A dehydrogenation reaction system for a liquid hydrogen source material includes a storage device used for storing a liquid hydrogen source material and a liquid hydrogen storage carrier, a reaction still for dehydrogenation of the liquid hydrogen source material, a gas-liquid separator for separating the products, hydrogen and liquid hydrogen storage carrier which are generated after dehydrogenation of the liquid hydrogen source material, a buffer tank used for storing hydrogen, and a heating device used for heating the reaction still. The liquid hydrogen source material is input into the reaction still by means of a pump through an input pipe, dehydrogenation reaction of the liquid hydrogen source material is conducted in the reaction still, generated hydrogen is conveyed to the buffer tank, and the liquid hydrogen storage carrier generated after dehydrogenation is conveyed back to the storage device.

The present invention provides a system and method of storing hydrogen (H.sub.2) and releasing it on demand, comprising and making use of diaminoalkanes and alcohols, or aminoalcohols as liquid-organic hydrogen carrier systems (LOHC). 2-amino-ethanol (AE) or its N-methyl derivative 2-(methylamino)ethanol undergo catalytic dehydrogenation to form a cyclic dipeptide (glycine anhydrideGA) or its N,N-dimethyl derivative (N,N-dimethyl GA) with release of hydrogen. Similarly, ethylenediamine (ED) and ethanol undergo catalytic dehydrogenation to form N,N-diacetylethylenediamine (DAE) with release of hydrogen. Glycine anhydride (GA) or N,N-dimethyl-GA may be hydrogenated back to 2-aminoethanol (AE) or 2-(methylamino)ethanol, respectively, each of which functions as a hydrogen storage system. N,N-diacetylethylenediamine (DAE) may be hydrogenated back to ED and ethanol, which functions as a hydrogen storage system. These reactions may be catalyzed by a variety of compounds or complexes, including Ruthenium complexes as described herein.

The desorbing process of the present disclosure includes a step of bringing a solution containing a hydrogenated aromatic compound, at least one of [P((CH.sub.2).sub.mCH.sub.3).sub.3((CH.sub.2).sub.nCH.sub.3) (5m24, 13n24)].sup.+ and [N((CH.sub.2).sub.mCH.sub.3).sub.3((CH.sub.2).sub.nCH.sub.3) (5m24, 13n24)].sup.+, and an anion into contact with an anode; and desorbing hydrogen from the hydrogenated aromatic compound.

The invention relates to a device (10) for degassing flowable fluids, in particular liquids used for hydrogen storage, comprising: a desorber (12) which can be filled with fluid to be degassed and through which said fluid can flow; a circulation pump (48) for circulating the fluid during a degassing process in the desorber (12); a vacuum pump (38) for generating a vacuum in the desorber (12) during a filling process with fluid and for discharging the gas from the desorber (12) during the degassing process; at least one sensor (44a, 44b) for measuring the pressure in the desorber (12) and/or for time measurement; and a control unit which ends the degassing process when a predefined pressure is measured by the respective sensor (44a, 44b) and/or when a predefined dwell time of the fluid in the desorber (12) is measured.

A method for the use of hydrogen as a resource includes producing a mixture by a catalytic reaction in a reactor. The mixture includes hydrogen carrier medium to which hydrogen can be chemically bound by a catalytic hydrogenation reaction and from which hydrogen can be released again by a catalytic dehydrogenation reaction, and hydrogen that is dissolved, i.e. physically stored, therein, and hydrogenating the hydrogen carrier medium with the dissolved hydrogen in a hydrogenation unit.

Provided is a hydrogen storage system including a solution including ethylenediamine bisborane (EDAB) and ethylenediamine (ED), in which the hydrogen storage system is capable of performing a reversible dehydrogenation/hydrogenation reaction at a temperature of 20 C. to 200 C. in the presence of a heterogeneous metal catalyst including ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Jr), platinum (Pt), nickel (Ni), iron (Fe), cobalt (Co), or a combination thereof.

The present disclosure relates generally to portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power. In particular, an electricity generation device for powering a battery comprising a formic acid reservoir containing a liquid consisting of formic acid; a reaction chamber capable of using a catalyst and heat to convert the formic acid to hydrogen and carbon dioxide; a fuel cell that generates electricity; a delivery system for moving converted hydrogen into the fuel cell; and a battery powered by electricity generated by the fuel cell is provided.

The present disclosure refers in one embodiment to processes for making and transporting clean hydrogen fuel. The processes may involve hydrotreating, hydrocracking, or both hydrotreating and hydrocracking an aromatic feedstock under conditions to obtain a liquid hydrocarbon fuel. The liquid hydrocarbon fuel is hydrogenated to obtain a hydrogen-rich fuel that is transported to a dehydrogenation facility that may also be at or near a hydrogen station. The hydrogen-rich fuel is used to obtain hydrogen and a second liquid hydrocarbon fuel.

The present invention provides novel diamine-monoborane liquid organic hydrogen carriers with hydrogen storage capacities at least equivalent to prior art hydrogen carriers. The novel diamine-monoboranes of the invention provide advantages over the prior art including low cost due to the simple one-step chemical synthesis method between a diamine and a borane complex, and that the starting materials are inexpensive compared to the prior art. The novel diamine-monoboranes of the invention provide excellent dehydrogenation performance. With the presence of inexpensive and readily-available commercial catalysts, dehydrogenation occurs at ambient temperatures and pressures with high hydrogen purity. The resulting 1,3,2-diazaborolidines (cyclic diaminoboranes) are readily hydrogenated to produce the novel diamine-monoboranes of the invention. The invention also provides use of the diamine-monoboranes of the invention in a fuel cell or a portable power cell, or cell installed in conjunction with a hydrogen-burning engine. Other uses relate to transport down pipelines and in tankers.

The present invention provides a porous coordination polymer having high ability of storing a gas. The porous coordination polymer according to the present invention comprises zinc cluster ions and one kind of tricarboxylic acid ions selected from the group consisting of the following chemical formula (I), the following chemical formula (II), and the following chemical formula (III); ##STR00001## where X represents a natural number of not less than 1 and not more than 3, wherein the tricarboxylic acid ions are bound to the zinc cluster ions as terdentate ligands.