Technologies are described for a process for in situ treatment of contaminated soil(s), water, waste, sludge, wastewater, sediment, other contaminated matrix, or combination thereof. The process comprises applying a reactive or treatment material and an adjunct to the contaminated matrix or in a flow path of the contaminant in the matrix. The adjunct is controllably released into the matrix and contributes to the treatment of the soil(s), water, waste, sludge, wastewater, sediment, other contaminated matrix, or combination thereof

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may include the transfer of contaminants from an aqueous phase to a foam prior to the destruction of the contaminants.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

The present disclosure discloses a method for removing chlorinated hydrocarbons in groundwater through step-by-step electrocatalytic dechlorination degradation. A double-chamber electrolyzer reactor is used to carry out step-by-step electrocatalytic dechlorination degradation to remove chlorinated hydrocarbons in groundwater. The double-chamber electrolyzer reactor comprises a cathode chamber, a proton exchange membrane, an anode chamber and an intermediate processing unit, wherein the cathode chamber is separated from the anode chamber through the proton exchange membrane, and the intermediate processing unit is connected between the cathode chamber and the anode chamber through a cathode chamber water outlet, an anode chamber water inlet and pipelines. The double-chamber electrolyzer reactor adopted in the present disclosure is simple in structure and convenient to use, is capable of effectively enhancing the removal effect of electric catalysis on chlorinated hydrocarbon substances and reducing toxic and harmful substances produced by direct oxidization of chlorinated hydrocarbons, and has a good application prospect.

The present invention discloses a method for initiating a graphene oxide (GO) through reduction by a reductant to controllably release organic compounds, comprising the following steps: (1) mixing GO and a buffer solution; (2) further mixing with a sewage containing organic contaminants; (3) conducting solid-liquid separation, mixing the solid phase and the pure, introducing and N.sub.2; (4) further adding the reductant; (5) conducting sequential batch kinetics experiment. The present invention utilizes the size effect and polarity control of GO to selectively adsorb aromatic organic contaminants in sewage and fully transfer the selectively adsorbed organic contaminants from a large amount of sewage to a small amount of pure water by initiating using the reductant, and no extraction of the organic phase is required, the time for purification is reduced, and the energy consumption for purification is also reduced.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may include the transfer of contaminants from an aqueous phase to a foam prior to the destruction of the contaminants.

A composition for remediation of soil and groundwater containing halogenated compounds. The remediation composition includes an elemental iron-based composition, which may include activated carbon capable of absorbing the halogenated compounds with numerous pores impregnated with elemental iron. The remediation composition further includes a first bioremediation material including a blend of one-to-many organisms capable of degrading the halogenated compounds. The remediation composition includes an organic compound or polymeric substance and a second bioremediation material including a blend of one-to-many organisms capable of degrading the organic compound or polymeric substance over time (e.g., 20 to 365 or more days to provide a time release substrate-creating material or platform) into smaller molecules or compounds used by the organisms in the first bioremediation material while degrading the halogenated compounds. The organic compound may be a complex carbohydrate such as food grade starch, chitin, or other complex carbohydrate such as one with low water solubility.

A method and system for the reduction of contamination in soil and groundwater is provided. Cyclic oligosaccharides can be used, for example, to carry oxidants, carry activators, solubilize organic contaminants and promote biodegradation.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

The present invention discloses a method for initiating a graphene oxide (GO) through reduction by a reductant to controllably release organic compounds, comprising the following steps: (1) mixing GO and a buffer solution; (2) further mixing with a sewage containing organic contaminants; (3) conducting solid-liquid separation, mixing the solid phase and the pure, introducing and N.sub.2; (4) further adding the reductant; (5) conducting sequential batch kinetics experiment. The present invention utilizes the size effect and polarity control of GO to selectively adsorb aromatic organic contaminants in sewage and fully transfer the selectively adsorbed organic contaminants from a large amount of sewage to a small amount of pure water by initiating using the reductant, and no extraction of the organic phase is required, the time for purification is reduced, and the energy consumption for purification is also reduced.