A hydrogen permeable membrane device is provided that includes a porous ceramic layer having a material that includes zirconia, Yttria-stabilized zirconia (YSZ), γ/Al.sub.2O.sub.3, and/or YSZ— γ/Al.sub.2O.sub.3, and a porous Pd film or porous Pd-alloy film deposited on the a mesoporous ceramic layer.

A system and method for producing hydrogen, including providing hydrocarbon and steam into a vessel to a region external to a tubular membrane in the vessel. The method includes steam reforming the hydrocarbon in the vessel via reforming catalyst to generate hydrogen and carbon dioxide. The method includes diffusing the hydrogen through the tubular membrane into a bore of the tubular membrane, wherein the tubular membrane is hydrogen selective.

A system and method of producing hydrogen, including converting hydrocarbon to methane via steam and pre-reforming catalyst in a pre-reformer, converting the methane to hydrogen and carbon dioxide by steam reforming via a reforming catalyst in a membrane reformer, diffusing through hydrogen through a tubular membrane in the membrane reformer.

A system and method for producing hydrogen from hydrocarbon and steam, including a membrane reformer with multiple membrane reactors each having a tubular membrane. The bore of the tubular membrane is the permeate side for the hydrogen. The region external to the tubular membrane is the retentate side for carbon dioxide. A sweep gas flows through the bore to displace hydrogen in a direction countercurrent to flow of hydrocarbon and steam in the region external to the tubular membrane. The method includes discharging hydrogen as permeate with the sweep gas from the bore, and discharging carbon dioxide in the region external to the tubular membrane as retentate from the membrane reactor.

A processing facility is provided that includes a feedstock separation system configured to separate a feed stream into a lights stream and a heavies stream, a hydrogen production system configured to produce hydrogen and carbon dioxide from the lights stream, and a carbon dioxide conversion system configured to produce synthetic hydrocarbons from the carbon dioxide. The processing facility includes a hydroprocessing system configured to process the heavies stream.

Provided is a fuel-reforming device comprising: an ammonia tank (4); a reformer (5) for reforming ammonia and generating high-concentration hydrogen gas having a hydrogen content of at least 99%; a mixing tank (7) for mixing ammonia and hydrogen for temporary storage; and a control means (10) for controlling the respective supply amounts of ammonia and high-concentration hydrogen gas that are supplied to the mixing tank (7). The control means (10) calculates the combustion rate coefficient C of mixed gas with respect to a reference fuel on the basis of equation (1). Equation (1): S.sub.0=S.sub.H×C+S.sub.A×(1−C). In equation (1), S.sub.0 is the combustion rate of the reference fuel, S.sub.H is the combustion rate of hydrogen, S.sub.A is the combustion rate of ammonia, and C is the combustion rate coefficient of mixed gas. In addition, on the basis of equation (2), the control means (10) determines the volume fractions of ammonia and hydrogen that are supplied to the mixing tank. Equation (2): C=1−exp(−A×M.sub.B). In equation (2), M is the volume fraction of hydrogen in mixed gas, and A and B are constants.

A method of producing hydrogen in a plant for hydrogen production during combustion of a mixture of hydrocarbon feedstock with an oxidizer with an oxidant excess ratio of less than 1. The method is characterized in that the combustion process is carried out at a temperature of less than 1400 K inside several cavities, completely or partially formed by a material permeable to a mixture of hydrocarbon feedstock with an oxidant.

Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

A gas turbine engine includes a cracking device that is configured to decompose an ammonia flow into a flow that contains more hydrogen (H2) than ammonia (NH3), a first separation device that separates hydrogen downstream of the cracking device, wherein residual ammonia and nitrogen are exhausted as a residual flow. The separated flow contains more hydrogen than ammonia, and nitrogen is exhausted separately as a hydrogen flow. A combustor is configured to receive and combust the hydrogen flow from the separation device to generate a gas flow. A compressor section is configured to supply compressed air to the combustor. A turbine section is in flow communication with the gas flow produced by the combustor and is mechanically coupled to drive the compressor section.

A reactive process for converting composite plastic waste into hydrogen gas and a reactor system for effecting such process.