A corrosion-resistant coating on an aluminum-containing substrate such as an aluminum substrate, an aluminum alloy substrate (e.g., AA 2024, AA 6061, or AA7075), or other aluminum-containing substrate includes a corrosion inhibitor-incorporated ZnAl layered double hydroxide (LDH) layer and a sol-gel layer. A zinc salt and a corrosion inhibitor (e.g., a salt of an oxyanion of a transition metal such as a vanadate) is dissolved to form a zinc-corrosion inhibitor solution, and the substrate is immersed in or otherwise contacted with the solution to form the corrosion inhibitor-incorporated ZnAl LDH layer on the substrate. A sol-gel composition is applied on the corrosion inhibitor-incorporated ZnAl LDH layer of the substrate to form a sol-gel layer, and the sol-gel layer is cured.

A printed flexible PH sensor is provided. The printed flexible PH sensor includes a flexible substrate. A working electrode is disposed on the flexible substrate, and the working electrode includes a first silver layer formed on the flexible substrate by an ink-jet printing process, a second silver layer formed on the first silver layer by a silver mirror reaction, and a metal oxide layer disposed on the second silver layer of an end portion of the working electrode. A reference electrode is disposed on the flexible substrate, and the reference electrode includes the first silver layer and the second silver layer formed on the first silver layer, and a silver chloride layer totally covering the second silver layer. A method for fabricating the printed flexible PH sensor is also provided.

A method for post-treatment of a chromium finish surface to improve corrosion resistance comprising a) providing a substrate having a chromium finish surface, and at least one intermediate layer between the chromium finish surface and the substrate, selected from the group consisting of nickel, nickel alloys, copper and copper alloys, wherein the chromium finish surface is a surface of a trivalent chromium plated layer, obtained by electroplating the substrate, having the at least one intermediate layer, in a plating bath, the plating bath comprising chromium (III) ions; b) contacting the chromium finish surface with an aqueous solution, comprising a permanganate, at least one compound which is selected from a phosphorus-oxygen compound, a hydroxide, a nitrate, a borate, boric acid, a silicate, or a mixture of two or more of these compounds; c) forming a transparent corrosion protection layer onto the chromium finish surface during step b.

A method for post-treatment of a chromium finish surface to improve corrosion resistance comprising a) providing a substrate having a chromium finish surface, and at least one intermediate layer between the chromium finish surface and the substrate, selected from the group consisting of nickel, nickel alloys, copper and copper alloys, wherein the chromium finish surface is a surface of a trivalent chromium plated layer, obtained by electroplating the substrate, having the at least one intermediate layer, in a plating bath, the plating bath comprising chromium (III) ions; b) contacting the chromium finish surface with an aqueous solution, comprising a permanganate, at least one compound which is selected from a phosphorus-oxygen compound, a hydroxide, a nitrate, a borate, boric acid, a silicate, or a mixture of two or more of these compounds; c) forming a transparent corrosion protection layer onto the chromium finish surface during step b.

This disclosure relates to compositions for protecting a metallic surface susceptible to corrosion, the composition comprising a first component comprising an aqueous mixture of an acid-phosphate of chemical formula A.sup.m(H.sub.2PO.sub.4).sub.m.nH.sub.2O, where A is hydrogen ion, ammonium cation, metal cation, or mixtures thereof where m=1-3, and n=0-6; the first component solution adjusted to a pH of about 2 to about 5, the first component having a particle size distribution between 0.04 to 60 micron; and a second component, configured for combination and at least partial reaction with the first component to provide a phosphate ceramic, the second component comprising an aqueous solution or suspension of an alkaline oxide or alkaline hydroxide represented by B.sup.2mO.sub.mB(OH).sub.2m, or mixtures thereof, where B is an element of valency 2m (m=1, 1.5, or 2) the second component solution adjusted to a pH of between 9-14.

This disclosure relates to compositions for protecting a metallic surface susceptible to corrosion, the composition comprising a first component comprising an aqueous mixture of an acid-phosphate of chemical formula A.sup.m(H.sub.2PO.sub.4).sub.m.nH.sub.2O, where A is hydrogen ion, ammonium cation, metal cation, or mixtures thereof where m=1-3, and n=0-6; the first component solution adjusted to a pH of about 2 to about 5, the first component having a particle size distribution between 0.04 to 60 micron; and a second component, configured for combination and at least partial reaction with the first component to provide a phosphate ceramic, the second component comprising an aqueous solution or suspension of an alkaline oxide or alkaline hydroxide represented by B.sup.2mO.sub.mB(OH).sub.2m, or mixtures thereof, where B is an element of valency 2m (m=1, 1.5, or 2) the second component solution adjusted to a pH of between 9-14.

An aqueous solution for metal surface treatment includes an alkyl silicate or an oligomer thereof in a concentration of 0.005 mass % or more and less than 1 mass %, and an organic silane compound in a concentration of 0.005 mass % or more and less than 1 mass %. The aqueous solution has a pH of 2 or more and 7 or less.

Assemblies of stacked layers of materials are described. The assemblies include functional and structural layers. Functional layers include binderless ceramic materials on woven or non-woven substrates of natural, synthetic, or metallic materials. The layers of functional and structural materials may be configured to transport moisture or heat from an inner surface to an outer surface that is exposed to an ambient environment.

Provided is an aluminum-resin bonded body that expresses excellent bonding strength and does not show a reduction in the strength after a durability test, thus being able to keep the excellent bonding strength over a long period of time. The aluminum-resin bonded body includes: an aluminum substrate formed of aluminum or an aluminum alloy; an oxygen-containing film containing oxygen, the oxygen-containing film being formed on a surface of the aluminum substrate; and a resin molded body formed of a thermoplastic resin composition containing a thermoplastic resin and an additive, the resin molded body being bonded onto the oxygen-containing film, in which the thermoplastic resin composition contains any one or both of: a thermoplastic resin containing an element having an unshared electron pair in a repeat unit and/or at an end; and an additive containing an element having an unshared electron pair.

Provided is an aluminum-resin bonded body that expresses excellent bonding strength and does not show a reduction in the strength after a durability test, thus being able to keep the excellent bonding strength over a long period of time. The aluminum-resin bonded body includes: an aluminum substrate formed of aluminum or an aluminum alloy; an oxygen-containing film containing oxygen, the oxygen-containing film being formed on a surface of the aluminum substrate; and a resin molded body formed of a thermoplastic resin composition containing a thermoplastic resin and an additive, the resin molded body being bonded onto the oxygen-containing film, in which the thermoplastic resin composition contains any one or both of: a thermoplastic resin containing an element having an unshared electron pair in a repeat unit and/or at an end; and an additive containing an element having an unshared electron pair.