A system is disclosed for use in additively manufacturing a composite structure. The system may include a head configured to discharge a continuous reinforcement at least partially coated with a matrix. The head may have a matrix reservoir, and a nozzle connected to an end of the matrix reservoir. The system may further include a support configured to move the head during discharging, and a supply of matrix. The system may also include at least one sensor configured to generate a signal indicative of a matrix characteristic inside of the head, and a controller configured to selectively affect the supply of matrix based on the signal.

The product of and a process for forming a metal composite comprising particles of a carbon allotrope dispersed in a metal or a mixture of metals. In one embodiment, the process includes the steps of: (a) contacting particles of a carbon allotrope with surfactant having an organic portion and an anionic portion wherein the anionic portion is bonded to the organic portion and wherein the anionic portion is ionically associated with a cation so that the organic portion of the surfactant is adsorbed onto the surface of the particles of the carbon allotrope to produce surfactant modified particles; (b) contacting the surfactant modified particles with a transition metal cation and/or a post-transition metal cation and/or mixtures thereof to replace some or all of the cations of the surfactant modified particles with a transition metal cation and/or a post-transition metal cation and/or mixtures thereof to produce metal ion modified particles; (c) mixing the metal ion modified particles with a metal or a mixture of metals to form a mixture thereof; and (d) processing the mixture to form a metal composite comprising particles of the carbon allotrope dispersed in the metal or mixture of metal. In another embodiment the process includes the steps of: (a) contacting particles of a carbon allotrope with a surfactant having an organic portion and an anionic portion wherein the anionic portion is bonded to the organic portion and wherein the anionic portion is ionically associated with a transition metal cation and/or a post-transition metal cation and/or mixtures to produce metal ion modified particles; (b) mixing the metal ion modified particles with a metal or a mixture of metals to form a mixture thereof; and (c) processing the mixture to form a metal composite comprising particles of the carbon allotrope dispersed in the metal or mixture of metals.

The present disclosure discloses a hybrid woven fiber preform-reinforced composite material, including a fiber preform, a composite material interface and a matrix, where the fiber preform is a three-dimensional fabric hybrid woven by 2-5 high-performance inorganic fibers, and the matrix is selected from the group consisting of resin, light alloy, carbon and ceramic. A preparation method of the composite material includes: preparing ceramic slurry, fiber bundle impregnation treatment, fiber weaving, molding of three-dimensional overall structure preform, preform heat treatment, preparing interface and preparing matrix. The present disclosure improves the weaving performance of inorganic rigid fibers, and the prepared hybrid woven fiber preform-reinforced composite material has desirable integrity, high interlayer bonding strength, and is not easy to layer. Meanwhile, the present disclosure realizes the functions of wave transmission, wave-absorbing, high-temperature structural material, thermal insulation and thermal prevention through the combination of hybrid woven fibers.

The present disclosure discloses a hybrid woven fiber preform-reinforced composite material, including a fiber preform, a composite material interface and a matrix, where the fiber preform is a three-dimensional fabric hybrid woven by 2-5 high-performance inorganic fibers, and the matrix is selected from the group consisting of resin, light alloy, carbon and ceramic. A preparation method of the composite material includes: preparing ceramic slurry, fiber bundle impregnation treatment, fiber weaving, molding of three-dimensional overall structure preform, preform heat treatment, preparing interface and preparing matrix. The present disclosure improves the weaving performance of inorganic rigid fibers, and the prepared hybrid woven fiber preform-reinforced composite material has desirable integrity, high interlayer bonding strength, and is not easy to layer. Meanwhile, the present disclosure realizes the functions of wave transmission, wave-absorbing, high-temperature structural material, thermal insulation and thermal prevention through the combination of hybrid woven fibers.

The present disclosure discloses a continuous electrophoretic deposition modified carbon fiber reinforced multi-matrix composite and a preparation method thereof, composing of a carbon fiber with a volume fraction of 30-55%, an inorganic powder with a volume fraction of 3-25% and a matrix with a volume fraction of 20-67%, wherein the inorganic powder is wrapped on the surface of the carbon fiber filament or embedded in the carbon fiber bundle, and the concentration gradually decreases from the fiber filament to the surface of the fiber bundle. The preparation method of the composite is as follows: (1) pretreating the carbon fibers; (2) preparing a slurry of the inorganic powder; (3) widening the pretreated carbon fiber to form a carbon fiber strip, and then carrying out electrophoretic deposition on the inorganic powders; (4) preparing a preform from the deposited carbon fibers; and (5) compounding a matrix in the preform.

The present disclosure discloses a continuous electrophoretic deposition modified carbon fiber reinforced multi-matrix composite and a preparation method thereof, composing of a carbon fiber with a volume fraction of 30-55%, an inorganic powder with a volume fraction of 3-25% and a matrix with a volume fraction of 20-67%, wherein the inorganic powder is wrapped on the surface of the carbon fiber filament or embedded in the carbon fiber bundle, and the concentration gradually decreases from the fiber filament to the surface of the fiber bundle. The preparation method of the composite is as follows: (1) pretreating the carbon fibers; (2) preparing a slurry of the inorganic powder; (3) widening the pretreated carbon fiber to form a carbon fiber strip, and then carrying out electrophoretic deposition on the inorganic powders; (4) preparing a preform from the deposited carbon fibers; and (5) compounding a matrix in the preform.

Solder-carbon nanostructure composites and methods of making and using thereof are described. Such composites can be useful for thermal application and can serve, for example, as thermal interface materials (TIMs).

A system is disclosed for additively manufacturing a composite structure. The system may include a print head configured to discharge a continuous reinforcement that is at least partially coated in a matrix, and a compactor configured to compact the continuous reinforcement and the matrix. The system may also include a cure enhancer configured to direct a path of cure energy toward the matrix after discharge, wherein the path of cure energy passes through at least a portion of the compactor.

A system is disclosed for additively manufacturing a composite structure. The system may include a print head configured to discharge a continuous reinforcement that is at least partially coated in a matrix, and a compactor configured to compact the continuous reinforcement and the matrix. The system may also include a cure enhancer configured to direct a path of cure energy toward the matrix after discharge, wherein the path of cure energy passes through at least a portion of the compactor.

The product of and a process for forming a metal composite comprising particles of a carbon allotrope dispersed in a metal or a mixture of metals. In one embodiment, the process includes the steps of: (a) contacting particles of a carbon allotrope with surfactant having an organic portion and an anionic portion wherein the anionic portion is bonded to the organic portion and wherein the anionic portion is ionically associated with a cation so that the organic portion of the surfactant is adsorbed onto the surface of the particles of the carbon allotrope to produce surfactant modified particles; (b) contacting the surfactant modified particles with a transition metal cation and/or a post-transition metal cation and/or mixtures thereof to replace some or all of the cations of the surfactant modified particles with a transition metal cation and/or a post-transition metal cation and/or mixtures thereof to produce metal ion modified particles; (c) mixing the metal ion modified particles with a metal or a mixture of metals to form a mixture thereof; and (d) processing the mixture to form a metal composite comprising particles of the carbon allotrope dispersed in the metal or mixture of metal. In another embodiment the process includes the steps of: (a) contacting particles of a carbon allotrope with a surfactant having an organic portion and an anionic portion wherein the anionic portion is bonded to the organic portion and wherein the anionic portion is ionically associated with a transition metal cation and/or a post-transition metal cation and/or mixtures to produce metal ion modified particles; (b) mixing the metal ion modified particles with a metal or a mixture of metals to form a mixture thereof; and (c) processing the mixture to form a metal composite comprising particles of the carbon allotrope dispersed in the metal or mixture of metals.