Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

A sonic reactor for transferring kinetic energy to a process fluid medium has a resonant element horizontally oriented and mounted to the two resonance units using two or more nodal support rings located at the nodal positions of the resonant element. The nodal support rings are adjustable in position relative to the resonant element and the resonance units to permit positioning of the rings directly at the nodal positions during operation. The sonic reactor has a grinding or mixing chamber mounted at one or both of the free ends of the resonant element. The sonic reactor is used for applications that include fly ash beneficiation, pulverization and dispersion; fine ore grinding; preparing ready mix cement formulations; oil sands cuttings for oil recovery; spilled oil, water and oily water storage treatment; organic and inorganic industrial wastewater treatment; environmental remediation of contaminated soils; sodium dispersion and destruction of PCBs; biosludge conditioning; cellulosic biofuels processing; lignin processing; dispersion and deagglomeration of pigments; and dye destruction.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

Described herein are passive samplers, making of such samplers, and methods of use. In an example embodiment, a passive sampling membrane comprises, for example, a continuous mesoporous sequestration media having a sequestration phase and a support membrane configured to support the sequestration phase. The sequestration phase may include a hydrophobic region and a hydrophilic region. The continuous mesoporous sequestration media may be configured to simultaneously sequester polar and non-polar organic substances.

A method of separating trace amounts of amphiphilic substances from water which is contaminated with the substances, the method comprising the steps of: admitting an amount of the water, which includes an initial concentration of the substances, into a chamber via an inlet thereinto: introducing a flow of gas into the chamber, wherein said introduced gas induces the water in the chamber to flow, and produces a froth layer which is formed at, and which rises above, an interface with the said flow ofcontrolling the water content of the froth layer which rises above the interface to influence the concentration of the substances therein; andremoving at least some of the froth layer from an upper portion of the chamber.

Disclosed are methods, apparatuses and systems for the remediation of contaminated soils, groundwater, water, and/or waste using a combination of reagents. The disclosed methods may be used to treat various recalcitrant halogenated substances, such as perfluoroalkyls and polyfluoroalkyls. Particular combinations of reagents that may be used in the disclosed methods include but are not limited to: (1) persulfate, oxygen and ozone; (2) persulfate, salt, oxygen and ozone; (3) persulfate, phosphate, and/or oxygen; (4) persulfate, phosphate, oxygen and ozone; (5) persulfate, phosphate, salt and oxygen (6) persulfate, phosphate, salt, oxygen and ozone; (7) oxygen and salt; and (8) air and salt. The disclosed methods may enhance destruction of organic contaminants in the liquid phase and may also control the rate of aerosol or foam formation relative to the rate of chemical oxidation and/or reduction/transfer.

A method and system for the reduction of contamination in soil and groundwater is provided. Cyclic oligosaccharides can be used, for example, to carry oxidants, carry activators, solubilize organic contaminants and promote biodegradation.

An encapsulated reactant(s) having at least one encapsulant and at least one reactant is presently provided. An outermost encapsulant is substantially nonreacting, impermeable and nondissolving with water. The reactant(s) contribute to at least one reaction with contaminants in environmental media rendering the environmental media less harmful. Processes for making and using the encapsulated reactant in environmental media is also hereby disclosed.

An encapsulated reactant(s) having at least one encapsulant and at least one reactant is presently provided. An outermost encapsulant is substantially nonreacting, impermeable and nondissolving with water. The reactant(s) contribute to at least one reaction with contaminants in environmental media rendering the environmental media less harmful. Processes for making and using the encapsulated reactant in environmental media is also hereby disclosed.

A sonic reactor for transferring kinetic energy to a process fluid medium has a resonant element horizontally oriented and mounted to the two resonance units using two or more nodal support rings located at the nodal positions of the resonant element. The nodal support rings are adjustable in position relative to the resonant element and the resonance units to permit positioning of the rings directly at the nodal positions during operation, where, for example, adjustment may be required due to changes in the total mass attached to one or both free ends of the resonant unit. The sonic reactor has a grinding or mixing chamber mounted at one or both of the free ends of the resonant element.