The present invention relates to a glass substrate, having a specific matrix composition and including an etched surface having the number of protrusions of 400 or more and 2,000 or less on at least one of main surfaces, in which the number of protrusions is obtained by measuring a region of 285.12 μm×213.77 μm with a laser microscope to obtain XYZ data of a surface shape, and conducting a shape analysis of the XYZ data by using an image processing software SPIP manufactured by Image Metrology.

Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO.sub.2, 0 to 20% B.sub.2O.sub.3, 0 to 25% Al.sub.2O.sub.3, 0 to 3% Li.sub.2O, 0 to 3% Na.sub.2O, 0 to 3% K.sub.2O, 0 to 3% Li.sub.2O+Na.sub.2O+K.sub.2O, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphate phosphor.

Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO.sub.2, 0 to 20% B.sub.2O.sub.3, 0 to 25% Al.sub.2O.sub.3, 0 to 3% Li.sub.2O, 0 to 3% Na.sub.2O, 0 to 3% K.sub.2O, 0 to 3% Li.sub.2O+Na.sub.2O+K.sub.2O, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphate phosphor.

Provided is a ceramic complex having high luminous characteristics. Proposed is a ceramic complex including a rare earth aluminate fluorescent material, glass, and calcium fluoride, wherein, when the total amount of the rare earth aluminate fluorescent material, the glass, and the calcium fluoride is taken as 100% by volume, the content of the rare earth aluminate fluorescent material is in a range of 15% by volume or more and 60% by volume or less, the content of the glass is in a range of 3% by volume or more and 84% by volume or less, and the content of the calcium fluoride is in a range of 1% by volume or more and 60% by volume of less.

A cover glass of the present invention is characterized by including in a glass composition at least three or more components selected from SiO.sub.2, Al.sub.2O.sub.3, B.sub.2O.sub.3, Li.sub.2O, Na.sub.2O, K.sub.2O, MgO, CaO, BaO, TiC.sub.2, Y.sub.2O.sub.3, ZrO.sub.2, and P.sub.2O.sub.5, and having an X value of 7, 400 or more calculated by the following equation. The X value is a value calculated by the equation

X=61.1×[SiO.sub.2]+174.3×[Al.sub.2O.sub.3]+11.3×[B.sub.2O.sub.3]+124.7×[Li.sub.2O]−5.2×[Na.sub.2O]+226.7×[K.sub.2O]+139.4×[MgO]+117.5×[CaO]+89.6×[BaO]+191.8×[TiO.sub.2]+226.7×[Y.sub.2O.sub.3]+157.9×[ZrO.sub.2]−42.2×[P.sub.2O.sub.5].

A cover glass of the present invention is characterized by including in a glass composition at least three or more components selected from SiO.sub.2, Al.sub.2O.sub.3, B.sub.2O.sub.3, Li.sub.2O, Na.sub.2O, K.sub.2O, MgO, CaO, BaO, TiC.sub.2, Y.sub.2O.sub.3, ZrO.sub.2, and P.sub.2O.sub.5, and having an X value of 7, 400 or more calculated by the following equation. The X value is a value calculated by the equation

X=61.1×[SiO.sub.2]+174.3×[Al.sub.2O.sub.3]+11.3×[B.sub.2O.sub.3]+124.7×[Li.sub.2O]−5.2×[Na.sub.2O]+226.7×[K.sub.2O]+139.4×[MgO]+117.5×[CaO]+89.6×[BaO]+191.8×[TiO.sub.2]+226.7×[Y.sub.2O.sub.3]+157.9×[ZrO.sub.2]−42.2×[P.sub.2O.sub.5].

Methods of producing a glass article include melting a first glass composition and feeding a second glass composition into the melter. Both glass compositions include the same combination of components but at least one component has a concentration that is different in each. At least three glass articles may be drawn from the melter, including: a first glass article formed from the first glass composition; at least one intermediate glass article composed of neither the first nor the second glass composition; and a final glass article not composed of the first glass composition. The concentration of the at least one component in the intermediate glass article may be between the concentration in the first and second glass compositions. The first glass article and final glass article may have differing values for certain properties, and the intermediate glass article may have an intermediate set of values for the same properties.

An optical material includes, in mol.%: 50-75% SiO.sub.2, 5-25% Al.sub.2O.sub.3, 2.5-25% MgO, and 1-15% at least one lanthanoid, such that the at least one lanthanoid includes: La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or oxides or fluorides thereof. An optical material includes at least one lanthanoid and at least one alkaline earth fluoride dopant, such that the at least one lanthanoid includes: La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or oxides or fluorides thereof, and such that the at least one alkaline earth fluoride dopant comprises BeF.sub.2, MgF.sub.2, CaF.sub.2, SrF.sub.2, and BaF.sub.2.

The disclosure relates to highly temperable colored glass compositions. The colored glass compositions have high coefficients of thermal expansion and high Young's moduli that advantageously absorb in the ultraviolet and/or blue wavelength ranges. Methods of making such glasses are also provided.

The disclosure relates to highly temperable colored glass compositions. The colored glass compositions have high coefficients of thermal expansion and high Young's moduli that advantageously absorb in the ultraviolet and/or blue wavelength ranges. Methods of making such glasses are also provided.