The invention is referred to chemical technology, namely to active high-purity magnesium oxide and its production method.

Active high-purity magnesium oxide, including the surface treated one, has BET specific surface area from 70 to 200 m.sup.2/g, average particle size (d50) determined by laser diffraction method not more than 10 microns, iodine activity in the range from 70 to 200 mg J/g MgO, citric activity not more than 40 s, pore volume in the range from 3.2×10.sup.−2 cm.sup.3/g to 10.2×10.sup.−2 cm.sup.3/g, diameter of 10% of the particles not more than 2 microns, diameter of 90% of the particles not more than 30 microns, mass fraction of residue on the 150 micron sieve not more than 1%, mass fraction of residue on the 45 micron sieve not more than 2%, mass fraction of chlorides not more than 0.1%, mass fraction of calcium not more than 0.1%, mass fraction of substances insoluble in hydrochloric acid not more than 0.05%, mass fraction of iron not more than 0.005%, mass fraction of impurities of each of Ti, Co, Mo, V, Sb, Ba cations not more than 1 ppm, Pb, Cd, As, Hg not more than 0.1 ppm.

Method for the production of active high-purity magnesium oxide including the surface treated one consists of calcination of magnesium hydroxide obtained by interaction of magnesium salt solution with alkaline agent. Magnesium hydroxide crystals are produced by continuous method in divided and isolated between each other zones in the presence of seed crystals of magnesium hydroxide and liquid oil products with mole ratio of ions of alkaline agent and magnesium chloride OH.sup.−/Mg.sup.++ within the range (1.9÷2.1):1, with the temperature in all zones not less than 40° C. and magnesium hydroxide crystals suspension residence time in each isolated zone not less than 20 minutes.

Active high-purity magnesium oxide produced by this method has high activity and high chemical purity that allows to use it as a filler for rubbers, adhesives, plastics, polymers, as stabilizers in production of chloroprene rubbers, refining additives of organic solvents, in production of catalysts, special ceramics, special glass, in pharmaceutical, pharmacopoeial and food industries, in production of magnesia cement and other magnesium-containing materials.

Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons. Related methods for use and manufacture of the same are also disclosed.

Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons. Related methods for use and manufacture of the same are also disclosed.

Disclosed herein are system and methods to effectively leach coal ash with hydrochloric acid and separate an insoluble silica product and then selectively precipitate, from the leachate, a number to value-added, strategic, marketable products using a hydroxide reagent. The resulting precipitated products include iron, aluminum, magnesium, calcium, and a mixture of rare earth elements and transition metals. These can be separated as hydroxides or converted to oxides or carbonates. Using hydrochloric acid for leaching and converting the chloride to sodium chloride in the final step results in practically no waste for this process. The silica can be further purified using sodium hydroxide fusion or caustic leach methods and some minor streams from this process are recycled to minimize any waste stream. These systems and methods can be applied to a number of other industrial waste products such as red mud from the aluminum process, slag from steel furnaces, mine tailings, and other metal-bearing waste streams.

A process and apparatus for manufacture of biocide products are described. The biocide properties arise from the caustic calcined powder, from carbonates such as such as magnesite and dolomite, and from hydroxides such as brucite. The method of manufacture is based on the production of high surface area oxide particles using an indirectly heated counterflow reactors for specifically calcining the carbonates and the hydroxides without significant sintering. The biocide products may be a powder or a hydrated slurry. A hydrated slurry is preferred for agricultural applications as a spray. For aquaculture applications, the products have a preferred particle size distribution to impact the aquatic and benthic ecosystems, and a Ca/Mg ratio that promotes the growth of the cultivates species when applied as a powder or a slurry. For applications such as a marine paint, the powder product or the slurry product is mixed with various agents to form a setting coating, and is applied to the infrastructure that is otherwise subject to biofilm growth.

A process and apparatus for manufacture of biocide products are described. The biocide properties arise from the caustic calcined powder, from carbonates such as such as magnesite and dolomite, and from hydroxides such as brucite. The method of manufacture is based on the production of high surface area oxide particles using an indirectly heated counterflow reactors for specifically calcining the carbonates and the hydroxides without significant sintering. The biocide products may be a powder or a hydrated slurry. A hydrated slurry is preferred for agricultural applications as a spray. For aquaculture applications, the products have a preferred particle size distribution to impact the aquatic and benthic ecosystems, and a Ca/Mg ratio that promotes the growth of the cultivates species when applied as a powder or a slurry. For applications such as a marine paint, the powder product or the slurry product is mixed with various agents to form a setting coating, and is applied to the infrastructure that is otherwise subject to biofilm growth.

An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator which has an adhesion water content and a hydration water content each falling in the quadrilateral region defined by the following points a to d as the vertices in a graph representing the adhesion water content-hydration water content relationship: a: adhesion water content: 0.25 mass %, hydration water content: 0.1 mass % b: adhesion water content: 0.60 mass %, hydration water content: 0.1 mass % c: adhesion water content: 0.40 mass %, hydration water content: 6.0 mass % d: adhesion water content: 0.20 mass %, hydration water content: 6.0 mass %.

An object of the present invention is to provide magnesium oxide for an annealing separator which is useful for obtaining grain-oriented electromagnetic steel sheets with excellent magnetic properties and insulating properties. To resolve the above object, an aspect of the present invention resides in magnesium oxide for an annealing separator which has an adhesion water content and a hydration water content each falling in the quadrilateral region defined by the following points a to d as the vertices in a graph representing the adhesion water content-hydration water content relationship: a: adhesion water content: 0.25 mass %, hydration water content: 0.1 mass % b: adhesion water content: 0.60 mass %, hydration water content: 0.1 mass % c: adhesion water content: 0.40 mass %, hydration water content: 6.0 mass % d: adhesion water content: 0.20 mass %, hydration water content: 6.0 mass %.

A process for producing a highly calcined and uniformly calcined product from a feedstock. The process comprising the steps of grinding the feedstock to powder, preheating the powder, and calcining the powder in a reactor plant that comprises a number of reactor segments in which a flash calciner is used in each progressive reactor segment to incrementally react the powder by raising the temperature in each segment. The last segment may be a high-temperature reactor that has a controlled residence time and temperature that may allow controlled finishing of the calcination process to achieve a desired degree of calcination and sintering of the product; and cooling of the product.

A process for producing a highly calcined and uniformly calcined product from a feedstock. The process comprising the steps of grinding the feedstock to powder, preheating the powder, and calcining the powder in a reactor plant that comprises a number of reactor segments in which a flash calciner is used in each progressive reactor segment to incrementally react the powder by raising the temperature in each segment. The last segment may be a high-temperature reactor that has a controlled residence time and temperature that may allow controlled finishing of the calcination process to achieve a desired degree of calcination and sintering of the product; and cooling of the product.