A method can include: processing precursors, electrochemically oxidizing sulfur dioxide, processing sulfuric acid and hydrogen, and/or any suitable steps.

Embodiments described herein provide systems and methods for a phosphate processing system with integrated sub-systems, such as a phosphoric acid plant, precipitation system, crystallizer system, rinsing system, granulation system, pond water system, organics removal system, and/or exhaust treatment system. Such sub-systems can be integrated with each other by using one or more output streams from one or more sub-systems as one or more input streams for one or more sub-systems. In some embodiments, the phosphate processing system can produce phosphoric acid, struvite containing fertilizer, fertilizer using recycled struvite, magnesium or fluoride containing compositions using recycled magnesium or fluoride, and other components using phosphoric acid collected from a phosphoric acid and gypsum composition or using sludge collected from a waste stream, for example.

A source of phosphate for agriculture and food industry comprises a phosphate salt in solid form of formula M.sub.n(HPO4)y.zH2O in which M is Na, K, NH4, n=2, and y=1; or M is Ca, n=1, y=1; or M is Al or Fe, n=2, y=3; and in which z is 0, 1 or 2, wherein said phosphate salt has a phosphate content expressed as a P2O5 content of between 30 and 50% by weight of the phosphate salt, and it has a cadmium content lower than 0.40 ppm.

A source of phosphate for agriculture and food industry comprises a phosphate salt in solid form of formula M.sub.n(HPO4)y.zH2O in which M is Na, K, NH4, n=2, and y=1; or M is Ca, n=1, y=1; or M is Al or Fe, n=2, y=3; and in which z is 0, 1 or 2, wherein said phosphate salt has a phosphate content expressed as a P2O5 content of between 30 and 50% by weight of the phosphate salt, and it has a cadmium content lower than 0.40 ppm.

The present invention provides for a method for producing an aqueous monoammonium phosphate containing fertilizer solution. The method provides for means to control the temperature of a reaction zone as measured at a reagent entry point and a product exit point. The pH of the reaction is monitored and the reaction is terminated when the reaction mixture has reached a pH of between about 5.5 and about 7.5. The invention further provides for a method of treating crops with a monoammonium phosphate solution having a pH of between 6 and 7.

Systems and methods for the treatment of wastewater are provided. By incorporating one or more intermediate phosphate recovery reactors and manipulating the effluent and/or solid streams from those reactors, the systems and methods provide effluent and solid streams having customized phosphate content throughout the wastewater treatment process.

Disclosed are a cathode active material for a lithium secondary battery including a core containing lithium composite metal oxide, and a coating layer disposed on the core, containing a mixture of lithium oxide, tungsten oxide, boron oxide and phosphorus oxide, and having an amorphous phase, and a lithium secondary battery including the same.

Apparatus and methods for removing solutes from wastewater are disclosed. An embodiment provides a reactor tank having a manifold located at or near an interface between a lower (upstream) section having a first cross-section and a higher (downstream) section having a second cross-section smaller than the first cross section. An inlet for wastewater to enter the reactor tank is located in or below the first cross-section. A recycling path is provided for removing wastewater from the manifold and recycling at least part of the removed wastewater into the reactor tank. An outlet for water to exit the reactor tank is located downstream from the manifold.

Apparatus and methods for removing solutes from wastewater are disclosed. An embodiment provides a reactor tank having a manifold located at or near an interface between a lower (upstream) section having a first cross-section and a higher (downstream) section having a second cross-section smaller than the first cross section. An inlet for wastewater to enter the reactor tank is located in or below the first cross-section. A recycling path is provided for removing wastewater from the manifold and recycling at least part of the removed wastewater into the reactor tank. An outlet for water to exit the reactor tank is located downstream from the manifold.

Provided herein are systems and methods for producing nitrophosphates and mineralized carbon. Advantageously, the systems and methods are capable of sequestering carbon from the atmosphere. The systems generally include a first reactor for producing nitric acid; a mixer for mixing the nitric acid produced in the first reactor with a phosphate source, thereby producing nitro-phosphoric acid; and a second reactor for producing a solution comprising nitrophosphates and mineralized carbon, wherein the second reactor is operable to receive: the nitro-phosphoric acid from the mixer, ammonia, water, and carbon dioxide.