Systems and methods are provided for improving the flow distribution in the high temperature zone of a cyclic flow reactor, such as a reverse flow reactor. The systems can include a plurality of mixing plates that can facilitate mixing of flows that have been maintained separately until a mixing location. Based in part on the use of a plurality of mixing plates, methods are provided for operating a reverse flow reactor with a temperature profile that has improved uniformity across the cross-section of the reactor. In some aspects, a flame diffuser can be included downstream from the plurality of mixing plates to further improve the uniformity of the temperature distribution.

Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or syngas) produced in a heat-generating unit such as a partial oxidation (PDX) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

Disclosed is a hydrogen production system using a biochar oven, the system including: a vertical pyrolysis furnace into which a pyrolysis target including at least one of waste plastic and fossil fuel is supplied in a free fall scheme by its own weight; a plate-shaped flameless heater configured to heat the vertical pyrolysis furnace such that a high-temperature atmosphere of 800 to 1300? C. is generated therein; a solid-gas separator installed under a bottom of the vertical pyrolysis furnace and configured to receive a biochar-gas mixture produced from the vertical pyrolysis furnace and to separate the biochar-gas mixture into the BOG and the biochar and to discharge the BOG and the biochar; and a BOG purification unit configured to receive therein the biochar separated using the solid-gas separator therefrom, and use the received biochar as an adsorbent, wherein the BOG separated using the solid-gas separator passes through the received biochar in the BOG purification unit such that impurities contained in the BOG are removed therefrom.

A method for providing hydrogen gas includes the process steps pre-heating of an at least partially hydrogenated hydrogen carrier material, release of hydrogen gas by at least partial dehydrogenation of the hydrogen carrier material, purification of the released hydrogen gas as well as cooling and conditioning of the at least partially dehydrogenated hydrogen carrier material.

Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or syngas) produced in a heat-generating unit such as a partial oxidation (POX) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

Embodiments of the invention relate to systems and methods for producing hydrogen gas and liquid fuels from methane-containing gases or organic feedstock using one or more of pyrolysis or electrolysis. The systems and methods include using gasifiers, oxidation units, cleaners, and liquid fuel manufacturing systems to produce liquid fuels. Ratios of carbon to hydrogen are controlled in the systems and methods to provide efficient liquid fuel and hydrogen formation.

Nuclear energy integrated hydrocarbon operation systems include a well site having a subsurface hydrocarbon well configured to produce a produced water output. The system further includes a deployable nuclear reactor system configured to produce a heat output. The system may further include a deployable desalination unit configured to produce a desalinated water output using the produced water output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor. The system may further include a deployable off-gas processing system configured to produce an industrial chemical using the off-gas output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor.

A hydrocarbon feed stream is exposed to heat in an absence of oxygen to the convert the hydrocarbon feed stream into a solids stream and a gas stream. The gas stream is separated into an exhaust gas stream and hydrogen. The carbon is separated from the solids stream as a carbon stream. Electrolysis is performed on a water stream to produce an oxygen stream and hydrogen. The oxygen and a portion of the carbon are combined to generate power and a carbon dioxide stream. At least a portion of the carbon stream, cement, and water are mixed to form a concrete mixture. The concrete mixture can be used to produce ready-mix concrete and precast concrete. Carbon dioxide used for curing the concrete can be sourced from the carbon dioxide stream produced by power generation.

A reformer unit and high temperature, pressure, or both variable orifice flow controller is provided. The reformer unit may have a reforming section, a heat exchanging section, and a bypass section. The bypass section provides a flow path for the hydrocarbon-containing fuel around the reforming section and has a variable orifice flow controller positioned in the bypassing flow path.

A reforming unit for a fuel cell system is provided. The reforming unit may comprise a reforming section, a heat exchanging section and a bypass plenum. The reforming section reforms a hydrocarbon containing fuel. The heat exchanging section effects a heat transfer between a fluid flowing therethrough and the fluid flowing through the reforming section, the bypass plenum, or both. The bypass plenum provides a flowpath for the hydrocarbon-containing fuel to bypass the reforming section. The bypass plenum may comprise a flow restrictor in the outlet of the bypass plenum to control the amount of fluid communication between the outlet of the bypass plenum and the outlet of the reforming section.