Alloys comprised of a refined microstructure, ultrafine or nano scaled, that when reacted with water or any liquid containing water will spontaneously and rapidly produce hydrogen at ambient or elevated temperature are described. These metals, termed here as aluminum based nanogalvanic alloys will have applications that include but are not limited to energy generation on demand. The alloys may be composed of primarily aluminum and other metals e.g. tin bismuth, indium, gallium, lead, etc. and/or carbon, and mixtures and alloys thereof. The alloys may be processed by ball milling for the purpose of synthesizing powder feed stocks, in which each powder particle will have the above mentioned characteristics. These powders can be used in their inherent form or consolidated using commercially available techniques for the purpose of manufacturing useful functional components.

The reaction between aluminum metal and water holds promise for producing hydrogen; however, solid aluminum metal is difficult to manage and use, and the reactivity between aluminum and water is often difficult to control. Certain embodiments of the disclosure are related to a water-stable aluminum slurry comprising a plurality of activated aluminum particles dispersed in a fluid carrier. In some embodiments, the reactivity of the aluminum slurry in the presence of water may be easily controlled with the addition of various additives (e.g., surfactants). Additionally, methods of making and using the water-stable aluminum slurry to controllable manage the reactivity between aluminum and water are presented herein.

The reaction between aluminum metal and water holds promise for producing hydrogen; however, solid aluminum metal is difficult to manage and use, and the reactivity between aluminum and water is often difficult to control. Certain embodiments of the disclosure are related to a water-stable aluminum slurry comprising a plurality of activated aluminum particles dispersed in a fluid carrier. In some embodiments, the reactivity of the aluminum slurry in the presence of water may be easily controlled with the addition of various additives (e.g., surfactants). Additionally, methods of making and using the water-stable aluminum slurry to controllable manage the reactivity between aluminum and water are presented herein.

Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Process for producing hydrogen gas from water is disclosed. The hydrogen gas is produced by exposing a reactive metal to an aqueous solution, where the aqueous solution is under supercritical conditions or is at a temperature of at least 200° C. and at a pressure of at least the saturated vapor pressure of water at said temperature. The reactive metals include Al, B, Mg, Si, Ti, Mn, and Zn. Heat and metal oxides and/or metal hydroxides may also be recovered from the process. The process may be used to produce hydrogen on demand in applications for producing clean energy.

Process for producing hydrogen gas from water is disclosed. The hydrogen gas is produced by exposing a reactive metal to an aqueous solution, where the aqueous solution is under supercritical conditions or is at a temperature of at least 200° C. and at a pressure of at least the saturated vapor pressure of water at said temperature. The reactive metals include Al, B, Mg, Si, Ti, Mn, and Zn. Heat and metal oxides and/or metal hydroxides may also be recovered from the process. The process may be used to produce hydrogen on demand in applications for producing clean energy.

Materials, kits, and methods are directed to controlling reactability of activated aluminum to produce hydrogen when exposed to water. For example, a moisture-stabilized material may be treatable with one or more additives to form a water-reactive source of hydrogen. The moisture-stabilized material may include a bulk volume including aluminum, at least one activation metal disposed along the aluminum within the bulk volume, the at least one activation metal more noble than the aluminum, and a salt along at least an outer surface of the bulk volume, the salt dissolvable in water to form an ion-containing solution at a rate faster than a reaction rate of water with the aluminum of the bulk volume.

Materials, kits, and methods are directed to controlling reactability of activated aluminum to produce hydrogen when exposed to water. For example, a moisture-stabilized material may be treatable with one or more additives to form a water-reactive source of hydrogen. The moisture-stabilized material may include a bulk volume including aluminum, at least one activation metal disposed along the aluminum within the bulk volume, the at least one activation metal more noble than the aluminum, and a salt along at least an outer surface of the bulk volume, the salt dissolvable in water to form an ion-containing solution at a rate faster than a reaction rate of water with the aluminum of the bulk volume.

A system and method for cleaning dirty water is disclosed. The systems and methods may include two heat exchangers, including a high temperature/high pressure (HT/HP) heat exchanger that receives superheated steam and hydrogen gas and a low temperature/low pressure (LT/LP) that receives steam at a reduced temperature and pressure. The LT/LP heat exchanger provides first stage heating to dirty water that is input into the system for cleansing. The LT/LP heat exchanger has a first coil and a second coil. The first coil carries the dirty water to be cleaned. The HT/HP heat exchanger provides a second stage of heating to the dirty water that is output from the LT/LP heat exchanger. A first coil of the HT/HP heat exchanger carries the superheated steam and hydrogen gas. A second coil carries the preheated dirty water that is output from the LT/LP heat exchanger.