The present disclosure provides a method for coating a composite structure comprising the steps of applying a first slurry of a first phosphate glass composition on an outer surface of the composite structure. The first slurry comprises a first additive including at least one of molybdenum disulfide or tungsten disulfide. The method may further include heating the composite structure to a temperature sufficient to form a base layer adhered to the composite structure.

The present disclosure provides a method for coating a composite structure comprising the steps of applying a first slurry of a first phosphate glass composition on an outer surface of the composite structure. The first slurry comprises a first additive including at least one of molybdenum disulfide or tungsten disulfide. The method may further include heating the composite structure to a temperature sufficient to form a base layer adhered to the composite structure.

Embodiments of methods for forming strengthened glass articles comprise providing an exchangeable glass substrate having a coefficient of thermal expansion (CTE) between about 60×10-7/° C. to about 110×10-7/° C., depositing at least one decorative porous inorganic layer onto at least a portion of the surface of the glass substrate, wherein the decorative porous inorganic layer comprises a glass transition temperature (Tg)≥450° C., a glass softening temperature (Ts)≤650° C., wherein the difference in CTE values between the glass substrate and the decorative porous inorganic layer is within 10×10-7/° C.; and curing the glass substrate and the deposited decorative porous inorganic layer at a temperature greater than the Ts of the decorative porous inorganic layer; and chemically strengthening the cured glass substrate and the decorative porous inorganic layer thereon via ion exchange at a temperature below the Tg of the decorative porous inorganic layer.

Embodiments of methods for forming strengthened glass articles comprise providing an exchangeable glass substrate having a coefficient of thermal expansion (CTE) between about 60×10-7/° C. to about 110×10-7/° C., depositing at least one decorative porous inorganic layer onto at least a portion of the surface of the glass substrate, wherein the decorative porous inorganic layer comprises a glass transition temperature (Tg)≥450° C., a glass softening temperature (Ts)≤650° C., wherein the difference in CTE values between the glass substrate and the decorative porous inorganic layer is within 10×10-7/° C.; and curing the glass substrate and the deposited decorative porous inorganic layer at a temperature greater than the Ts of the decorative porous inorganic layer; and chemically strengthening the cured glass substrate and the decorative porous inorganic layer thereon via ion exchange at a temperature below the Tg of the decorative porous inorganic layer.

Glass compositions include niobia (Nb.sub.2O.sub.5), phosphorus oxide (P.sub.2O.sub.5) and titania (TiO.sub.2) as essential components and may optionally include calcium oxide (CaO), potassium oxide (K.sub.2O), barium oxide (BaO), sodium oxide (Na.sub.2O), lithium oxide (Li.sub.2O), magnesia (MgO), zinc oxide (ZnO) and other components. The glasses may be characterized by high refractive index at 587.56 nm at comparably low density at room temperature.

The invention relates to phosphate-based glasses suitable for use as a solid laser medium, doped with Er3+ and sensitized with Yb, in “eye-safe” applications. In particular, the invention relates to improving the physical properties of such phosphate-based laser glass composition, particularly with regards to strength of the glass structure and improved thermal shock resistance.

The invention relates to phosphate-based glasses suitable for use as a solid laser medium, doped with Er3+ and sensitized with Yb, in “eye-safe” applications. In particular, the invention relates to improving the physical properties of such phosphate-based laser glass composition, particularly with regards to strength of the glass structure and improved thermal shock resistance.

The present disclosure provides a method for coating a composite structure, comprising forming a first slurry by combining a glass frit comprising a first phosphate glass composition with a first carrier fluid comprising an acid aluminum phosphate, wherein the ratio of aluminum to phosphoric acid is between 1 to 2 and 1 to 3, applying the first slurry on a surface of the composite structure to form a base layer, and heating the composite structure to a temperature sufficient to adhere the base layer to the composite structure.

The present invention relates to an anisotropic glass containing, in terms of mol % on the basis of oxides, P.sub.2O.sub.5 in a content of from 45 mol % to 57 mol %, two or more kinds of alkali metal oxides selected from the group consisting of Li.sub.2O, Na.sub.2O, K.sub.2O, Rb.sub.2O, and Cs.sub.2O in a total content of from 30 mol % to 54 mol %, and at least one polyvalent element oxide other than P.sub.2O.sub.5 in a total content of from 0.1 mol % to 20 mol %, and having a birefringence of 30×10.sup.−6 or more.

The present invention relates to an anisotropic glass containing, in terms of mol % on the basis of oxides, P.sub.2O.sub.5 in a content of from 45 mol % to 57 mol %, two or more kinds of alkali metal oxides selected from the group consisting of Li.sub.2O, Na.sub.2O, K.sub.2O, Rb.sub.2O, and Cs.sub.2O in a total content of from 30 mol % to 54 mol %, and at least one polyvalent element oxide other than P.sub.2O.sub.5 in a total content of from 0.1 mol % to 20 mol %, and having a birefringence of 30×10.sup.−6 or more.