mixed layer of stacked layers of an undercoat of an alloy having 10 atomic % or more of aluminum and a second layer including hafnium or a mixed layer of an alloy of aluminum and hafnium, and then a third layer including hafnium, and diffusing and performing an oxidation treatment so as to obtain a hafnium-doped alumina layer.

A slurry and a coating method are provided. The slurry includes, by weight, between 10% and 40% metal powder, between 10% and 15% activator, between 10% and 20% adhesive, between 10% and 20% thickener, up to 30% ceramic, and up to 25% binder. The coating method includes providing a slurry including, by weight, between 10% and 40% metal powder, between 10% and 15% activator, between 10% and 20% adhesive, between 10% and 20% thickener, up to 30% ceramic, and up to 25% organic polymer binder, providing a substrate, applying the slurry over a surface of the substrate to form a slurry coating, drying the slurry coating over the substrate, baking the substrate and the slurry coating, and curing the slurry coating over the substrate. The curing the slurry coating over the substrate transfers metal elements of the metal powder in the slurry to the substrate to form a coating on the substrate.

A slurry and a coating method are provided. The slurry includes, by weight, between 10% and 40% metal powder, between 10% and 15% activator, between 10% and 20% adhesive, between 10% and 20% thickener, up to 30% ceramic, and up to 25% binder. The coating method includes providing a slurry including, by weight, between 10% and 40% metal powder, between 10% and 15% activator, between 10% and 20% adhesive, between 10% and 20% thickener, up to 30% ceramic, and up to 25% organic polymer binder, providing a substrate, applying the slurry over a surface of the substrate to form a slurry coating, drying the slurry coating over the substrate, baking the substrate and the slurry coating, and curing the slurry coating over the substrate. The curing the slurry coating over the substrate transfers metal elements of the metal powder in the slurry to the substrate to form a coating on the substrate.

Provide a metal surface reforming method enabling metallic products with superior characteristics such as surface hardness, heat resistance, corrosion resistance, high temperature oxidation, high temperature corrosion, and environmental corrosion and the like.

Halogenation treatment of heating and retaining a base material in an atmosphere containing a halogen based gas is performed on a base material of iron based metal or nickel based metal, then nitride processing of heating and retaining the halogenated base material described above in an atmosphere containing a nitrogen source gas is performed, then chromizing treatment is performed by placing the nitrided base material in a powder containing metal chromium powder to form a surface reformed layer on the base material described above. These metallic products obtained have high hardness, superior heat resistance and corrosion resistance, and exhibit superior performance in high temperature oxidation, high temperature corrosion, erosion, and cavitation and the like environments. Further, the metallic products described above exhibit superior performance in acid or alkali environments, neutral environments, and corrosive environments such as chlorides like salt water.

Provide a metal surface reforming method enabling metallic products with superior characteristics such as surface hardness, heat resistance, corrosion resistance, high temperature oxidation, high temperature corrosion, and environmental corrosion and the like.

Halogenation treatment of heating and retaining a base material in an atmosphere containing a halogen based gas is performed on a base material of iron based metal or nickel based metal, then nitride processing of heating and retaining the halogenated base material described above in an atmosphere containing a nitrogen source gas is performed, then chromizing treatment is performed by placing the nitrided base material in a powder containing metal chromium powder to form a surface reformed layer on the base material described above. These metallic products obtained have high hardness, superior heat resistance and corrosion resistance, and exhibit superior performance in high temperature oxidation, high temperature corrosion, erosion, and cavitation and the like environments. Further, the metallic products described above exhibit superior performance in acid or alkali environments, neutral environments, and corrosive environments such as chlorides like salt water.

Treated articles and a process of producing the treated articles, systems having treated articles, and processes incorporating treated articles are disclosed. The treated articles include a metal or metallic substrate, and a surface treatment of the metal or metallic substrate, the surface treatment having fluorine, silicon, and carbon. The systems include a flow path, with the surface treatment being within the flow path. The processes include flowing a fluid through the flow path.

Methods of forming an environmental barrier coating are disclosed. A method includes disposing a powder-based coating on a substrate, heat-treating the powder-based coating at a temperature greater than 800° C. and less than 1200° C. to form a porous coating that includes surface-connected pores, infiltrating at least some of the surface-connected pores of the porous coating with an infiltrant material to form an infiltrated coating, and sintering the infiltrated coating at a temperature greater than 1200° C. and less than 1500° C. to form the environmental barrier coating on the substrate.