Provided is a device that uses a high-temperature exhaust gas released from an internal combustion engine to produce a fuel. The present invention relates to the fuel production device including the internal combustion engine, an electrolysis device connected to the internal combustion engine, and a hydrogenation reactor connected to the electrolysis device, wherein the electrolysis device is a device for decomposing high-temperature water vapor contained in the exhaust gas from the internal combustion engine into hydrogen and oxygen, and the hydrogenation reactor is a device for converting the hydrogen resulting from the decomposition to the fuel.

A method for degassing flowable fluids, in particular liquids used for hydrogen storage, uses a device including a desorber (12) that can be filled with fluid to be degassed and through which the fluid can flow. A circulation pump (48) circulates the fluid during a degassing process in the desorber (12). A vacuum pump (38) generates a vacuum in the desorber (12) during a filling step with fluid and for discharging the gas from the desorber (12) during the degassing step. At least one sensor (44a, 44b) measures the pressure in the desorber (12) and/or a dwell time. A control unit ends the degassing process when a predefined pressure is measured by the sensor (44a, 44b) and/or when a predefined dwell time of the fluid in the desorber (12) is measured.

The invention relates to a method for storing and re-releasing dihydrogen (1) comprising at least: a step of generating hydrogen (G) by dehydrogenating hydroxyl groups of dipropylene glycol into respective carbonyl groups, in order to produce a dehydrogenated substrate (SD) and gaseous dihydrogen (H.sub.2), a step of regenerating (R) at least a portion of the dipropylene glycol (DG), by hydrogenating said carbonyl groups into respective hydroxyl groups by means of gaseous dihydrogen (H.sub.2).

The invention is particularly suitable for storing dihydrogen as an energy carrier.

The present invention concerns a process for producing hydrogen by partial dehydrogenation of an organic liquid, said process comprising a step of supplying at least one organic liquid having a Degree of Hydrogenation DHplus, a step of partially dehydrogenating said liquid, a step of recovering firstly gaseous hydrogen and secondly said organic liquid having a Degree of Hydrogenation DHminus, and wherein the ratio DHplus/DHminus is between 1 and 25, endpoints excluded.

The invention likewise concerns a hydrogenation/dehydrogenation cycle comprising at least the process of the invention for producing hydrogen by partial dehydrogenation of an organic liquid and at least one hydrogenation reaction of said organic liquid.

A hydrogen desorption method includes a step of bringing a liquid containing an alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain, a quinone, and an electrolyte into contact with a anode and a step of desorbing hydrogen from the alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain.

The desorbing process of the present disclosure includes a step of bringing a solution containing a hydrogenated aromatic compound, at least one of [P((CH.sub.2).sub.mCH.sub.3).sub.3((CH.sub.2).sub.nCH.sub.3) (5≦m≦24, 13≦n≦24)].sup.+ and [N((CH.sub.2).sub.mCH.sub.3).sub.3((CH.sub.2).sub.nCH.sub.3) (5≦m≦24, 13≦n≦24)].sup.+, and an anion into contact with an anode; and desorbing hydrogen from the hydrogenated aromatic compound.

A process for producing and storing hydrogen includes providing an intermediate gas mixture having an increased proportion of hydrogen and contacting of the intermediate gas mixture with a hydrogen carrier medium in order to hydrogenate the hydrogen carrier medium.

Mixed metal metal-organic frameworks (MM-MOFs) of copper-1,3,5-benzenetricarboxylate (BTC), M-Cu-BTC, wherein M is Zn(II), Ni(II), Co(II), and/or Fe(II) may be made using post-synthetic exchange (PSE) with metal ions. Such MM-MOFs may be used in H.sub.2 storage, especially Ni(II) and Co(II) MM-MOFs. Selected metal exchanged materials can provide gravimetric H.sub.2 uptake around 1.63 wt. % for Zn—Cu-BTC, around 1.61 wt. % for Ni—Cu-BTC, around 1.63 wt. % for Fe—Cu-BTC, and around 1.12 wt. % for Co—Cu-BTC.

The present invention relates to a process for producing hydrogen from a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, said process comprising at least one step wherein said liquid is brought into contact with a filtering agent. The invention also relates to the use of a filtering agent for the purification of a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, in a hydrogen production process.

The present invention provides a porous coordination polymer, wherein the porous coordination polymer is formed of unit lattices; each of the unit lattices has a shape of a cube having eight vertexes and twelve sides; each of the vertexes of the unit lattices consists of a Zn.sub.4O cluster; each of the sides of the unit lattices consists of a .sup.−OOC—C≡C—COO.sup.− group. At least a part of the unit lattices contains at least one hydrogen molecule only, or the inside of at least a part of the unit lattices is empty. The present invention provides a novel porous coordination polymer, especially, a porous coordination polymer suitable for separating hydrogen molecules from a gaseous mixture of the hydrogen molecules and impurity molecules (e.g., nitrogen molecules, oxygen molecules, or carbon dioxide molecules).