A method of cleaning a condensate thermosyphon reboiler including modifying a flow rate of a hot oil stream introduced into the tube-side of a first condensate thermosyphon reboiler, modifying a flow rate of a condensate hydrocarbon stream introduced into the shell-side of the first condensate thermosyphon reboiler, and maintaining an operation of the condensate stabilizer system until the value of an overhead temperature of the first condensate thermosyphon reboiler is detected to have been modified from the first overhead temperature to a second overhead temperature. The method further includes modifying the flow rate of the condensate hydrocarbon stream from the second condensate flow rate to the first condensate flow rate, and modifying the flow rate of the hot oil stream from the second hot oil flow rate to the first hot oil flow rate.

An apparatus for producing a purified, pressurized liquid carbon dioxide stream includes a distillation column (B) having packing (C) therein and a sump (D) below the packing, the distillation column in fluid communication with the liquid carbon dioxide supply tank for receiving the liquid carbon dioxide stream and the packing stripping volatile impurities from the liquid carbon dioxide stream; a heater (E) in contact with the liquid carbon dioxide stream in the sump (D) for vaporizing the liquid carbon dioxide stream in the sump; a vent in the distillation column (B) from which a first vaporized portion (G) of carbon dioxide vapor in the sump (D) is withdrawn from the distillation column: and a conduit (I) in fluid communication with the sump (D) and from which a second vaporized portion (H) of the carbon dioxide vapor in the sump is withdrawn into the conduit (I) to be introduced into the carbon dioxide vapor feed stream.

The present invention relates to an improved method for removing contaminants from a gaseous stream substantially comprising carbon dioxide. More specifically, the method comprises the step of subjecting the gaseous stream to an absorption step in which the absorbent is liquid carbon dioxide wherein the waste of carbon dioxide is minimized by utilizing a compressing means for generating a pressure difference between two streams in a reboiler.

Enhancements to a dual column, nitrogen producing cryogenic air separation unit are provided. Such enhancements include an improved air separation cycle that uses three condenser-reboilers and recycles a portion of the vapor from one or more of the condenser-reboilers to the incoming feed stream and or the compressed purified air streams to yield improvements in the performance of such dual column, nitrogen producing cryogenic air separation units in terms of overall nitrogen recovery as well as power consumption.

The present invention relates to an improved method for removing contaminants from a gaseous stream substantially comprising carbon dioxide. More specifically, the method comprises the step of subjecting the gaseous stream to an absorption step in which the absorbent is liquid carbon dioxide wherein the waste of carbon dioxide is minimized by utilizing a compressing means for generating a pressure difference between two streams in a reboiler.

An apparatus for producing a purified, pressurized liquid carbon dioxide stream includes a distillation column (B) having packing (C) therein and a sump (D) below the packing, the distillation column in fluid communication with the liquid carbon dioxide supply tank for receiving the liquid carbon dioxide stream and the packing stripping volatile impurities from the liquid carbon dioxide stream; a heater (E) in contact with the liquid carbon dioxide stream in the sump (D) for vaporizing the liquid carbon dioxide stream in the sump; a vent in the distillation column (B) from which a first vaporized portion (G) of carbon dioxide vapor in the sump (D) is withdrawn from the distillation column: and a conduit (I) in fluid communication with the sump (D) and from which a second vaporized portion (H) of the carbon dioxide vapor in the sump is withdrawn into the conduit (I) to be introduced into the carbon dioxide vapor feed stream.

A batch process for producing a purified, pressurized liquid carbon dioxide stream, includes withdrawing a liquid carbon dioxide stream (A) from a liquid carbon dioxide supply (10); introducing the liquid carbon dioxide stream (A) into a distillation column (B) having packing (C) therein, and stripping volatile impurities from the liquid carbon dioxide stream with the packing; vaporizing the liquid carbon dioxide stream (A) in a sump (D) of the distillation column (B) for providing a carbon dioxide vapor; withdrawing from a vaporized portion (F) of carbon dioxide vapor in the sump (D) a first vapor stream (G) vented from the distillation column (B); withdrawing from the vaporized portion (F) of the carbon dioxide vapor in the sump (D) a second vapor portion (H) vented from the sump into a conduit (I); and introducing the second vapor portion (H) in the conduit (I) into a carbon dioxide vapor feed stream.

A method of cleaning a condensate thermosyphon reboiler including modifying a flow rate of a hot oil stream introduced into the tube-side of a first condensate thermosyphon reboiler, modifying a flow rate of a condensate hydrocarbon stream introduced into the shell-side of the first condensate thermosyphon reboiler, and maintaining an operation of the condensate stabilizer system until the value of an overhead temperature of the first condensate thermosyphon reboiler is detected to have been modified from the first overhead temperature to a second overhead temperature. The method further includes modifying the flow rate of the condensate hydrocarbon stream from the second condensate flow rate to the first condensate flow rate, and modifying the flow rate of the hot oil stream from the second hot oil flow rate to the first hot oil flow rate.

A batch process for producing a purified, pressurized liquid carbon dioxide stream, includes withdrawing a liquid carbon dioxide stream (A) from a liquid carbon dioxide supply (10); introducing the liquid carbon dioxide stream (A) into a distillation column (B) having packing (C) therein, and stripping volatile impurities from the liquid carbon dioxide stream with the packing; vaporizing the liquid carbon dioxide stream (A) in a sump (D) of the distillation column (B) for providing a carbon dioxide vapor; withdrawing from a vaporized portion (F) of carbon dioxide vapor in the sump (D) a first vapor stream (G) vented from the distillation column (B); withdrawing from the vaporized portion (F) of the carbon dioxide vapor in the sump (D) a second vapor portion (H) vented from the sump into a conduit (I); and introducing the second vapor portion (H) in the conduit (I) into a carbon dioxide vapor feed stream.