The present disclosure provides systems and methods for processing ammonia. The system may comprise one or more reactor modules configured to generate hydrogen from a source material comprising ammonia. The hydrogen generated by the one or more reactor modules may be used to provide additional heating of the reactor modules (e.g., via combustion of the hydrogen), or may be provided to one or more fuel cells for the generation of electrical energy.

The present disclosure provides systems and methods for processing ammonia. The system may comprise one or more reactor modules configured to generate hydrogen from a source material comprising ammonia. The hydrogen generated by the one or more reactor modules may be used to provide additional heating of the reactor modules (e.g., via combustion of the hydrogen), or may be provided to one or more fuel cells for the generation of electrical energy.

Methods and systems for producing hydrogen substantially without greenhouse gas emissions, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

The present invention relates to the technical field of catalysts, and discloses a yolk/shell-type Co.sub.xCu.sub.1-xCo.sub.2O.sub.4@Co.sub.yCu.sub.1-yCo.sub.2O.sub.4 catalyst as well as a preparation method and application thereof to catalytic hydrogen generation. The preparation method of the yolk/shell-type Co.sub.xCu.sub.1-xCo.sub.2O.sub.4@Co.sub.yCu.sub.1-yCo.sub.2O.sub.4 catalyst includes the steps of: successfully synthesizing, by applying a hydrothermal synthesis method, a [Co(C.sub.6H.sub.12N.sub.4).sub.2](NO.sub.3).sub.2 solid sphere complex from a cobalt salt and hexamethyleneteramine serving as an alkali source; and then, performing calcination to obtain a yolk/shell-type Co.sub.3O.sub.4 microsphere structure, adsorbing Cu.sup.2+ on a surface in a physical adsorption manner, and performing calcination again to form yolk/shell-type Co.sub.xCu.sub.1-xCo.sub.2O.sub.4@Co.sub.yCu.sub.1-yCo.sub.2O.sub.4. The preparation method is simple, raw materials are cheap and available, and the prepared yolk/shell-type Co.sub.xCu.sub.1-xCo.sub.2O.sub.4@Co.sub.yCu.sub.1-yCo.sub.2O.sub.4 catalyst is high in purity, good in catalysis performance and capable of showing excellent catalytic activity in term of ammonia borane catalytic hydrolysis for hydrogen generation.

Disclosed is a ruthenium-based catalyst for hydrogen production from ammonia decomposition, comprising an active component, a promoter and a carrier, wherein the active component is ruthenium, the promoter is cesium and/or potassium, and the carrier comprises magnesium oxide, an activated carbon, cerium oxide, molybdenum oxide, tungsten oxide, barium oxide and potassium oxide. The present invention further discloses a preparation method and application of the aforementioned ruthenium-based catalyst for hydrogen production from ammonia decomposition. Compared with the prior art, the ruthenium-based catalyst for hydrogen production from ammonia decomposition provided by the present invention is low in preparation cost and simple in process, and has high catalytic activity at low temperature and good heat resistance.

A process for generating power using a gas turbine, comprising the steps of: (i) vaporising and pre-heating liquid ammonia to produce pre-heated ammonia gas; (ii) introducing the pre-heated ammonia gas into an ammonia-cracking device suitable for converting ammonia gas into a mixture of hydrogen and nitrogen; (iii) converting the pre-heated ammonia gas into a mixture of hydrogen and nitrogen in the device; (iv) cooling the mixture of hydrogen and nitrogen to give a cooled hydrogen and nitrogen mixture; (v) introducing the cooled hydrogen and nitrogen mixture into a gas turbine; and (vi) combusting the cooled hydrogen and nitrogen mixture in the gas turbine to generate power.

Provided are a hydrogen recycle system and a hydrogen recycle method, whereby hydrogen can be purified to high purity at high yield from a gas, said gas being exhausted from a nitride compound production device, and recycled. The hydrogen recycle system comprises an exhaust gas supply path supplying a gas exhausted from a nitride compound production device, a hydrogen recycle means and a hydrogen supply path. The hydrogen recycle means of the hydrogen recycle system is characterized by comprising: a plasma reaction vessel that defines at least a part of a discharge space; a hydrogen separation membrane that divides the discharge space from a hydrogen flow path communicated with the hydrogen supply path, defines at least a part of the discharge space by one surface thereof and also defines at least a part of the hydrogen flow path by the other surface thereof; an electrode that is disposed outside the discharge space; and an adsorbent that is filled in the discharge space and adsorbs the supplied exhaust gas.

An ammonia decomposition apparatus comprises a casing, a heating zone, a heat exchange zone, a reaction section and a heat exchange coil. The heat exchange coil is spirally wound on an outer wall of the reaction section to efficiently heat ammonia gas. The reaction section has a first reaction zone and a second reaction zone communicated successively, the ammonia gas decomposed into a nitrogen-hydrogen mixture after entering the first reaction zone, with the second reaction zone decomposing for the second time the residual ammonia gas in the nitrogen-hydrogen mixture produced in the first reaction zone, so that the ammonia gas is decomposed more thoroughly. The conversion rate of ammonia gas can reach 99.9% or more, and the residual amount of ammonia gas in the nitrogen-hydrogen mixture can be less than 1000 ppm.

A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H.sub.2) from ammonia (NH.sub.3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N.sub.2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.

A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.