A self-healing ceramic ion-selective membrane assembly including a ceramic ion-selective membrane, and at least one additive layer. The at least one additive layer includes an ionic ceramic material which is porous or ion-selective. The at least one additive layer having a metal cation diffusivity higher than the metal cation diffusivity of the ceramic ion-selective membrane. When a defect occurs through the ceramic ion-selective membrane, metal cation transport will be enhanced by orders of magnitude towards and into the defect, driven by the chemical or electrical potential difference between the two sides of the membrane.

A pass or tube or a section thereof or U bend in a coil in a paraffin cracker having section having a pore size in the metal substrate from about 0.001 to 0.5 microns over coated with a dense metal membrane permits the permeation of one or more of H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases moving the reaction equilibrium to the production of ethylene and reduces the load on the down-stream separation train of the steam cracker.

The disclosure relates to systems and methods that include using a plurality of reactors for the conversion of a stream of ammonia (NH.sub.3) to hydrogen (H.sub.2) and nitrogen (N.sub.2). The stream of ammonia is heated prior to introduction into each reactor. The reactors can be adiabatically operated.

A hydrogen supply system includes an electrochemical hydrogen pump which includes: an electrolyte membrane; an anode provided on a first surface of the electrolyte membrane; a cathode provided on a second surface of the electrolyte membrane opposite to the first surface; and a current adjuster adjusting a current amount flowing between the anode and the cathode, and which performs a hydrogen supply operation by allowing a current to flow between the anode and the cathode using the current adjuster so as to boost the pressure of hydrogen which is supplied to an anode side at a cathode side and to supply the pressure-boosted hydrogen to a hydrogen demander; and a dew point adjuster adjusting a dew point of a mixed gas in which a hydrogen-containing gas which is discharged from the anode side and a hydrogen-containing gas which is supplied from an outside are mixed together.

Provided are a hydrogen recycle system and a hydrogen recycle method, whereby hydrogen can be purified to high purity at high yield from a gas, said gas being exhausted from a nitride compound production device, and recycled. The hydrogen recycle system comprises an exhaust gas supply path supplying a gas exhausted from a nitride compound production device, a hydrogen recycle means and a hydrogen supply path. The hydrogen recycle means of the hydrogen recycle system is characterized by comprising: a plasma reaction vessel that defines at least a part of a discharge space; a hydrogen separation membrane that divides the discharge space from a hydrogen flow path communicated with the hydrogen supply path, defines at least a part of the discharge space by one surface thereof and also defines at least a part of the hydrogen flow path by the other surface thereof; an electrode that is disposed outside the discharge space; and an adsorbent that is filled in the discharge space and adsorbs the supplied exhaust gas.

Provided are a hydrogen recycle system and a hydrogen recycle method, whereby hydrogen can be purified to high purity at high yield from a gas, said gas being exhausted from a nitride compound production device, and recycled. The hydrogen recycle system 1 comprises an exhaust gas supply path 11 supplying a gas exhausted from a nitride compound production device 2, a hydrogen recycle means 10 and a hydrogen supply path 12. The hydrogen recycle means 10 of the hydrogen recycle system 1 is characterized by comprising: a plasma reaction vessel 31 that defines at least a part of a discharge space 32; a hydrogen separation membrane 34 that divides the discharge space 32 from a hydrogen flow path 33 communicated with the hydrogen supply path 12, defines at least a part of the discharge space 32 by one surface thereof and also defines at least a part of the hydrogen flow path 33 by the other surface thereof; an electrode 35 that is disposed outside the discharge space 32; and an adsorbent 36 that is filled in the discharge space 32 and adsorbs the supplied exhaust gas.

Hydrogen-producing fuel processing systems and related methods. The systems include a hydrogen-producing region configured to produce a mixed gas stream from a feedstock stream, a hydrogen-separation membrane module having at least one hydrogen-selective membrane and configured to separate the mixed gas stream into a product hydrogen stream and a byproduct stream, and an oxidant delivery system configured to deliver an oxidant-containing stream to the hydrogen-separation membrane module in situ to increase hydrogen permeance of the hydrogen-selective membrane. The methods include operating a hydrogen-producing fuel processing system in a hydrogen-producing regime, and subsequently operating the hydrogen-producing fuel processing system in a restoration regime, in which an oxidant-containing stream is delivered to the hydrogen-separation membrane module in situ to expose the at least one hydrogen-selective membrane to the oxidant-containing stream to increase the hydrogen permeance of the at least one hydrogen-selective membrane.

An apparatus includes: an electrolyte membrane; a cathode catalyst layer provided to one main surface of the electrolyte membrane; an anode catalyst layer provided to the other main surface of the electrolyte membrane; a cathode gas diffusion layer provided on a main surface of the cathode catalyst layer not facing the electrolyte membrane; a separator including a recess through which cathode gas flows; an anode gas diffusion layer provided on a main surface of the anode catalyst layer not facing the electrolyte membrane; a voltage applicator applying a voltage between the cathode catalyst layer and the anode catalyst layer; and a fastener fastening a laminated body. The cathode gas diffusion layer is accommodated in the recess, projects from the recess in a thickness direction before fastening of the laminated body, and includes an elastic member between side surfaces of the cathode gas diffusion layer and of the recess.

Method and system for producing CO2, purified hydrogen and electricity from a reformed process gas feed using a solid oxide fuel cell. The method having the steps of: introducing the reformed process gas into the solid oxide fuel cell; converting hydrogen and CO of the reformed process gas in combination with oxygen into an anode off-gas including steam, CO.sub.2 and unconverted process gas; introducing the anode off-gas into a high temperature water gas shift reactor; in the high temperature water-gas shift reactor, converting CO and steam into CO.sub.2 and hydrogen, introducing the gas exiting the high temperature water-gas shift reactor into a low temperature water-gas shift membrane reactor, in the low temperature water-gas shift membrane reactor, converting CO and steam into CO.sub.2 and hydrogen, whereby the low temperature water-gas shift membrane reactor comprises a hydrogen pump producing purified hydrogen on a permeate side, while removing hydrogen from a feed side.

The invention relates to a system for separating and storing molecules, atoms and/or ions from air, wherein at least one air collecting means comprises at least one collecting tank configured to receive molecules, atoms and/or ions separated from air through an inlet and at least one membrane adapted to fit in the inlet of the collecting tank and configured to let a specified pre-determined size of molecules, atoms and/or ions to pass through the at least one membrane. The system further comprises at least one storing tank for storing the separated molecules, atoms and/or ions, and at least one outlet. The system according to the invention can be used to utilize the energy present in such molecules or separate unwanted gases present in the air.