A process for preparing or regenerating peroxodisulfuric acid and its salts by electrolysis of an aqueous solution containing sulfuric acid and/or metal sulfates at diamond-coated electrodes without addition of promoters is described, with bipolar silicon electrodes which are coated with diamond on one side and whose uncoated silicon rear side serves as cathode being used.

What is proposed is an apparatus for conducting an electrolysis with an oxygen depolarized cathode, comprising: (a) an electrolyzer 1 which (b) is connected on the reactant side via an inlet control valve 2 to an oxygen source 3, and (c) on the product side has at least one off gas line 4, (d) which has at least one pressure regulator (PT) 5, at least one gas analyzer (QI) 6, at least one flow regulator (FT) 7 and at least one outlet control valve 8, wherein (e) the pressure regulator 5 controls the inlet control valve 2, (f) the gas analyzer 6 controls the flow regulator 7 or the outlet control valve 8 and/or (g) the flow regulator 7 controls the outlet control valve 8.

What is proposed is an apparatus for conducting an electrolysis with an oxygen depolarized cathode, comprising: (a) an electrolyzer 1 which (b) is connected on the reactant side via an inlet control valve 2 to an oxygen source 3, and (c) on the product side has at least one off gas line 4, (d) which has at least one pressure regulator (PT) 5, at least one gas analyzer (QI) 6, at least one flow regulator (FT) 7 and at least one outlet control valve 8, wherein (e) the pressure regulator 5 controls the inlet control valve 2, (f) the gas analyzer 6 controls the flow regulator 7 or the outlet control valve 8 and/or (g) the flow regulator 7 controls the outlet control valve 8.

A system to prepare an antimicrobial solution by the electrolysis of brine is presented where the antimicrobial solution is a solution comprising HOCl that contains a HOCl concentration in excess of 500 ppm or more at a pH of 6 to 6.8 with a low residual salt concentration and displays a stability in excess of 60 days and can have a HOCl concentration in excess of 450 for 180 days. The system includes an electrolysis cell that is improved by a superior anode and ceramic membrane such that when employed with a DC power supply controlled by a microprocessor and a controlled brine concentration provided to the cell at ambient temperature at a controlled rate, delivers a fluid that is continuously monitored by a pH probe and an ORP probe for input to the microprocessor.

A system to prepare an antimicrobial solution by the electrolysis of brine is presented where the antimicrobial solution is a solution comprising HOCl that contains a HOCl concentration in excess of 500 ppm or more at a pH of 6 to 6.8 with a low residual salt concentration and displays a stability in excess of 60 days and can have a HOCl concentration in excess of 450 for 180 days. The system includes an electrolysis cell that is improved by a superior anode and ceramic membrane such that when employed with a DC power supply controlled by a microprocessor and a controlled brine concentration provided to the cell at ambient temperature at a controlled rate, delivers a fluid that is continuously monitored by a pH probe and an ORP probe for input to the microprocessor.

The invention relates to an integrated process for continuous production of liquid hydrogen, comprising (a) producing gaseous hydrogen by electrolysis; and (b) liquefying said gaseous hydrogen in a hydrogen liquefaction unit, which liquefaction unit is powered by energy essentially from renewable sources; and, (c) when additional power is needed, using electrical energy generated in a process in which electrical energy and hydrogen are co-generated by an integrated electrolysis process comprising: (d) electrolysing a metal salt or mixture of metal salts and water into the corresponding metal or metals, acid or acids, and oxygen (electricity storage phase), and (e) producing gaseous hydrogen and recovering electricity in a regeneration reaction of the metal (s) and acid(s) of step (d) (regeneration phase); wherein at least part of the gaseous hydrogen generated in step (e) is used in step (b) of the process.

The invention relates to an integrated process for continuous production of liquid hydrogen, comprising (a) producing gaseous hydrogen by electrolysis; and (b) liquefying said gaseous hydrogen in a hydrogen liquefaction unit, which liquefaction unit is powered by energy essentially from renewable sources; and, (c) when additional power is needed, using electrical energy generated in a process in which electrical energy and hydrogen are co-generated by an integrated electrolysis process comprising: (d) electrolysing a metal salt or mixture of metal salts and water into the corresponding metal or metals, acid or acids, and oxygen (electricity storage phase), and (e) producing gaseous hydrogen and recovering electricity in a regeneration reaction of the metal (s) and acid(s) of step (d) (regeneration phase); wherein at least part of the gaseous hydrogen generated in step (e) is used in step (b) of the process.

Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H.sub.2O and SO.sub.2 and for electrolysing the H.sub.2O and SO.sub.2 to produce hydrogen and sulphuric acid (H.sub.2SO.sub.4), a decomposition reactor for receiving and decomposing the H.sub.2SO.sub.4 into SO.sub.3 and H.sub.2O, wherein the H.sub.2O is recycled to the SDE, a sulphur submerged combustor for converting the SO.sub.3 to SO.sub.2 and producing S.sub.n vapor, a sulphur power plant for combusting S.sub.n vapor to produce SO.sub.2, electricity and heat and for supplying the SO.sub.2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO.sub.2 from flue gas, a CO.sub.2 converter generates COS, and a separator separates the COS from the flue gas.

Disclosed herein is a system and method for sulphur-assisted carbon capture and utilization. The system includes a sulphur depolarized electrolyser (SDE) for receiving electricity, H.sub.2O and SO.sub.2 and for electrolysing the H.sub.2O and SO.sub.2 to produce hydrogen and sulphuric acid (H.sub.2SO.sub.4), a decomposition reactor for receiving and decomposing the H.sub.2SO.sub.4 into SO.sub.3 and H.sub.2O, wherein the H.sub.2O is recycled to the SDE, a sulphur submerged combustor for converting the SO.sub.3 to SO.sub.2 and producing S.sub.n vapor, a sulphur power plant for combusting S.sub.n vapor to produce SO.sub.2, electricity and heat and for supplying the SO.sub.2 and the electricity to the SDE and for supplying the heat to the decomposition reactor. The hydrogen is delivered to a carbon capture and utilization facility. An optional Flue Gas Desulphurisation (FGD) regenerable system removes SO.sub.2 from flue gas, a CO.sub.2 converter generates COS, and a separator separates the COS from the flue gas.

A functional water concentration sensor includes: a light source which emits ultraviolet light; a container capable of holding functional water having a pH between 6 and 9, inclusive, and containing hypochlorous acid and hypochlorite dissociated from the hypochlorous acid; a light-receiving element; and a signal processor. The signal processor calculates the concentration of the hypochlorite in the functional water on the basis of the output signal, calculates the percentages of the hypochlorous acid and the hypochlorite in the functional water on the basis of the pH of the functional water and the dissociation constant of the hypochlorous acid, and calculates the concentration of the hypochlorous acid in the functional water on the basis of the calculated hypochlorite concentration and the calculated percentages.