The disclosure discloses a system for treating high-salt high-organic wastewater and recovering energy, the system includes a cold wall-type reactor (6), a multi-level cyclone separator (16, 19, and 25), a waste liquid feeding system, an oxidant feeding system and a fuel feeding system; The cold wall-type reactor designed by the disclosure is formed by inner and outer double-housing structures, a cooling medium is fed into a gap between the inner housing and the outer housing of the reactor, the fluid on an inner wall surface of the inner housing of the reactor is cooled below a supercritical temperature of the water by using countercurrent heat exchange, blockage of the inorganic salts is effectively prevented. The disclosure is capable of realizing gradient utilization of the reaction heat of the high-salt high-organic wastewater supercritical water oxidation system, and improving a system energy recovery utilization ratio in the greatest degree.

A process including introducing, into a device, an aqueous fluid containing at least one inorganic salt, the water of the aqueous fluid being in supercritical conditions or close to the supercritical range in the device, and measuring the concentration or the amount of inorganic salt in the device, this measurement preferably being carried out before the entry of the inorganic salt into the device, Then bringing the inorganic salt into contact with an aqueous flow containing at least one hydroxide salt to obtain in the device an aqueous fluid mixture containing an inorganic salt and a hydroxide salt and adjusting the concentration or amount of the hydroxide salt as a function of the concentration or amount of the inorganic salt needed to at least partially solubilize the inorganic salt. Preferably the measurement of the concentration or the amount of inorganic salt leaving the device is also performed.

A supercritical water oxidation-flame piloted vortex reactor has a hydrothermal flame produced within the interior of the reactor fed by a fuel including a waste water stream, and has a subcritical wash stream, including water below its critical point, that creates an upward helical flow in the material within the reactor. The hydrothermal flame and upward helical flow produce within the reactor a supercritical core region, a subcritical outer region around the core region, and a transcritical intermediate region between them. The upward helical flow serves to transfer precipitated ionic compounds out of the supercritical core region, through the transcritical intermediate region, and into the subcritical outer region where they re-dissolve. A processed flow, including purified water, is removed from an upper portion of the supercritical core region by an aspirator.

The present invention relates to supercritical water oxidation reactor adapted to contain inside the reactor an aqueous fluid below and above its supercritical state, said fluid comprising organic and/or inorganic material and a method of controlling such a reactor.

A waste processing system includes a reactor including an inlet end and an outlet end configured to discharge reactor effluent. The inlet end includes a mixing unit having an oxidizing material input and a waste stream input. The reactor oxidizing material input is configured to receive reactor oxidizing material at a temperature greater than 200 C. and at a pressure greater than 60 atm. A second waste stream input is positioned between the reactor inlet end and the reactor outlet end.

The invention relates to a method for the fractioned separation of valuable substances from aqueous many-component mixtures such as aqueous wastes, sludges and sewage sludge under supercritical conditions. The invention also comprises valuable substance fractions that are enriched after the method according to the invention, more particularly phosphorous-containing and phosphorous- and ammonium-containing compounds such as fertilisers and synthesis gas as an energy source and as a valuable substance for the chemicals industry. The invention comprises devices for carrying out the methods. With the method and devices according to the invention, valuable substances can be completely recovered from wastes, sludges and sewage sludge and given a new use. The methods and devices are particularly suitable for recovering phosphorous and ammonium in the form of plant-available fertiliser, for recovering metals and heavy metals, for producing synthesis gas and for obtaining hydrogen from synthesis gas, i.e. for mobility.

The disclosed technology relates to methods of inhibiting corrosion in reaction chambers configured for hydrothermal reaction of feeds containing a heteroatom. An embodiment of such a method comprises providing a feed stream comprising a phosphorus-containing material, an alkali metal compound, water, and a corrosion-inhibitor. The embodiment additionally includes introducing the feed stream and oxidant into a reactor chamber and oxidizing the phosphorus-containing material at an oxidation temperature greater than about 374 C. and an oxidation pressure exceeding about 25 bar, wherein the reactor chamber has inner surfaces comprising a material that corrodes when in contact with a phosphorus compound within the reactor. The embodiment additionally includes selectively reacting the corrosion-inhibitor with phosphorus within the reactor, thereby precipitating in the reactor chamber a phosphorus-containing solid inorganic compound. The embodiment further includes forming in the reactor chamber an alkali salt melt and carrying away from the reactor chamber a mixture comprising the solid phosphorus-containing inorganic compound and the alkali salt melt.

Apparatus for salt separation (2) under supercritical water conditions, comprising a heat exchanger (4) and a fluidized bed reactor (6). The fluidized bed reactor comprising a supercritical water pressure containing wall (8) defining therein a fluidized bed chamber (10) connected to an inlet system (16) at one end thereof and an outlet system (18) configured to separate solids from supercritical fluid at another end thereof. The fluidized bed chamber receives a fluidized bed (12) therein and is configured to receive through the inlet system (16) a liquefied aqueous substance (14) for treatment in the fluidized bed chamber. The inlet system (16) comprises an inlet chamber (20) and a fluidization plate (22) positioned between the inlet chamber (20) and the fluidized bed chamber (10). The fluidized bed chamber extends between the inlet system (16) and outlet system (18) and comprises an entry section (10a) adjacent the inlet system (16), an outlet section (10c) adjacent the outlet system (18), and a mid-section (10b) extending between the entry section and the outlet section. The heat exchanger (4) extends along the fluidized bed chamber (10) and is configured to generate a decreasing temperature gradient in the fluidized bed chamber from the outlet section (10c) to the entry section (10a), the temperature gradient in the outlet section and mid-section being supercritical for aqueous substances and being subcritical for aqueous substances in the entry section (10a) adjacent the fluidization plate (22).

A method of, and apparatus and system for, decontaminating a liquid containing dissolved solids including subjecting liquid containing dissolved solids to Joule heating under conditions effective to cause said dissolved solids to precipitate out of solution.

A horizontal self-balancing supercritical reaction apparatus, comprising a pressure vessel, a high pressure air compression apparatus, and at least one reactor arranged within the pressure vessel. The reactor is internally provided with front and rear pistons, two ends of the reactor are sealed by the reactor front piston and the reactor rear piston, a pressure medium is filled between the reactor front piston and an inner wall of the pressure vessel, the reactor rear piston is connected to a rear piston driving motor by a rear piston push rod, the reactor is provided with a water inlet and a water/air outlet which are controlled by valves, the reactor is internally provided with a heating apparatus, and the high pressure air compression apparatus is connected to the inside of the reactor. The present invention utilises a pressure self-balancing system, which significantly improves the stress characteristics of the reactor.